File name: Pandora105s1_Helsinki_20240520_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T082335.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240520_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240520T030514.5Z 8906.128641 186 1 49.89 2 81.12 64.80 108.45 284.37 0.00 1 0.00 1 0 17 5.776e-01 2.006e-02 3.846e-01 1.181e-02 9.733380e-01 7.099963e-03 1.234954e-02 -6.000000e+00 3.508727e-01 232.00 -2.00 4.26 -2.00 322.19 0.00e+00 5.122921e-03 3.183986e-03 1.702006e-03 -6.000000e+00 1.437650e-02 273.34 -2.00 20.00 -2.00 321.83 0.00e+00 6.128 0.006 302.00 328.00 3 1.1657e+00 2.3394e-02 8.9726e-02 -6.0000e+00 8.9074e-01 8.7745e-01 3.4396e-02 6.5574e-02 -6.0000e+00 9.6722e-01 -1.1286e+00 3.9332e-02 3.7214e-02 -6.0000e+00 5.6124e-01 4.4156e-01 1.8789e-02 1.2812e-02 -6.0000e+00 2.3267e-01 1.2725e-04 -6.3431e-04 3.2354e-04 1.5287e-04 -6.0000e+00 1.5869e-02 2.3365e-02 5.4888e-05 12 8 8 10 0 0 48.79 17.03 0.19 0.02336 0.01860 50 10 1 5 0 997.480 20.14 15.00 17.03 999.00 -9.0 -9.00 -208471 900000 -82287 900000 -233850 900000 -105721 900000 -162204 -34768 -141212 -168884 -141392 -125297 -62118 -2377 -36485 -20989 -60617 -65001 235149 -18067 900000 -58816 4290 -64348 11237 -102558 -107097 -61726 31695 21646 92526 -5950 -18706 900000 -68522 6229 40982 253711 37925 35658 11807 16439 28420 50791 47711 -5904 40016 -22060 24516 1628 28083 23050 28358 9460 30136 3777 30374 21993 10205 7294 15590 10935 11030 17632 13042 7094 6612 12317 9991 14584 9358 17358 601 10048 -14150 5230 -1524 3655 2659 3902 996 1866 1956 3500 4960 -807 4022 -2657 4073 -2196 -3030 -34 -1209 -3762 -1564 -137 123 552 -3427 -2251 -5437 2721 -4610 -2011 -4677 -1832 -2088 -973 -1518 -423 451 196 -664 -1041 -1319 -141 83 402 2869 566 1762 1414 2625 494 1376 945 2282 873 1245 -613 -476 203 -514 236 -499 1271 88 488 -1277 -1935 -4794 900000 -946 900000 -6111 900000 -1216 900000 -2374 -400 -1771 -3354 -2808 -2750 -909 -27 -534 -285 -1267 -1427 2704 -227 900000 -1230 54 -1480 129 -3216 -3582 -1549 437 398 1064 -164 -538 900000 -3295 186 1037 2917 1221 1230 529 699 1078 1577 1591 -360 1656 -1877 1494 138 2002 1855 2250 935 2426 378 2200 1694 939 788 1811 1509 1560 2311 1860 1166 1270 2521 2206 3069 1948 3014 109 1525 -2766 944 -358 984 847 1395 393 768 852 1577 2281 -394 1822 -1213 1639 -917 -1317 -16 -702 -2656 -1268 -114 108 508 -2940 -1664 -3926 1934 -3769 -1674 -4275 -1799 -2377 -1274 -2026 -587 622 263 -952 -1494 -1980 -221 136 647 4229 808 2425 1908 3420 633 1775 1421 4009 1774 2512 -1346 -1122 512 -1391 646 -1387 3491 235 1211 -3249 -4618 SS 20240520T032146.8Z 8906.140125 191 1 50.18 2 79.23 68.25 110.41 288.02 0.00 1 0.00 1 0 17 7.016e-01 1.125e-02 2.828e-01 4.948e-03 8.365750e-01 2.871721e-03 1.074607e-02 -6.000000e+00 4.206373e-01 232.00 -2.00 4.26 -2.00 321.84 0.00e+00 3.582689e-03 1.233741e-03 1.263835e-03 -6.000000e+00 1.754794e-02 273.34 -2.00 20.00 -2.00 321.50 0.00e+00 5.151 0.003 302.00 328.00 3 1.0662e+00 9.1772e-03 7.6029e-02 -6.0000e+00 1.0663e+00 2.3190e-01 1.4340e-02 5.6756e-02 -6.0000e+00 1.1558e+00 -3.2031e-01 1.7555e-02 3.2899e-02 -6.0000e+00 6.7629e-01 1.2047e-01 8.3082e-03 1.1338e-02 -6.0000e+00 2.7942e-01 4.5495e-04 3.8958e-05 1.3907e-04 1.1755e-04 -6.0000e+00 1.8698e-02 2.2802e-02 6.0577e-05 12 8 8 10 0 0 73.77 17.03 0.09 0.02280 0.02310 111 22 1 5 0 451.990 20.14 15.00 17.03 999.00 -9.0 -9.00 -319545 -203113 -155525 -246796 -216262 -261656 -249948 -139220 -175868 -211570 900000 -154257 36230 -169028 -56933 -137653 -46180 -51643 -95934 -90538 -65141 -83160 -90344 -95441 -82663 -48239 -80179 -1611 -58352 25077 -62530 43461 -21239 -19218 -30619 -24844 -36087 -9122 -443 -5193 19597 1468 13703 -5123 9395 -8192 10123 -399 11406 1689 9776 15657 8247 15994 7002 15808 3461 7871 3461 3695 2436 1800 2487 10390 4741 8925 1606 1551 4110 5239 5934 5588 6758 2712 5750 -482 -892 -4053 231 -1090 1806 -2188 -1060 -2445 -248 -892 -282 1892 1205 1973 -487 -223 -2526 -955 -2063 -1081 -767 1110 -260 347 -751 -1389 -2111 95 -1514 -1196 -487 -1466 -427 -213 363 237 499 -366 -439 -975 288 -51 431 319 -169 653 754 571 1066 390 -736 1347 827 758 -68 110 -606 320 -110 -367 -47 444 238 -43 -512 -810 -4624 -1069 -750 -2056 -1233 -2410 -2302 -672 -1003 -1856 900000 -1116 175 -2298 -357 -2113 -356 -473 -1481 -1398 -786 -1203 -1525 -1888 -1555 -675 -1547 -14 -929 206 -1568 461 -502 -454 -768 -611 -1149 -273 -15 -215 700 67 582 -267 435 -470 508 -24 655 119 731 1239 776 1512 763 1655 417 885 392 417 300 255 408 1774 874 1554 311 326 985 1410 1686 1606 1829 702 1295 -107 -198 -1028 67 -387 726 -1034 -530 -1311 -139 -531 -174 1147 718 1102 -262 -115 -1362 -569 -1462 -887 -663 1069 -265 336 -728 -1196 -1758 83 -1439 -1183 -509 -1691 -505 -288 534 361 750 -533 -611 -1354 411 -78 682 502 -254 927 1146 845 1528 539 -1039 2127 1389 1432 -140 239 -1415 798 -293 -1004 -129 1226 638 -107 -1201 -1798 SS 20240520T032739.9Z 8906.144212 194 1 50.16 2 78.55 69.47 111.10 289.33 0.00 1 0.00 1 0 25 6.704e-01 8.526e-03 2.338e-01 3.755e-03 8.074758e-01 2.184334e-03 1.048820e-02 -6.000000e+00 4.027840e-01 232.00 -2.00 4.26 -2.00 321.72 0.00e+00 2.411183e-03 9.137058e-04 1.163253e-03 -6.000000e+00 1.620078e-02 273.35 -2.00 20.00 -2.00 321.38 0.00e+00 4.869 0.003 302.00 328.00 3 9.3803e-01 6.9294e-03 7.2753e-02 -6.0000e+00 1.0234e+00 1.4417e-01 1.0668e-02 5.4937e-02 -6.0000e+00 1.1098e+00 -1.7138e-01 1.3164e-02 3.1801e-02 -6.0000e+00 6.4730e-01 5.6042e-02 6.2839e-03 1.0891e-02 -6.0000e+00 2.6647e-01 6.9363e-04 1.8820e-06 1.0769e-04 1.1699e-04 -6.0000e+00 1.7772e-02 2.2453e-02 7.5091e-05 11 8 0 10 0 0 94.86 17.04 0.01 0.02245 0.02247 148 29 1 5 0 338.830 20.14 15.01 17.04 999.00 -9.0 -9.00 -268146 -220256 -205849 -264547 -228388 -277972 -107109 -225568 900000 -179032 -191041 -178909 -62182 -147211 -72956 -85722 -55499 -38626 -39189 -52606 -76028 -42365 -62890 -28652 -26649 -33532 -53976 -21580 -76785 -25145 -34611 -6778 -36266 -25566 -24710 -26195 -2299 -21013 -15707 -8512 92 1832 7358 1235 6886 -4427 -334 83 7108 -4056 8266 1929 3727 3634 3959 3511 6564 5701 -1636 4286 325 7324 1701 6616 2919 3520 230 254 2116 3872 3560 2341 3103 2940 1979 1211 -2059 -2305 249 -574 -1549 -854 -2208 -1696 -770 -491 745 1334 903 1426 518 930 -1342 -305 -321 -829 130 474 303 497 -306 -1769 -974 -291 -1246 -1014 -1433 -1211 -294 135 352 120 366 -302 -648 -25 -410 -29 373 129 -459 86 508 562 1334 630 -422 1022 734 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