File name: Pandora105s1_Helsinki_20240524_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T083158.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240524_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240524 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240524T022751.2Z 8910.102676 164 1 50.76 2 84.51 56.55 98.80 229.37 0.00 1 0.00 1 0 25 7.800e-01 7.631e-02 4.650e-01 5.562e-02 1.225290e+00 3.663006e-02 1.574640e-02 -6.000000e+00 4.941585e-01 232.37 -2.00 4.26 -2.00 322.16 0.00e+00 -5.608045e-03 9.823625e-03 9.416021e-04 -6.000000e+00 2.180585e-02 274.01 -2.00 20.00 -2.00 321.73 0.00e+00 9.154 0.020 302.00 328.00 3 -6.0605e-01 1.0987e-01 1.2004e-01 -6.0000e+00 1.2577e+00 2.9813e+00 1.2564e-01 7.3823e-02 -6.0000e+00 1.3699e+00 -2.7617e+00 8.5099e-02 3.8953e-02 -6.0000e+00 7.9117e-01 8.5904e-01 4.9946e-02 1.2856e-02 -6.0000e+00 3.2717e-01 1.8331e-05 1.7712e-03 1.3877e-03 1.3759e-04 -6.0000e+00 2.2514e-02 2.4158e-02 5.1504e-05 12 9 8 11 8 0 40.08 17.12 0.31 0.02416 0.03747 24 5 1 5 0 2114.590 20.25 15.00 17.12 999.00 -9.0 -9.00 900000 46851 900000 64763 900000 900000 900000 192609 5020 900000 -39917 900000 78985 287152 46515 900000 51833 900000 20536 115758 -50036 63082 109716 900000 95436 -16460 -17589 -81362 200796 18828 900000 6315 70049 7914 -6560 79958 900000 -62745 900000 30180 -4495 81015 64889 181175 -44654 334005 -22297 3464 -67109 350328 39366 900000 7634 900000 16960 26725 114606 15631 43232 -23390 900000 -66570 300034 -27442 50229 -17866 900000 19415 103830 84180 140138 41653 12142 40095 -8645 6840 -50803 121287 -19264 38916 9814 33393 39340 63474 33430 27517 804 19221 718 10846 2924 -10310 14465 2646 10565 -8320 18479 -12057 2035 -11752 5690 -1009 7797 10304 7713 -7677 -2139 -2302 -816 6924 -2992 7283 -9005 11261 -7234 4053 2573 4921 -7061 3577 -2112 12669 -5218 1053 557 -9493 6704 -3816 2407 -4624 4561 -4375 2573 -2177 3299 -4582 3900 593 573 -1086 804 439 900000 6049 900000 4892 900000 900000 900000 10409 502 900000 -5761 900000 4570 15519 4735 900000 5339 900000 2624 6256 -9968 3779 5930 900000 5158 -2107 -2004 -14919 10852 1390 900000 716 4487 850 -700 4321 900000 -13646 900000 3343 -708 5487 4839 9791 -8223 18051 -3178 396 -16119 18933 4013 900000 1212 900000 2599 3730 6516 2123 3975 -3744 900000 -18393 16215 -6571 5676 -3899 900000 3366 8934 9578 9391 6958 2437 5303 -1559 978 -13122 6643 -5030 6863 2666 8062 9567 12548 9200 8112 312 6044 257 3286 905 -3622 4248 1026 4508 -5086 10155 -10100 1535 -9592 3451 -565 3770 5166 4185 -5061 -1436 -1729 -717 6682 -3603 8424 -12310 12520 -9408 4734 3189 6275 -10393 4534 -2601 12828 -6200 1157 602 -10983 7058 -5330 3837 -9071 9097 -10403 6246 -6047 9222 -14068 11055 1737 1602 -2858 1876 960 SS 20240524T023858.7Z 8910.110401 167 1 50.35 2 83.34 58.88 99.84 231.56 0.00 1 0.00 1 0 17 4.764e-01 2.479e-02 4.856e-01 2.054e-02 1.064675e+00 1.277735e-02 1.336464e-02 -6.000000e+00 2.875401e-01 232.37 -2.00 4.26 -2.00 322.58 0.00e+00 -3.967307e-03 5.615998e-03 1.912996e-03 -6.000000e+00 1.132250e-02 274.01 -2.00 20.00 -2.00 322.22 0.00e+00 7.847 0.012 302.00 328.00 3 6.4671e-02 4.3710e-02 1.0608e-01 -6.0000e+00 7.2897e-01 1.5984e+00 5.4711e-02 6.9810e-02 -6.0000e+00 7.8915e-01 -2.0644e+00 5.0081e-02 3.8589e-02 -6.0000e+00 4.6290e-01 7.8883e-01 2.6095e-02 1.3417e-02 -6.0000e+00 1.9142e-01 6.8212e-05 1.6854e-04 5.7477e-04 1.7393e-04 -6.0000e+00 1.2619e-02 2.4336e-02 6.8196e-06 12 8 8 10 0 0 8.19 17.13 0.37 0.02434 0.02560 54 11 1 5 0 932.200 20.25 15.01 17.13 999.00 -9.0 -9.00 -22901 81979 11929 494 -111019 -34519 -14555 -83351 38144 231294 -18444 -53778 27573 -43650 -15901 157932 80230 81676 78686 53065 34465 4328 -64634 29107 -73658 -25057 10441 32463 -71388 75530 25494 14481 -5518 128046 100674 113789 13134 98898 115745 21301 95454 12535 130227 18408 900000 98632 34950 -27432 40659 -2384 40966 21088 50223 75310 47005 94921 13017 24665 8219 -18649 -46046 20586 -11065 64926 -137 39465 6309 52650 10136 39159 23919 35992 18555 22506 1490 -8534 2149 8187 4544 4309 5382 -10641 15090 7721 8519 7398 654 -2461 9933 652 4101 4858 -4082 -819 -8053 -3114 -4399 898 -2113 1378 -4523 -4185 -4294 808 724 -239 -1050 -4402 -3064 -573 1485 -2351 1145 -2082 -484 -2310 -869 161 -529 -240 2736 2628 949 2011 1984 535 -955 1789 311 3133 -293 331 -2085 282 305 916 27 900 561 -861 -528 -2454 -764 1642 282 11 -5558 -817 -291 -3490 764 4631 -403 -1860 552 -1907 -608 3162 1607 1635 1576 1063 753 118 -3647 689 -4961 -1003 266 650 -3509 1512 650 474 -241 2564 2016 2279 473 1980 2318 1109 2485 753 2608 958 900000 2173 1470 -2252 1791 -177 2215 1520 2916 3619 3106 3991 1225 1926 691 -1942 -6546 1690 -1440 4420 -18 3477 809 4639 1583 5097 3784 4973 2824 2929 209 -1213 280 1131 792 906 1315 -3473 4079 2365 2729 2504 244 -941 3242 219 1265 1469 -1422 -320 -4063 -1777 -2995 665 -1697 1024 -3179 -2556 -2502 480 461 -161 -769 -3737 -3012 -647 1849 -3230 1539 -2834 -629 -3072 -1194 233 -800 -355 3670 3347 1206 2488 2408 637 -1191 2565 542 6105 -653 790 -5529 793 915 2785 84 2767 1662 -2388 -1330 -5881 SS 20240524T025026.4Z 8910.118361 170 1 50.00 2 82.11 61.28 100.95 233.81 0.00 1 0.00 1 0 25 6.614e-01 1.995e-02 3.880e-01 9.122e-03 1.001672e+00 5.461863e-03 1.276444e-02 -6.000000e+00 3.969041e-01 232.37 -2.00 4.26 -2.00 322.34 0.00e+00 3.193651e-03 2.532090e-03 1.814519e-03 -6.000000e+00 1.568611e-02 274.01 -2.00 20.00 -2.00 321.99 0.00e+00 6.795 0.008 302.00 328.00 3 -4.3414e-03 1.8696e-02 9.6110e-02 -6.0000e+00 1.0074e+00 9.2764e-01 2.7746e-02 6.7915e-02 -6.0000e+00 1.0917e+00 -1.2585e+00 3.1124e-02 3.8635e-02 -6.0000e+00 6.3845e-01 5.0576e-01 1.4757e-02 1.3438e-02 -6.0000e+00 2.6301e-01 2.2249e-04 -1.3298e-03 2.5546e-04 1.6281e-04 -6.0000e+00 1.7515e-02 2.4068e-02 3.4082e-05 12 8 8 10 0 0 25.65 17.13 0.05 0.02407 0.01408 107 21 1 5 0 467.190 20.25 15.00 17.13 999.00 -9.0 -9.00 -97182 -179678 -18011 -145662 -160034 -236794 -112338 -204118 -117279 -192314 -103358 -141005 -77044 -90027 116374 -67847 -71139 -46144 -64639 -85457 -104650 251370 -27813 -8023 -104820 59155 -97884 188881 -104851 80087 159876 53193 -2798 46870 91030 -15908 32138 -16860 84552 -19033 46022 -10542 131764 38913 41688 24779 82155 13459 67446 41258 61399 27751 42855 60298 25796 53390 26129 21451 15347 38590 23797 26475 6418 31672 20901 30543 18492 10580 16499 13097 13551 19595 18258 6125 2546 -4999 5777 -3059 12217 2604 8615 6266 1712 1193 1621 2235 1650 3861 -2085 2730 -4458 69 -5192 -970 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