File name: Pandora105s1_Helsinki_20240528_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T083159.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240528_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240528T025044.9Z 8914.118576 126 1 50.27 2 81.52 60.93 85.40 186.19 0.00 1 0.00 1 0 33 6.101e-01 2.609e-02 3.905e-01 1.614e-02 9.470377e-01 9.907896e-03 1.216458e-02 -6.000000e+00 3.713019e-01 232.74 -2.00 4.26 -2.00 322.25 0.00e+00 6.861640e-03 4.297920e-03 1.556644e-03 -6.000000e+00 1.594916e-02 274.69 -2.00 20.00 -2.00 321.89 0.00e+00 6.381 0.007 302.00 328.00 3 1.3052e+00 3.2544e-02 9.0030e-02 -6.0000e+00 9.4559e-01 1.1120e+00 4.2409e-02 6.2206e-02 -6.0000e+00 1.0272e+00 -1.4189e+00 4.2592e-02 3.3669e-02 -6.0000e+00 5.9635e-01 5.4620e-01 2.1231e-02 1.1363e-02 -6.0000e+00 2.4406e-01 8.6471e-05 -1.4338e-03 4.6251e-04 1.4609e-04 -6.0000e+00 1.6748e-02 2.5886e-02 3.0288e-05 12 8 8 10 0 0 5.57 17.27 0.31 0.02589 0.01511 41 8 1 5 0 1225.930 20.35 15.01 17.27 999.00 -9.0 -9.00 -43024 -60396 -63880 -150045 900000 32259 -168889 900000 -112558 900000 -150072 44717 -94027 232991 -12806 900000 -91723 85987 -53599 211165 -65938 182240 -36656 -30073 -5466 -14901 900000 -8291 99699 -25915 900000 -41861 326400 -26050 50378 -27563 2722 -173 68641 -2349 105561 98012 67699 47056 29554 75211 955 61551 105356 82799 44806 84956 36274 44929 44922 18313 55159 40937 38952 27147 47380 22507 20943 20000 42261 17010 35608 -6568 20572 11051 8545 17378 24163 -84 -7254 -7515 -3509 6044 3198 7236 1143 12656 -2582 3751 -3365 6047 -2890 3747 2202 912 2147 -6523 -2339 -8282 -1065 -7204 -1312 -2690 284 -1107 -2685 -3021 284 -7496 554 -5166 -1749 -437 -2645 558 -1131 -180 -1980 399 -2852 1729 -942 -108 -59 3816 1132 1701 2897 3074 428 574 -14 -29 1606 423 2606 128 11 -1073 428 -697 729 368 -157 -87 -275 -2504 -676 -1112 -1240 -5863 900000 507 -6481 900000 -2602 900000 -4996 703 -2777 3663 -262 900000 -4962 1352 -2196 3319 -2827 2865 -1100 -901 -129 -381 900000 -179 1567 -777 900000 -2180 5131 -1280 1073 -1219 98 -7 1810 -137 2302 2386 2266 1909 1424 2326 64 2372 2778 2981 2658 3705 2777 3349 3440 1867 3860 3135 2864 2189 3291 2271 2485 2698 4650 2363 4225 -1279 3526 2342 1950 3613 4399 -18 -1442 -1368 -616 1073 705 1846 362 4043 -1027 1470 -1500 2576 -1394 1697 986 390 852 -2739 -967 -4116 -587 -4993 -1005 -2322 251 -985 -2179 -2149 185 -5633 411 -4247 -1484 -404 -2881 684 -1521 -252 -2919 558 -3962 2287 -1335 -161 -93 5686 1634 2314 3805 3941 551 711 -18 -42 2728 829 5471 295 27 -2801 1175 -1976 2053 1048 -436 -231 -672 -5846 SS 20240528T030153.6Z 8914.126315 129 1 50.05 2 80.29 63.24 85.54 188.64 0.00 1 0.00 1 0 25 7.013e-01 1.581e-02 3.111e-01 7.345e-03 8.738024e-01 4.302502e-03 1.119271e-02 -6.000000e+00 4.223564e-01 232.74 -2.00 4.26 -2.00 322.00 0.00e+00 2.055028e-03 1.896848e-03 1.391120e-03 -6.000000e+00 1.691514e-02 274.69 -2.00 20.00 -2.00 321.66 0.00e+00 5.659 0.005 302.00 328.00 3 1.0771e+00 1.4038e-02 8.1640e-02 -6.0000e+00 1.0722e+00 4.1384e-01 2.1595e-02 5.9637e-02 -6.0000e+00 1.1620e+00 -5.8867e-01 2.5661e-02 3.4390e-02 -6.0000e+00 6.7838e-01 2.3004e-01 1.2129e-02 1.1840e-02 -6.0000e+00 2.7920e-01 2.6876e-04 -5.8673e-04 2.0696e-04 1.2615e-04 -6.0000e+00 1.8673e-02 2.4968e-02 3.8035e-05 12 8 8 10 0 0 12.99 17.27 0.07 0.02497 0.02056 86 17 1 5 0 581.910 20.35 15.00 17.27 999.00 -9.0 -9.00 -196836 -238468 -203059 -153938 900000 -258704 -214444 -256403 -99045 -250356 -207086 -206165 -160483 -174688 -105470 67184 -30936 -112315 -95485 -71167 -80593 -41047 -33438 -40189 -71832 -81467 7393 -64878 -92313 -42645 -26883 -24687 -6933 60472 17799 -39633 83963 -46261 5580 4983 19894 16516 13146 7237 25881 -7887 27708 -3167 1916 40791 26257 24320 20492 3973 10556 24121 11824 21723 4981 13215 8504 17828 10006 9516 10687 10203 9638 10104 8711 10155 7732 6765 6961 4120 9169 -3383 3774 -2671 3806 -1951 870 -1551 -2298 349 -2458 1107 -506 1771 1292 3314 269 3153 -4104 -1437 -4128 -703 -705 1408 -631 -491 -1793 -2588 -2925 -799 -1753 -3103 -1694 -1691 -1406 -756 819 -344 884 -1097 -943 -685 73 707 406 315 1256 972 1610 964 1013 1025 -185 1102 1026 898 307 -210 -551 -160 50 -99 233 745 -213 -101 -568 -1462 -1409 -2949 -1851 -1102 900000 -3537 -2094 -4340 -709 -4726 -2696 -3221 -2089 -3411 -1304 481 -266 -2193 -1678 -1121 -1385 -470 -383 -547 -1440 -1867 69 -1208 -2314 -763 -520 -566 -154 693 293 -1192 842 -2087 184 193 727 662 565 332 1001 -441 1131 -188 117 1869 1598 1689 1629 404 1058 2211 1245 2007 521 1259 907 1979 1397 1506 1706 1615 1587 1801 1840 2400 1988 1768 1725 962 1819 -700 730 -610 981 -640 324 -671 -1073 168 -1297 595 -287 989 708 1680 132 1461 -2090 -803 -2796 -540 -574 1277 -613 -456 -1669 -2141 -2325 -668 -1583 -2969 -1705 -1866 -1609 -987 1161 -514 1296 -1583 -1300 -938 103 1053 636 491 1836 1491 2395 1406 1440 1398 -258 1742 1724 1708 637 -467 -1310 -408 136 -275 654 2095 -587 -259 -1354 -3308 SS 20240528T031111.6Z 8914.132773 134 1 50.05 2 79.25 65.17 85.71 190.69 0.00 1 0.00 1 0 25 6.464e-01 1.073e-02 2.540e-01 4.521e-03 8.111339e-01 2.620060e-03 1.048580e-02 -6.000000e+00 3.893071e-01 232.74 -2.00 4.26 -2.00 321.80 0.00e+00 5.602284e-03 1.107069e-03 1.169387e-03 -6.000000e+00 1.562753e-02 274.69 -2.00 20.00 -2.00 321.46 0.00e+00 5.160 0.003 302.00 328.00 3 9.1273e-01 8.2689e-03 7.4883e-02 -6.0000e+00 9.9091e-01 2.1795e-01 1.2790e-02 5.4987e-02 -6.0000e+00 1.0740e+00 -3.1907e-01 1.5590e-02 3.1495e-02 -6.0000e+00 6.2614e-01 1.2232e-01 7.4025e-03 1.0721e-02 -6.0000e+00 2.5730e-01 5.4462e-04 -3.2757e-04 1.2742e-04 1.0795e-04 -6.0000e+00 1.7145e-02 2.4604e-02 6.2085e-05 12 8 8 10 0 0 0.33 17.28 0.05 0.02460 0.02214 133 26 1 5 0 376.250 20.35 15.00 17.28 999.00 -9.0 -9.00 -207868 -258133 -234963 -269628 -72715 -203367 -152512 -227116 900000 -214036 -105039 -112764 -133741 -138669 -126698 -130690 -112449 -70233 -65900 -41589 -84263 -27952 -59861 22044 -95477 -21725 -28708 -14027 -53079 -21498 -37981 -51521 -18344 -19916 -48582 -40815 -7826 -14708 2885 -9584 4874 2060 19812 -2315 7611 17174 12219 3397 9281 4406 8794 15158 3308 9937 916 9021 1520 5501 1228 7948 2223 10079 3261 12194 8784 5995 3617 -425 2401 3709 7447 2190 4863 1321 1492 2038 0 -2078 287 -1702 -449 318 -2407 -1361 -344 80 314 1933 1102 2043 707 -134 -3071 -1572 -1680 -942 -468 684 144 -111 -446 -1819 -1650 -1013 -205 -2115 -1404 -1846 -280 212 899 291 20 -437 -495 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