File name: Pandora105s1_Helsinki_20240922_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240927T090119.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240922_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240922 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240922T044820.2Z 9031.200234 234 1 51.60 2 85.50 97.66 49.08 240.81 0.00 1 0.00 1 0 41 5.484e-01 8.767e-02 5.521e-01 9.014e-02 9.154954e-01 5.285068e-02 1.200357e-02 -6.000000e+00 3.248332e-01 226.84 -2.00 4.26 -2.00 321.55 0.00e+00 -1.124353e-02 1.385689e-02 6.149810e-04 -6.000000e+00 1.431347e-02 274.46 -2.00 20.00 -2.00 321.11 0.00e+00 10.584 0.031 302.00 328.00 3 -8.3095e-01 1.5623e-01 1.2134e-01 -6.0000e+00 8.1627e-01 2.2645e+00 1.7685e-01 5.4898e-02 -6.0000e+00 8.9052e-01 -1.9669e+00 1.0810e-01 2.7753e-02 -6.0000e+00 5.1976e-01 5.7364e-01 6.0351e-02 8.8939e-03 -6.0000e+00 2.1751e-01 1.1761e-05 5.3086e-03 2.4887e-03 9.1250e-05 -6.0000e+00 1.4565e-02 1.5527e-02 4.5701e-05 12 8 8 10 0 0 -225.64 16.60 1.38 0.01553 0.05542 17 3 1 5 0 3034.610 19.85 15.01 16.60 10.56 31.6 949.97 2504 -7039 55927 144118 75724 -87033 48765 -11905 187027 900000 -36376 900000 61899 119257 -14955 223182 -20752 61077 66890 280263 -18881 900000 8870 17970 35811 39722 9776 -58333 -39936 -12019 900000 -33752 900000 132683 3285 80772 40626 -20648 143795 31331 3718 -40112 5164 -64844 38955 -30898 49744 2129 -76653 900000 81784 900000 -41599 7571 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-7200 3933 -1085 -3042 1754 13946 -9366 8605 -6476 -12188 -5905 10822 -13571 8377 962 346 -16974 9517 11821 -2475 -7054 11722 -4979 -8120 1080 -571 11307 1143 11257 4246 10031 -9446 -6721 -3493 4408 -25668 12136 10315 6973 -6864 -17134 -5874 7449 4682 -5328 4563 -6856 8100 6524 533 -1771 SS 20240922T050002.7Z 9031.208365 237 1 50.00 2 84.06 100.22 50.30 243.84 0.00 1 0.00 1 0 33 4.490e-01 2.699e-02 4.006e-01 2.045e-02 9.154515e-01 1.253003e-02 1.210181e-02 -6.000000e+00 2.677922e-01 226.84 -2.00 4.26 -2.00 322.33 0.00e+00 3.741760e-03 5.256057e-03 1.439017e-03 -6.000000e+00 1.171056e-02 274.46 -2.00 20.00 -2.00 321.97 0.00e+00 8.611 0.016 302.00 328.00 3 -4.7170e-01 4.1375e-02 1.0437e-01 -6.0000e+00 6.7323e-01 1.4116e+00 4.9780e-02 5.8397e-02 -6.0000e+00 7.3409e-01 -1.7657e+00 4.3077e-02 3.1133e-02 -6.0000e+00 4.2894e-01 6.8905e-01 2.2639e-02 1.0538e-02 -6.0000e+00 1.7793e-01 6.9525e-05 -2.0245e-03 6.0084e-04 1.4928e-04 -6.0000e+00 1.2408e-02 1.7306e-02 1.5518e-06 12 8 8 10 0 0 27.20 16.60 0.30 0.01731 0.00209 54 11 1 5 0 925.700 19.85 14.98 16.60 11.08 31.6 953.57 -30835 103874 -49613 900000 -123840 -48779 -12041 900000 -96350 900000 -36920 -38658 22075 -14088 146160 109520 900000 35842 75135 48836 150430 7260 -3639 -45890 39888 70685 900000 -23976 61502 -42141 26816 85273 -8003 44060 3205 137654 -1806 81900 -12432 60741 12233 178013 25990 112875 30173 57305 17670 30945 104671 24188 67554 23582 72061 33660 47860 35563 67870 2436 19724 -7227 32690 22207 62783 26488 53532 30490 -1248 33860 11798 23746 12441 36709 -2157 25284 5373 7933 -12221 1515 -5717 11890 -6222 1697 4585 601 -3223 -2965 6844 -4531 -675 -2129 662 -14924 6075 -10876 -4464 -4625 -74 689 1086 51 -3204 -816 -4264 857 -5975 -3113 -7342 -2398 -3183 -579 -195 -836 2437 -341 147 -1821 141 -2833 809 -60 2403 360 2502 2250 5985 2382 1433 761 2038 1272 250 948 -207 -552 -430 629 -598 803 -404 -397 -1035 -1153 -1331 2069 -2553 900000 -9249 -1678 -283 900000 -5408 900000 -1070 -1260 480 -536 2911 2181 900000 1168 1632 1326 2996 250 -138 -2742 1011 1408 900000 -955 1225 -2136 908 1868 -449 1579 153 2742 -94 2120 -966 2540 877 3545 1656 2922 1743 2511 1161 1849 3127 1734 3498 2066 4162 3017 3813 3258 4461 291 1846 -849 2669 2256 4877 3324 5224 3643 -209 4248 2115 4256 2626 6068 -494 3978 910 1185 -2215 262 -1275 2676 -1958 561 1580 226 -1335 -1287 2794 -2085 -292 -882 251 -6390 2153 -5133 -2347 -2883 -52 549 917 42 -2476 -540 -2743 558 -4486 -2380 -6258 -2145 -3302 -682 -256 -1168 3320 -465 192 -2412 191 -4198 1218 -91 3378 491 3269 2890 7260 2893 1767 1084 3397 2445 533 2147 -508 -1471 -1225 1820 -1766 2363 -1173 -1076 -2598 -2701 SS 20240922T051050.5Z 9031.215862 240 1 50.43 2 82.75 102.60 51.45 246.56 0.00 1 0.00 1 0 25 5.049e-01 2.184e-02 3.016e-01 1.047e-02 8.348851e-01 6.210902e-03 1.096272e-02 -6.000000e+00 2.988595e-01 226.83 -2.00 4.26 -2.00 322.09 0.00e+00 7.761462e-03 2.700050e-03 1.349848e-03 -6.000000e+00 1.269303e-02 274.46 -2.00 20.00 -2.00 321.75 0.00e+00 7.309 0.010 302.00 328.00 3 3.8829e-02 2.0286e-02 9.0617e-02 -6.0000e+00 7.4981e-01 7.9489e-01 2.7565e-02 5.4793e-02 -6.0000e+00 8.1733e-01 -1.0557e+00 2.9328e-02 3.0771e-02 -6.0000e+00 4.7745e-01 4.3350e-01 1.4397e-02 1.0653e-02 -6.0000e+00 2.0023e-01 1.6566e-04 -1.3126e-03 3.0930e-04 1.3218e-04 -6.0000e+00 1.3516e-02 1.6215e-02 7.2332e-05 12 8 8 10 0 0 96.66 16.60 0.07 0.01622 0.00635 75 15 1 5 0 672.280 19.85 15.00 16.60 11.63 31.5 957.01 900000 -130932 -3121 -192692 900000 -172668 -106389 -161868 900000 -154289 -140383 -125341 -103356 -26856 -60194 188834 -57220 -23308 -7015 900000 -25570 55074 96741 900000 -67727 147153 -74383 -57547 51338 27042 42639 39046 49724 31084 40772 -17512 46789 -9656 82345 15877 67455 10398 45543 12682 32694 5634 15218 29284 21774 59993 30251 28422 18085 34100 18375 36705 20029 40103 28762 30062 16726 23057 14793 26477 23708 15320 26431 11361 10098 3400 19580 7917 17070 1226 5372 2950 6812 -9824 -6672 -1813 1479 1771 -3668 2399 -2593 2470 -1417 4738 -2613 3006 21 -169 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