File name: Pandora105s1_Helsinki_20240519_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T082425.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240519_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240519T023632.5Z 8905.108709 168 1 49.77 2 84.44 58.90 104.71 289.63 0.00 1 0.00 1 0 33 7.541e-01 6.469e-02 5.345e-01 5.070e-02 1.174783e+00 3.255700e-02 1.501572e-02 -6.000000e+00 4.609648e-01 231.90 -2.00 4.26 -2.00 322.34 0.00e+00 -1.823291e-02 1.109243e-02 1.386897e-03 -6.000000e+00 1.882584e-02 273.17 -2.00 20.00 -2.00 321.95 0.00e+00 9.068 0.019 302.00 328.00 3 -4.2832e-01 1.0485e-01 1.1855e-01 -6.0000e+00 1.1705e+00 2.5021e+00 1.1894e-01 7.3007e-02 -6.0000e+00 1.2707e+00 -2.4763e+00 8.1325e-02 3.8690e-02 -6.0000e+00 7.4158e-01 7.9881e-01 4.7338e-02 1.2918e-02 -6.0000e+00 3.0675e-01 2.2464e-05 1.1538e-03 1.3278e-03 1.6257e-04 -6.0000e+00 2.0767e-02 2.3276e-02 -6.8463e-06 12 8 8 10 0 0 21.95 16.91 0.48 0.02328 0.03195 27 5 1 5 0 1843.020 20.04 15.00 16.91 999.00 -9.0 -9.00 -643 -6309 900000 900000 181731 -16010 900000 72917 164054 95968 273553 21875 286420 -45200 900000 7809 900000 615 21503 60186 -20937 23605 86509 114980 -37652 156143 -19443 41598 -112887 900000 -14391 78100 -16795 54665 -32667 199744 168706 -36630 31720 166280 123054 64550 112953 -53647 301463 -89184 23409 -39406 900000 7161 103280 136598 43968 88327 40299 900000 240861 77341 -18431 13920 -59158 80745 -21245 112516 -13956 62489 -1831 61418 46672 100372 16390 80398 10941 71525 -28105 -8584 -12623 -6547 -23842 -4349 28245 48014 73147 1091 42824 3816 3779 -11794 -12306 -4328 -21423 37106 -11272 23761 -8642 10642 5363 5676 330 11478 1098 4697 2307 7197 6858 1319 17722 -8528 -734 -4172 2935 -3943 4244 -7044 2388 -6177 743 -6927 697 686 -543 6347 -2976 7885 3925 1743 -5402 5972 -7536 5234 -2315 1702 216 2522 -2448 14 659 2477 -801 -2136 769 -222 -61 -597 900000 900000 8970 -922 900000 3599 8097 4737 13502 1276 14137 -5577 900000 701 900000 58 1544 2971 -1879 1271 4270 5675 -4899 7707 -1745 2053 -19248 900000 -1162 3855 -1658 2698 -3078 9859 8327 -4602 2420 8207 6074 4055 5575 -9147 14880 -18808 1576 -5128 900000 675 5098 6742 4123 5668 4376 900000 11888 5344 -2911 1443 -11680 4782 -3985 6109 -2686 5552 -325 6366 6450 8917 3479 8730 2160 6708 -6104 -1398 -2181 -1196 -6237 -1116 6134 9717 12275 393 10569 1432 1436 -5123 -5102 -1538 -8565 8242 -4340 7506 -4521 5410 3362 4034 258 7592 710 2527 1207 3837 3893 827 10147 -7156 -674 -4695 3476 -5332 5384 -9840 2946 -8324 975 -10359 994 945 -700 7206 -3643 8524 4321 1893 -6586 7781 -13576 9611 -5095 3915 552 6873 -7480 43 1999 7396 -2364 -5863 1860 -507 SS 20240519T024735.9Z 8905.116388 171 1 49.88 2 83.25 61.22 105.99 292.07 0.00 1 0.00 1 0 25 5.589e-01 2.457e-02 4.234e-01 1.774e-02 1.084403e+00 1.112134e-02 1.376149e-02 -6.000000e+00 3.348464e-01 231.90 -2.00 4.26 -2.00 322.54 0.00e+00 -7.525007e-03 4.801243e-03 1.879455e-03 -6.000000e+00 1.408182e-02 273.17 -2.00 20.00 -2.00 322.18 0.00e+00 7.761 0.012 302.00 328.00 3 -1.2536e-01 3.7583e-02 1.0620e-01 -6.0000e+00 8.4966e-01 1.6673e+00 4.6988e-02 7.1165e-02 -6.0000e+00 9.2175e-01 -2.1116e+00 4.3074e-02 3.9572e-02 -6.0000e+00 5.3883e-01 8.0694e-01 2.2642e-02 1.3744e-02 -6.0000e+00 2.2363e-01 8.4589e-05 -5.8794e-04 4.9176e-04 1.7772e-04 -6.0000e+00 1.4928e-02 2.4222e-02 2.0529e-05 12 8 8 10 0 0 -8.39 16.91 0.27 0.02422 0.01980 62 12 1 5 0 804.400 20.04 14.97 16.91 999.00 -9.0 -9.00 195378 165790 900000 27725 -105098 139251 -55270 121749 -72357 900000 -95744 14900 -22761 191046 25244 65261 2627 54728 142993 -30286 49958 -47986 25853 -64196 107252 -27874 38111 -54591 172259 8912 900000 -21923 85077 -32074 17340 -19288 5135 50765 27800 121337 91747 145160 -12998 186183 -6124 127336 5242 62526 137605 30158 5824 34012 55791 53657 28965 43208 29254 18166 46036 -16205 57384 37307 49122 13920 46815 10069 15942 16382 30978 24992 15816 41417 17212 12117 -538 -4873 15405 6693 -13104 -5379 -1022 8466 -98 3859 2821 4547 4386 -12385 10799 1859 -3986 -5649 -1590 -5541 1605 -7787 192 -2227 1631 -3306 -2940 -1467 -2966 -4557 -3562 2997 -4954 -813 -3179 814 -2763 1231 388 -446 -1943 21 41 1414 -459 978 577 -185 2178 626 4172 662 3698 -338 1802 305 1591 -1636 601 -1326 92 -323 365 1435 203 495 -1616 -1892 3378 2867 900000 523 -5604 2408 -1911 2105 -3299 900000 -5418 304 -787 3304 714 1334 103 1290 2473 -1523 1021 -2414 650 -4339 1855 -1315 839 -2660 2979 238 900000 -1103 1765 -1866 600 -849 213 1580 1298 2518 2697 2510 -960 3219 -413 2202 308 2162 2379 1669 463 2235 3184 3340 2404 3213 2479 1602 2786 -1709 2977 2645 3568 1613 3967 1219 1902 2125 4018 3846 2790 5586 2738 1802 -79 -683 1785 949 -2742 -1256 -269 2313 -31 1248 971 1604 1593 -5290 3529 624 -1344 -1915 -544 -2280 738 -4673 125 -1710 1272 -2601 -2059 -880 -1708 -2853 -2365 1954 -3761 -662 -3111 903 -3593 1639 529 -603 -2584 27 56 2018 -694 1428 790 -241 2720 781 4920 781 4342 -487 3048 603 3441 -3945 1538 -3757 274 -987 1112 4342 598 1339 -4060 -4427 SS 20240519T025858.4Z 8905.124287 174 1 50.18 2 82.00 63.60 107.28 294.61 0.00 1 0.00 1 0 25 5.430e-01 1.808e-02 3.271e-01 7.785e-03 9.947908e-01 4.628416e-03 1.255608e-02 -6.000000e+00 3.252631e-01 231.90 -2.00 4.26 -2.00 322.27 0.00e+00 2.365500e-03 2.112139e-03 1.820574e-03 -6.000000e+00 1.287645e-02 273.17 -2.00 20.00 -2.00 321.93 0.00e+00 6.715 0.008 302.00 328.00 3 -1.3693e-01 1.5491e-02 9.4920e-02 -6.0000e+00 8.2459e-01 8.8744e-01 2.3674e-02 6.7376e-02 -6.0000e+00 8.9392e-01 -1.1739e+00 2.7196e-02 3.8674e-02 -6.0000e+00 5.2300e-01 4.6698e-01 1.2848e-02 1.3474e-02 -6.0000e+00 2.1566e-01 2.7443e-04 -1.3149e-03 2.1326e-04 1.6006e-04 -6.0000e+00 1.4376e-02 2.3711e-02 2.3497e-05 12 8 8 10 0 0 9.39 16.91 0.05 0.02371 0.01383 123 24 1 5 0 407.840 20.04 14.98 16.91 999.00 -9.0 -9.00 -128262 -132930 -109334 -197346 -124942 -197667 -122148 -262861 -123389 -140985 -21115 -179669 -126028 -96344 10421 -94663 -8626 -76906 -55378 -3862 -70409 -12431 -92236 41212 -67390 -17324 -52285 -14741 -80356 -14547 -46670 -15784 7976 8052 -22806 -17006 10707 15587 55192 14569 39510 12677 73075 23640 47503 -12954 23117 16763 15847 15393 19277 34164 41927 31109 36764 41644 19677 47328 14744 25357 -3670 24705 10399 28972 10098 20362 10745 22732 12885 11036 17009 13257 15821 4508 13069 -938 2042 -5095 2914 226 3721 -1700 1709 -1183 -733 3717 2824 4066 3466 4314 -857 1041 -4541 1783 -3384 -1185 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