File name: Pandora105s1_Helsinki_20240604_L2Fit_fwvt1c3d20210617p1-8.txt File generation date: 20240927T084455.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240604_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 1622 1772 Nominal wavelengths inside fitting window [nm]: 492.0899 492.2105 492.3310 492.4516 492.5721 492.6927 492.8132 492.9337 493.0542 493.1746 493.2951 493.4155 493.5359 493.6563 493.7767 493.8970 494.0174 494.1377 494.2580 494.3783 494.4986 494.6189 494.7391 494.8593 494.9795 495.0997 495.2199 495.3401 495.4602 495.5803 495.7005 495.8205 495.9406 496.0607 496.1807 496.3007 496.4208 496.5407 496.6607 496.7807 496.9006 497.0205 497.1405 497.2603 497.3802 497.5001 497.6199 497.7397 497.8595 497.9793 498.0991 498.2189 498.3386 498.4583 498.5780 498.6977 498.8174 498.9370 499.0567 499.1763 499.2959 499.4155 499.5351 499.6546 499.7742 499.8937 500.0132 500.1327 500.2521 500.3716 500.4910 500.6104 500.7298 500.8492 500.9686 501.0879 501.2073 501.3266 501.4459 501.5652 501.6844 501.8037 501.9229 502.0421 502.1613 502.2805 502.3997 502.5188 502.6380 502.7571 502.8762 502.9953 503.1143 503.2334 503.3524 503.4714 503.5904 503.7094 503.8284 503.9473 504.0662 504.1852 504.3041 504.4229 504.5418 504.6606 504.7795 504.8983 505.0171 505.1359 505.2546 505.3734 505.4921 505.6108 505.7295 505.8482 505.9668 506.0855 506.2041 506.3227 506.4413 506.5599 506.6784 506.7970 506.9155 507.0340 507.1525 507.2710 507.3894 507.5079 507.6263 507.7447 507.8631 507.9815 508.0998 508.2182 508.3365 508.4548 508.5731 508.6914 508.8096 508.9279 509.0461 509.1643 509.2825 509.4007 509.5188 509.6370 509.7551 509.8732 509.9913 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240604T011920.3Z 8921.055096 91 1 48.61 2 89.54 40.97 80.95 72.17 0.00 1 0.00 1 0 29 1.872e-02 1.827e-02 1.156e-03 1.147e-03 1.600118e+04 8.082597e+01 1.044816e+03 -6.000000e+00 1.032944e+03 275.85 -2.00 20.00 -2.00 505.53 0.00e+00 3.499176e-03 3.195844e-05 1.653049e-04 -6.000000e+00 5.220651e-04 275.85 -2.00 20.00 -2.00 501.24 0.00e+00 1.719880e+00 2.250288e-02 1.263853e-01 -6.000000e+00 3.796883e-01 233.38 -2.00 4.26 -2.00 502.74 0.00e+00 19.799 0.202 489.00 513.00 1 4.6108e+00 1.7164e-03 4.1495e-02 -6.0000e+00 2.8988e-02 -4.6468e-02 4.2751e-04 3.7141e-03 -6.0000e+00 7.5587e-03 9.8944e-04 6.5201e-03 1.0038e-04 1.2933e-04 -6.0000e+00 1.7990e-03 -1.5235e-01 1.1699e-03 12 9 9 12 1 1 21.98 17.25 11.02 -0.15235 -0.10712 18 4 1 4 0 2557.970 20.35 14.99 17.25 999.00 -9.0 -9.00 -6820 -5262 -3023 -1701 -281 329 1201 1016 433 -578 -1273 -1698 -2566 -2642 -3032 -2163 -800 482 1062 1298 896 1389 1398 1554 1955 1861 1793 57 -1258 -2932 -2643 -1795 316 1939 2564 1579 1424 506 446 505 896 1525 2058 2776 2845 3110 2139 1386 296 -1122 -2433 -3034 -2438 -1270 434 1833 2203 2386 2216 1851 2196 2516 2500 1985 1393 260 -92 -761 -1375 -2196 -2221 -1708 -768 -129 -165 -1118 -1988 -2528 -2636 -2177 -1819 -1299 -1280 -512 -220 -154 -433 -310 -171 136 918 2145 2635 2326 1870 1323 531 -1003 -2438 -3389 -3157 -2282 -231 721 1041 192 -801 -1468 -1300 -771 135 907 1588 2103 2716 3376 3361 2641 1335 106 -535 -322 281 1022 1386 1390 875 659 542 -3 -352 -1419 -1890 -2335 -2044 -1267 -405 296 798 667 541 363 674 1106 770 235 -1257 -2772 -3614 -3147 900000 -5781 -4543 -2653 -1519 -253 301 1107 942 401 -533 -1168 -1546 -2333 -2388 -2757 -1976 -739 453 1011 1239 860 1332 1350 1512 1908 1820 1748 56 -1206 -2787 -2501 -1715 307 1924 2572 1595 1427 507 445 505 900 1544 2106 2644 2733 2980 2056 1326 281 -1142 -2447 -3021 -2420 -1276 411 1761 2144 2326 2162 1815 2161 2489 2484 1977 1381 257 -90 -742 -1336 -2128 -2149 -1658 -749 -127 -163 -1098 -1931 -2434 -2525 -2074 -1735 -1241 -1235 -496 -215 -152 -426 -302 -165 132 893 2095 2576 2246 1756 1204 512 -960 -2329 -3235 -3031 -2073 -217 707 1049 197 -821 -1503 -1332 -799 141 954 1667 2203 2842 3558 3612 2896 1479 117 -582 -344 298 1088 1485 1499 952 720 594 -4 -386 -1548 -2055 -2555 -2262 -1322 -428 316 862 733 603 408 760 1247 870 265 -1416 -3114 -4060 -3545 900000 SQ 20240604T012237.6Z 8921.057380 95 1 50.26 2 89.27 41.68 80.56 72.83 0.00 1 0.00 1 0 57 1.372e-02 1.336e-02 6.803e-04 6.741e-04 2.007309e+04 4.930916e+01 1.346287e+03 -6.000000e+00 7.562598e+02 275.85 -2.00 20.00 -2.00 505.52 0.00e+00 3.440347e-03 1.869581e-05 1.771667e-04 -6.000000e+00 3.826897e-04 275.85 -2.00 20.00 -2.00 501.29 0.00e+00 1.737783e+00 1.315927e-02 1.426909e-01 -6.000000e+00 2.780543e-01 233.38 -2.00 4.26 -2.00 502.77 0.00e+00 19.267 0.186 489.00 513.00 1 3.7874e+00 1.0037e-03 3.9922e-02 -6.0000e+00 2.1233e-02 -6.3335e-02 2.4783e-04 4.1404e-03 -6.0000e+00 5.5408e-03 2.4118e-03 4.8367e-03 5.7329e-05 1.6495e-04 -6.0000e+00 1.3221e-03 -9.0893e-03 2.7012e-04 12 8 8 10 0 0 -15.76 17.25 7.87 -0.00909 0.02446 48 9 1 4 0 1046.810 20.35 14.99 17.25 999.00 -9.0 -9.00 -4878 -3413 -1898 -726 -159 682 959 885 290 -395 -832 -1514 -1917 -2205 -2123 -1565 -352 326 1140 852 661 879 1104 1441 1593 1642 1108 -16 -1171 -2163 -2076 -1189 214 1395 1691 1351 680 368 45 116 487 1017 1535 1870 2082 2042 1595 804 79 -874 -1768 -2461 -2021 -1040 428 1170 1568 1576 1323 1397 1572 1864 1689 1461 788 138 -400 -861 -1178 -1663 -1688 -1370 -670 -164 -312 -1019 -1505 -1908 -1926 -1566 -1034 -817 -665 -480 -5 -127 -159 -265 -182 133 832 1733 1825 1975 1589 974 345 -711 -1979 -2769 -2705 -1823 -535 514 691 181 -552 -1021 -938 -604 35 329 872 1430 1874 2501 2642 1982 1120 187 -475 -345 203 994 1115 1053 648 467 496 174 -293 -740 -1327 -1502 -1308 -967 -268 157 534 470 368 382 434 748 774 228 -702 -1869 -2592 -2399 900000 -4064 -2901 -1652 -644 -144 624 888 824 269 -364 -762 -1381 -1739 -1994 -1922 -1429 -326 309 1090 822 640 852 1076 1414 1571 1621 1096 -16 -1131 -2057 -1970 -1139 210 1404 1603 1282 644 346 42 110 461 971 1482 1827 2049 2012 1568 787 77 -834 -1661 -2291 -1876 -979 411 1152 1564 1578 1328 1401 1587 1892 1725 1492 802 139 -400 -857 -1165 -1637 -1657 -1352 -667 -165 -315 -1021 -1485 -1862 -1866 -1509 -995 -790 -648 -473 -5 -127 -158 -263 -178 131 820 1720 1817 1929 1501 888 306 -670 -1860 -2599 -2558 -1642 -504 508 707 188 -575 -1061 -976 -637 37 353 936 1527 1999 2690 2710 2083 1188 197 -492 -376 219 1073 1135 1082 672 485 517 182 -306 -763 -1366 -1555 -1371 -1033 -291 173 596 533 424 445 507 875 904 266 -815 -2162 -2994 -2783 900000 SQ 20240604T012546.9Z 8921.059571 99 1 50.24 2 89.01 42.36 80.19 73.46 0.00 1 0.00 1 0 22 1.032e-02 1.003e-02 4.478e-04 4.443e-04 2.163888e+04 3.347604e+01 1.454842e+03 -6.000000e+00 5.688305e+02 275.85 -2.00 20.00 -2.00 505.49 0.00e+00 2.979816e-03 1.240653e-05 1.627896e-04 -6.000000e+00 2.878538e-04 275.85 -2.00 20.00 -2.00 501.21 0.00e+00 1.686138e+00 8.802955e-03 1.408422e-01 -6.000000e+00 2.091448e-01 233.38 -2.00 4.26 -2.00 502.67 0.00e+00 18.669 0.169 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