File name: Pandora105s1_Helsinki_20240607_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T083843.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240607_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240607T021037.5Z 8924.090712 134 1 51.19 2 84.69 51.65 83.60 43.18 0.00 1 0.00 1 0 25 6.886e-01 8.340e-02 5.411e-01 8.164e-02 1.181658e+00 5.003353e-02 1.520682e-02 -6.000000e+00 4.181456e-01 233.66 -2.00 4.26 -2.00 321.71 0.00e+00 1.254069e-02 1.313043e-02 8.424665e-04 -6.000000e+00 1.786763e-02 276.36 -2.00 20.00 -2.00 321.32 0.00e+00 9.387 0.021 302.00 328.00 3 -4.8056e-01 1.4656e-01 1.2068e-01 -6.0000e+00 1.0640e+00 3.0644e+00 1.6381e-01 7.1365e-02 -6.0000e+00 1.1537e+00 -2.6026e+00 9.9975e-02 3.5833e-02 -6.0000e+00 6.7279e-01 7.8216e-01 5.6554e-02 1.1205e-02 -6.0000e+00 2.7611e-01 1.1923e-05 1.8182e-03 1.9338e-03 1.1688e-04 -6.0000e+00 1.9153e-02 3.0334e-02 -1.6245e-04 12 8 8 10 0 0 22.19 16.88 0.72 0.03033 0.04400 14 3 1 5 0 3655.840 20.04 14.97 16.88 18.31 30.8 953.78 18774 118044 98373 1160 138660 900000 -53359 73918 11312 900000 55017 89654 900000 122173 900000 19609 11965 1310 177674 15203 118558 -33077 64772 -50818 171388 -53362 900000 -81263 18796 48453 -13137 -38797 99234 -35103 85226 -51244 99957 900000 15654 251137 141853 71799 28151 28559 -34503 -25024 -65342 -40288 -58340 -5371 28005 181862 347182 -24903 168058 124889 54771 5907 900000 -55197 62443 -35003 207041 -3575 17409 39373 6784 -13988 -8165 37273 -4930 48923 -22567 -35672 -22736 71293 -1266 138798 -4134 75291 22662 6356 29959 18697 14216 13107 34431 33910 2362 -15085 27612 -22872 3597 10 17719 1542 19983 10989 12573 2985 -2608 -10963 -8671 -5773 11994 4829 -7879 5410 1045 10280 463 -444 -5714 7748 -6764 1056 -1835 -4735 -930 -1403 7344 -2881 12489 -4554 -3918 90 -9237 -2307 4104 559 -3171 -5105 -842 -1394 977 1857 4340 1385 -5231 3571 -518 2153 3198 9384 7820 165 11023 900000 -8181 5876 899 900000 4374 7127 900000 9712 900000 2998 2049 248 14124 2138 9425 -5664 5149 -9323 13625 -8484 900000 -14411 1494 3852 -1848 -8066 7889 -6654 6775 -9401 7946 900000 2074 19964 11277 5708 3357 3216 -7086 -4642 -18613 -9341 -17005 -996 4082 14457 27599 -6929 13360 9928 6168 978 900000 -14626 5378 -9043 16459 -853 3344 5999 1483 -4077 -2542 7901 -1600 8751 -7325 -11343 -5422 6698 -235 11034 -1123 10973 6455 2358 9129 6565 5368 5123 10949 10558 954 -6696 7500 -10152 1310 4 7982 971 12312 8372 9662 2353 -1883 -7335 -5400 -3710 6754 3039 -6055 4122 983 10352 573 -582 -7949 9187 -9007 1315 -2467 -6901 -1331 -1924 9235 -3473 13809 -5858 -4899 104 -12617 -3568 7178 1071 -6974 -12411 -2137 -3861 2790 5314 12189 4002 -15351 9573 -1310 4995 SS 20240607T022140.7Z 8924.098388 137 1 50.02 2 83.60 53.96 82.67 45.35 0.00 1 0.00 1 0 17 5.064e-01 3.489e-02 4.596e-01 3.153e-02 1.104863e+00 1.974582e-02 1.423375e-02 -6.000000e+00 3.059244e-01 233.66 -2.00 4.26 -2.00 322.43 0.00e+00 -9.538006e-03 7.522211e-03 1.479728e-03 -6.000000e+00 1.264286e-02 276.36 -2.00 20.00 -2.00 322.06 0.00e+00 8.102 0.014 302.00 328.00 3 1.7513e-01 6.4700e-02 1.0904e-01 -6.0000e+00 7.7807e-01 2.0059e+00 7.4919e-02 7.0246e-02 -6.0000e+00 8.4299e-01 -2.3024e+00 5.6516e-02 3.7044e-02 -6.0000e+00 4.9270e-01 8.3672e-01 3.2001e-02 1.2307e-02 -6.0000e+00 2.0370e-01 3.9364e-05 -8.5700e-04 8.3779e-04 1.5610e-04 -6.0000e+00 1.3674e-02 2.5907e-02 3.2643e-05 12 8 8 10 0 0 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1306 782 639 2096 7718 -3490 3509 1786 -2280 1507 -3957 -6656 900000 3399 -4569 -5705 -105 -117 -549 1917 2697 -582 349 1693 1112 900000 3510 2454 3176 3509 -1606 2227 5741 2335 -395 -572 3744 3826 -527 4331 1556 4965 3431 4340 720 3921 -4502 2961 -3140 4968 3329 2536 2589 4828 1746 3455 6305 6877 4009 4466 3735 -664 -922 -2839 4090 -31 4303 907 4676 2390 2197 4336 3728 4004 -1693 -2005 -4648 -2719 -3858 -145 -5968 3392 -1494 1296 -7994 -125 -1934 -3898 609 -4846 2748 -2266 -4945 -2015 -3456 -3652 2084 -2396 -2015 1769 2231 -8368 -390 -2335 4105 3393 2634 5186 3936 1066 3465 -549 3759 3409 -3641 3652 -1585 2196 3032 5982 -6625 -2847 -1890 2208 5069 -1188 -955 -3956 -1984 SS 20240607T023309.6Z 8924.106361 140 1 50.35 2 82.43 56.35 81.67 47.59 0.00 1 0.00 1 0 25 4.627e-01 2.381e-02 3.889e-01 1.306e-02 1.015813e+00 7.903794e-03 1.300798e-02 -6.000000e+00 2.820619e-01 233.66 -2.00 4.26 -2.00 322.34 0.00e+00 8.076331e-03 3.551153e-03 1.699052e-03 -6.000000e+00 1.108395e-02 276.36 -2.00 20.00 -2.00 321.99 0.00e+00 7.041 0.009 302.00 328.00 3 2.0931e-01 2.6431e-02 9.8263e-02 -6.0000e+00 7.1940e-01 1.2897e+00 3.4576e-02 6.6932e-02 -6.0000e+00 7.8137e-01 -1.6466e+00 3.4700e-02 3.5988e-02 -6.0000e+00 4.5520e-01 6.5432e-01 1.7256e-02 1.2074e-02 -6.0000e+00 1.8509e-01 1.2617e-04 -2.2207e-03 3.5865e-04 1.5135e-04 -6.0000e+00 1.2391e-02 2.6204e-02 3.2654e-06 12 8 8 10 0 0 -37.88 16.90 0.11 0.02620 0.00952 66 13 1 5 0 762.710 20.04 14.98 16.90 19.48 30.9 962.17 119286 -140153 26166 -113442 6851 53176 -113867 -78743 -64250 189728 -88182 -59317 -130496 900000 -57122 900000 -49220 63114 -60221 44485 -53041 54641 -15131 900000 46155 -59888 -55154 64728 42837 -25085 92094 -49044 19358 90966 900000 -52888 69992 -12201 64915 7005 98432 13552 49514 41176 79471 96203 1354 54221 24469 62793 43088 97772 10938 94929 29671 34473 22884 48942 3833 18122 8362 10608 46250 16428 40004 14881 35000 13232 37421 9687 39439 16569 31257 9229 22390 -1383 -1369 -4674 884 3704 1280 3560 2237 4665 -1879 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