File name: Pandora105s1_Helsinki_20240511_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T082214.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240511_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240511 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240511T024051.9Z 8897.111711 126 1 50.54 2 85.63 60.69 89.98 21.71 0.00 1 0.00 1 0 41 6.991e-01 1.428e-01 5.745e-01 1.344e-01 1.191918e+00 8.891831e-02 1.690430e-02 -6.000000e+00 4.425799e-01 231.02 -2.00 4.26 -2.00 320.93 0.00e+00 -1.070711e-02 1.607768e-02 3.986521e-04 -6.000000e+00 1.844824e-02 271.81 -2.00 20.00 -2.00 320.32 0.00e+00 10.814 0.033 302.00 328.00 3 -1.5217e+00 2.4258e-01 1.3339e-01 -6.0000e+00 1.1126e+00 3.4700e+00 2.7619e-01 7.3110e-02 -6.0000e+00 1.2075e+00 -2.4726e+00 1.6486e-01 3.6443e-02 -6.0000e+00 7.1193e-01 5.9558e-01 8.3652e-02 1.0605e-02 -6.0000e+00 2.9437e-01 7.2253e-06 -6.0323e-03 3.3423e-03 1.7813e-04 -6.0000e+00 1.9128e-02 2.6252e-02 -1.5651e-04 12 8 8 10 0 0 18.51 16.59 1.35 0.02625 -0.01908 15 3 1 5 0 3368.800 19.85 14.99 16.59 999.00 -9.0 -9.00 45703 53248 -6104 79778 900000 900000 -55025 -66275 -61956 7969 -9630 900000 203126 106228 187779 900000 900000 36125 163654 900000 173148 900000 53162 25563 -8312 121929 271532 -33942 -33890 900000 57638 140551 -30075 -48811 -55937 261760 266019 -24703 900000 25213 900000 132694 -37178 66161 900000 -77295 900000 2596 900000 41687 121113 100267 14339 41734 8082 128544 64585 -31223 -44506 -49859 900000 -3390 3413 74537 -50062 -27036 -28253 -25300 -3747 25353 16772 7002 114517 15308 3040 -51206 -35381 54765 1996 -20809 -27845 79167 58660 40098 46647 20559 -29785 39026 13472 -32283 52307 3266 6051 36206 25543 78225 23727 29069 15474 15040 39753 -18200 -32640 -1228 18062 14194 66924 6964 29244 20716 11465 -1453 7839 31359 -1162 -8840 7045 -8628 4096 -2547 -15884 6522 -7802 -4267 -704 -1857 682 1517 -7241 5034 -8975 -4767 -3857 -5825 -1472 774 -344 1938 6089 6300 -530 3641 5974 6960 -1227 10427 900000 900000 -11987 -17325 -16196 1042 -1469 900000 26550 13884 24544 900000 900000 5902 21390 900000 22631 900000 6949 3620 -1720 15937 35491 -6655 -5906 900000 7534 18371 -7862 -14886 -17281 34213 34770 -6164 900000 5093 900000 17344 -13694 8648 900000 -33064 900000 494 900000 5944 15830 13105 3408 7934 2209 16801 9976 -11501 -16394 -17181 900000 -765 811 9742 -23199 -9637 -10407 -9620 -1291 7230 5381 2413 14968 3820 723 -18253 -10510 7874 522 -8159 -13565 16556 16101 13627 15242 8868 -19466 13772 5811 -20254 12990 1281 2373 11831 11017 23516 14265 18997 12338 11598 21303 -14749 -27304 -770 9915 8349 24492 5097 19876 18142 12588 -1956 9836 30741 -1518 -12247 8563 -12856 5568 -3628 -23875 7246 -9688 -5020 -782 -2014 722 1844 -11735 8488 -19590 -10903 -9528 -16066 -4195 2224 -1006 5598 16474 15811 -1296 7851 SS 20240511T025328.9Z 8897.120474 129 1 50.69 2 84.24 63.36 89.39 24.31 0.00 1 0.00 1 0 25 8.564e-01 4.986e-02 4.853e-01 3.480e-02 1.365655e+00 2.262219e-02 1.709108e-02 -6.000000e+00 5.170804e-01 231.02 -2.00 4.26 -2.00 322.64 0.00e+00 -3.319218e-02 7.898780e-03 1.743461e-03 -6.000000e+00 2.288372e-02 271.81 -2.00 20.00 -2.00 322.24 0.00e+00 8.829 0.018 302.00 328.00 3 -8.9811e-01 7.4561e-02 1.2424e-01 -6.0000e+00 1.3064e+00 2.8007e+00 8.6905e-02 8.3879e-02 -6.0000e+00 1.4193e+00 -2.9450e+00 6.2115e-02 4.6331e-02 -6.0000e+00 8.2759e-01 9.7187e-01 3.7039e-02 1.6132e-02 -6.0000e+00 3.4269e-01 3.7979e-05 1.9803e-03 8.4095e-04 1.9123e-04 -6.0000e+00 2.3231e-02 2.3169e-02 1.2792e-05 12 8 8 10 0 0 19.09 16.59 0.30 0.02317 0.03805 48 9 1 5 0 1055.960 19.75 15.01 16.59 999.00 -9.0 -9.00 52628 900000 250370 -15817 26803 -15923 900000 -36657 99946 -14168 900000 -18942 181676 19050 176691 39669 199172 57298 -1275 20286 -1998 76418 -50318 900000 -13259 900000 -46908 85688 -87242 80961 -31199 -11971 -20315 138423 6132 -50413 13945 86885 223878 8472 241518 4401 464438 -1884 436670 17290 92686 -54883 99683 -2083 34357 197360 107683 108575 17181 179106 16963 900000 3985 91740 5225 31233 -60945 51650 -17373 -74 24889 24226 52316 37344 72188 26251 71157 -7385 119911 -63485 -6033 -23032 14860 3351 58171 22730 35855 34098 19207 37966 12115 15886 -4528 -1141 -21222 12489 -8014 6808 -11321 675 -7959 2718 -3915 -519 -7939 -3885 -4191 -3510 -658 -3608 -1002 -3651 11761 -2409 6591 -656 3746 -4905 -568 -3218 16 -2796 -808 3089 -72 3571 2584 3856 -3493 5059 -4264 5743 -3443 4360 -3666 1356 -2089 -72 1047 -679 2344 137 2167 -2856 1082 -2553 3349 900000 8485 -1150 1067 -985 900000 -3727 3387 -1380 900000 -1910 6157 1340 5988 2447 6750 2738 -100 1146 -123 2590 -5640 900000 -1371 900000 -5339 2904 -10192 2744 -2560 -897 -1739 4691 331 -4541 754 2944 7587 846 8185 451 15739 -157 14798 993 3141 -6384 3378 -175 2264 6688 4055 4395 1860 6070 1900 900000 383 3287 428 2238 -12277 3851 -2535 -9 2675 2932 5521 5026 7059 3914 6063 -1180 4661 -13386 -765 -3947 2115 642 7660 4908 7290 7362 4965 8308 3449 4214 -1385 -313 -6822 2939 -2553 2228 -5233 328 -4960 1737 -2783 -337 -4858 -2001 -2045 -1818 -351 -2075 -609 -2620 8746 -2425 6974 -809 4577 -6506 -705 -4123 20 -3909 -1126 3926 -89 3966 2857 4163 -3978 5118 -5040 7535 -5922 8148 -8362 3242 -5714 -212 3247 -2172 7288 433 6355 -7974 2672 -6084 SS 20240511T030434.3Z 8897.128175 132 1 50.23 2 83.00 65.70 88.82 26.58 0.00 1 0.00 1 0 17 3.637e-01 1.856e-02 3.773e-01 1.294e-02 1.281839e+00 8.081227e-03 1.590057e-02 -6.000000e+00 2.184774e-01 231.03 -2.00 4.26 -2.00 322.67 0.00e+00 -2.461475e-03 3.816953e-03 2.658540e-03 -6.000000e+00 8.707906e-03 271.82 -2.00 20.00 -2.00 322.33 0.00e+00 7.530 0.011 302.00 328.00 3 -7.4975e-01 2.7949e-02 1.1447e-01 -6.0000e+00 5.5242e-01 1.9401e+00 3.7285e-02 8.3865e-02 -6.0000e+00 5.9950e-01 -2.3507e+00 3.7839e-02 4.7541e-02 -6.0000e+00 3.4993e-01 8.9170e-01 1.9255e-02 1.7029e-02 -6.0000e+00 1.4413e-01 1.4082e-04 -1.7132e-03 3.3074e-04 2.2737e-04 -6.0000e+00 9.6480e-03 2.3502e-02 2.8154e-06 12 8 8 10 0 0 12.90 16.60 0.11 0.02350 0.01063 103 20 1 5 0 487.540 19.75 15.00 16.60 999.00 -9.0 -9.00 -36899 5230 -26888 -70326 -61130 900000 19521 -13024 39663 -111532 -1504 -62976 -100264 -49413 -18990 -16593 -11185 -30820 57672 120315 39904 38767 -27932 10745 81521 -8565 -6761 -77585 -51255 -22129 -42009 -36980 -23316 -54711 -30062 -21066 -30646 -5151 84517 83546 83171 84192 31775 45376 49828 233 -22976 18793 -14980 -14810 122681 37148 98230 42595 64206 56278 74039 44446 22331 6417 17128 6321 19275 5999 32811 8623 15010 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