File name: Pandora105s1_Helsinki_20240817_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T084126.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240817_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20240817T075404.3Z 8995.329216 1647 1 49.79 2 54.41 133.17 146.79 352.34 0.00 1 0.00 1 0 17 1.480e-02 7.488e-03 8.583e-03 2.783e-03 2.410772e-01 1.476534e-03 3.542155e-03 -6.000000e+00 8.896890e-03 232.46 -2.00 4.26 -2.00 317.40 0.00e+00 5.616406e-04 1.928370e-04 6.022015e-05 -6.000000e+00 3.509866e-04 279.52 -2.00 20.00 -2.00 317.07 0.00e+00 1.713 0.000 302.00 328.00 3 4.7287e+00 3.9307e-03 2.3168e-02 -6.0000e+00 2.2588e-02 5.6915e-02 4.3671e-03 1.5435e-02 -6.0000e+00 2.4465e-02 -1.0059e-02 2.6394e-03 7.5674e-03 -6.0000e+00 1.4303e-02 -6.1220e-04 1.2790e-03 2.1225e-03 -6.0000e+00 5.9022e-03 6.3608e-04 6.1432e-04 7.9540e-05 2.1705e-05 -6.0000e+00 3.9111e-04 1.0547e-02 3.9245e-05 11 8 0 10 0 0 84.12 17.61 0.07 0.01055 0.01516 13 3 1 5 0 3829.220 20.56 15.00 17.61 999.00 -9.0 -9.00 -4207 -1506 3821 -1494 -7702 -2256 -2940 -1911 345 -781 -3733 -2255 -2759 -1655 -2000 -48 -917 1830 -823 470 1667 1955 -19 24 455 4231 198 1554 1170 3291 346 876 259 786 -1940 -2847 -3460 -3094 -1891 -566 -909 -499 -338 -626 344 -7 -167 -288 -658 -376 735 1110 312 1048 592 1490 1165 703 -98 566 873 1018 1504 2394 846 -570 -807 -1852 701 -122 878 618 1168 606 354 -19 -1459 -1909 -406 -1312 -806 -1108 -2191 -1823 -902 -498 -196 9 712 889 253 83 -425 -126 339 316 501 1268 603 -151 -949 -1227 -1177 567 -559 -786 -562 -655 -48 533 566 284 95 -420 -446 -511 -61 -115 581 24 -329 232 443 22 532 71 350 1170 934 820 518 107 -435 150 360 -337 -36 327 -88 -460 -337 -1032 -501 -187 456 -171 -844 -229 -326 -239 46 -108 -522 -325 -454 -304 -417 -11 -207 423 -202 118 418 479 -5 7 130 1197 57 412 293 822 95 257 83 245 -577 -870 -1184 -1255 -891 -293 -500 -283 -195 -362 197 -4 -94 -159 -356 -207 429 679 202 700 403 1030 818 487 -67 387 627 781 1238 2035 693 -432 -584 -1366 560 -109 811 583 1085 540 293 -14 -1036 -1364 -310 -1130 -755 -1112 -2282 -1967 -1040 -602 -244 12 884 1051 280 85 -413 -123 355 360 622 1662 812 -196 -1158 -1421 -1358 690 -730 -1056 -775 -940 -72 831 899 448 143 -596 -591 -667 -82 -161 861 38 -508 346 647 31 725 93 446 1534 1307 1201 774 161 -679 243 611 -587 -65 588 -158 -799 -570 -1716 SU 20240817T075650.1Z 8995.331135 1650 1 32.38 2 54.16 133.94 146.83 353.40 0.00 1 0.00 1 0 17 1.344e-02 7.360e-03 8.901e-03 3.050e-03 2.359465e-01 1.619242e-03 3.480733e-03 -6.000000e+00 8.076891e-03 232.46 -2.00 4.26 -2.00 317.20 0.00e+00 7.577637e-05 2.016508e-04 5.542902e-05 -6.000000e+00 3.188443e-04 279.52 -2.00 20.00 -2.00 316.87 0.00e+00 1.703 0.000 302.00 328.00 3 4.6453e+00 4.2997e-03 2.2865e-02 -6.0000e+00 2.0505e-02 3.3225e-02 4.7748e-03 1.5125e-02 -6.0000e+00 2.2213e-02 1.8302e-03 2.8621e-03 7.4153e-03 -6.0000e+00 1.2988e-02 -6.2703e-03 1.3757e-03 2.0752e-03 -6.0000e+00 5.3561e-03 7.1150e-04 -2.8141e-05 8.6550e-05 2.1310e-05 -6.0000e+00 3.5576e-04 1.3004e-02 -6.0771e-05 12 9 1 12 1 1 98.03 17.61 -0.17 0.01300 0.01279 8 3 1 5 0 3596.930 20.67 15.01 17.61 999.00 -9.0 -9.00 1993 459 709 247 -2300 4261 -3325 -1245 2222 1758 -2849 -5204 -4650 -646 -4145 773 37 1605 561 -234 1003 3055 -730 -526 -248 976 902 1351 -299 -466 162 848 2022 -1501 -1775 -4281 -2897 -2684 -1153 -1018 -622 -277 221 929 562 1072 -1284 -204 -293 306 210 675 222 548 425 1572 840 717 590 -20 857 736 662 1672 373 164 -849 -685 345 652 394 591 964 603 324 -2 -1114 -1269 -757 -862 -912 -1754 -2655 -1529 -998 -25 112 405 395 737 411 155 -537 527 22 147 953 1388 770 -425 -736 -1675 -462 -77 -552 -854 -973 -498 -75 552 682 211 -18 18 -1015 -247 230 181 472 -259 -333 179 178 361 796 135 61 1094 1095 569 596 -209 -500 23 356 -232 -13 446 -448 -347 -316 -701 239 60 93 30 -255 440 -399 -167 318 258 -429 -839 -835 -127 -942 181 9 395 144 -63 269 790 -203 -155 -77 307 275 385 -81 -129 48 266 677 -510 -562 -1402 -1056 -1136 -566 -556 -354 -163 132 548 333 636 -758 -117 -165 175 128 434 149 382 301 1129 608 517 418 -14 641 583 560 1456 315 128 -631 -518 285 588 373 568 914 548 276 -2 -819 -924 -597 -751 -870 -1784 -2803 -1662 -1152 -30 139 509 488 873 458 161 -525 522 23 169 1177 1822 1026 -556 -906 -1945 -535 -94 -716 -1141 -1343 -703 -110 849 1071 330 -26 26 -1353 -321 303 251 689 -395 -506 267 260 506 1076 177 78 1439 1520 831 887 -316 -770 36 591 -397 -23 779 -781 -591 -529 -1151 SU 20240817T075912.5Z 8995.332783 1653 1 13.12 2 53.95 134.61 146.85 354.32 0.00 1 0.00 1 0 17 1.276e-02 7.502e-03 7.063e-03 2.991e-03 2.338540e-01 1.593468e-03 3.454736e-03 -6.000000e+00 7.664809e-03 232.46 -2.00 4.26 -2.00 316.60 0.00e+00 1.629404e-04 1.728652e-04 4.663041e-05 -6.000000e+00 3.025243e-04 279.52 -2.00 20.00 -2.00 316.27 0.00e+00 1.695 0.000 302.00 328.00 3 3.9926e+00 4.2047e-03 2.2689e-02 -6.0000e+00 1.9459e-02 4.2273e-02 4.6605e-03 1.4958e-02 -6.0000e+00 2.1079e-02 -1.1713e-03 2.7236e-03 7.3184e-03 -6.0000e+00 1.2324e-02 -3.5727e-03 1.2700e-03 2.0386e-03 -6.0000e+00 5.0839e-03 1.3776e-03 1.3044e-04 8.3867e-05 2.1560e-05 -6.0000e+00 3.3734e-04 1.1525e-02 -3.5780e-05 12 9 1 12 1 1 84.44 17.62 -0.11 0.01152 0.01250 5 4 1 5 0 2184.980 20.67 15.01 17.62 999.00 -9.0 -9.00 3379 -2484 3403 -2479 1622 -2863 422 -812 1809 2019 -2820 -626 -3156 1205 -2840 834 -1847 1445 -236 2355 -936 1973 -581 -1105 -750 2384 1229 1644 283 1054 1166 -1302 3623 212 -889 -5037 -2221 -2555 -416 -1386 -652 -907 -357 -464 114 -847 -542 -12 -746 555 -121 311 546 1306 278 1103 531 1327 128 -87 144 820 1744 1611 1241 -443 -292 -412 644 425 635 117 587 921 841 75 -727 -1018 -618 -785 -1083 -906 -2724 -1176 -972 -27 -319 -144 414 474 759 72 -353 526 317 134 720 1077 376 -737 -552 -1360 -393 445 -407 -1212 -501 -1053 64 362 699 108 123 -121 -830 -70 142 531 146 508 -499 -45 -35 385 679 391 106 1201 1034 482 331 -575 -157 237 254 -417 429 160 -120 -570 -295 -829 521 -428 561 -400 225 -407 63 -140 333 378 -535 -123 -702 293 -791 239 -556 437 -74 758 -310 631 -195 -396 -279 892 451 563 93 346 410 -495 1418 84 -331 -1990 -941 -1252 -231 -857 -420 -598 -239 -310 76 -565 -353 -7 -475 356 -82 221 402 982 213 858 421 1024 99 -68 116 695 1548 1477 1102 -371 -234 -333 563 404 624 118 581 875 753 63 -575 -797 -520 -719 -1070 -941 -2943 -1305 -1132 -33 -397 -182 514 569 854 76 -360 537 344 156 888 1398 496 -951 -676 -1591 -458 545 -522 -1614 -679 -1466 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