File name: Pandora105s1_Helsinki_20240924_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20240924T221714.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20240924_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20240924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240924T052228.6Z 9033.223942 257 1 49.72 2 81.95 105.70 36.50 219.38 0.00 1 0.00 1 0 25 4.862e-01 2.549e-02 3.695e-01 1.751e-02 7.561294e-01 1.054447e-02 1.009028e-02 -6.000000e+00 2.908257e-01 226.49 -2.00 4.26 -2.00 321.85 0.00e+00 9.364487e-03 4.340643e-03 1.095344e-03 -6.000000e+00 1.330779e-02 274.12 -2.00 20.00 -2.00 321.50 0.00e+00 6.681 0.008 302.00 328.00 3 1.5301e+00 3.3322e-02 8.2210e-02 -6.0000e+00 7.2854e-01 7.3623e-01 4.3391e-02 4.9249e-02 -6.0000e+00 7.9572e-01 -9.4163e-01 4.5325e-02 2.7217e-02 -6.0000e+00 4.6770e-01 3.7963e-01 2.2686e-02 9.2445e-03 -6.0000e+00 1.9753e-01 7.0939e-05 -9.1154e-04 5.3845e-04 1.1511e-04 -6.0000e+00 1.3269e-02 9.7238e-03 8.1449e-05 12 8 8 10 0 0 33.08 17.12 0.27 0.00972 0.00287 26 5 1 5 0 1911.710 20.25 15.00 17.12 21.30 32.6 1026.75 900000 -88221 900000 -61592 900000 -140080 137282 -94246 -78391 -118151 -99094 900000 127493 900000 -125874 900000 -46529 900000 38347 900000 -87611 900000 -62170 -44677 27053 900000 -28198 50740 104989 5009 900000 -28630 217579 15029 105318 -36230 137739 584 900000 65322 60181 -10 3086 52643 50617 105817 14160 66338 29019 106391 -7843 91940 47 29316 18331 30959 -1389 25115 23778 16850 32347 5629 24216 13523 9229 3148 16232 -4455 28078 1273 22710 -1747 8724 -3743 9847 -2717 -8647 1810 4794 -4257 3468 3344 4088 6517 -7728 -1138 -8105 7885 134 5943 -4019 -185 -2696 975 -10099 -859 -3088 -1817 1631 -2112 854 -3094 1175 -5076 -757 -3793 -920 -2412 216 -855 -635 1329 681 766 -1010 -775 -1977 -515 -979 2441 -1119 1946 1069 2798 1533 1322 -494 1677 1774 674 1482 187 644 -337 599 -758 622 -915 839 -1704 98 -1277 900000 -2092 900000 -1049 900000 -4151 2338 -1895 -1391 -3103 -2133 900000 2172 900000 -8254 900000 -1786 900000 709 900000 -5410 900000 -2834 -1783 541 900000 -954 864 1788 134 900000 -1534 3706 602 1794 -2138 2346 31 900000 2458 2555 -1 244 2623 2600 3250 1082 3188 2117 3899 -976 4770 6 3150 2255 3420 -212 2880 2648 1988 3454 873 3626 2486 1801 629 2901 -1017 5375 356 5514 -538 2340 -1047 2153 -611 -2022 411 1250 -1452 1267 1379 1759 2919 -4191 -611 -4869 4146 75 2967 -2072 -88 -1302 499 -6740 -612 -2566 -1702 1562 -2030 735 -2448 844 -4145 -637 -3440 -861 -2488 244 -1118 -898 1913 992 1071 -1367 -1033 -2769 -754 -1525 3715 -1693 2726 1498 3750 2028 1686 -638 2375 2915 1241 2931 395 1434 -814 1507 -1987 1626 -2461 2203 -4323 228 -2863 SS 20240924T053456.0Z 9033.232593 261 1 50.46 2 80.47 108.48 37.49 223.49 0.00 1 0.00 1 0 25 4.441e-01 1.074e-02 2.666e-01 7.508e-03 6.833925e-01 4.240908e-03 9.218720e-03 -6.000000e+00 2.629507e-01 226.48 -2.00 4.26 -2.00 321.52 0.00e+00 3.832507e-03 1.689548e-03 9.020927e-04 -6.000000e+00 1.054324e-02 274.12 -2.00 20.00 -2.00 321.17 0.00e+00 5.756 0.005 302.00 328.00 3 1.3804e+00 1.3033e-02 7.2037e-02 -6.0000e+00 6.5860e-01 2.4915e-01 1.8115e-02 4.5115e-02 -6.0000e+00 7.1689e-01 -3.1017e-01 2.0994e-02 2.5463e-02 -6.0000e+00 4.1945e-01 1.1770e-01 1.0386e-02 8.6281e-03 -6.0000e+00 1.7451e-01 2.3242e-04 -8.0880e-04 2.2123e-04 9.7582e-05 -6.0000e+00 1.1895e-02 1.0840e-02 1.8519e-05 12 8 8 10 0 0 26.47 17.13 0.28 0.01084 0.00476 57 11 1 5 0 885.020 20.25 15.00 17.13 21.72 32.7 1029.81 -63297 -169915 -147725 -164201 -58666 -151042 900000 -114682 -124733 -167650 -142629 -136099 -130272 -80862 -92643 -42086 -16744 -52687 -66937 -18872 -40448 34312 -60000 -9202 -13734 -9495 -6160 49885 26876 -38363 16311 -20655 -17675 -9672 62907 -26986 -9259 -7820 21284 -5127 6241 12380 -1978 2206 4134 -976 5384 9205 3562 4070 7221 4544 -2466 5914 8298 5596 3432 9554 5867 290 4143 1803 5039 6695 4880 -676 -728 -1725 3651 2718 1898 3129 3337 -807 5339 2205 -616 2410 1947 -2589 -3296 -321 -2955 -405 -2442 -42 1878 1410 2894 726 -233 -175 -1805 -1156 -1929 -475 153 493 543 -89 -794 -1221 -1600 -1695 -1145 -2046 -1043 -1391 -385 -559 901 1257 -112 -377 -535 -1111 -447 612 -46 251 63 -235 939 493 1456 747 564 955 389 596 586 -475 221 -62 -25 -355 270 120 -135 12 33 -1104 -463 -2261 -1671 -2076 -429 -1508 900000 -992 -1328 -2900 -1993 -2083 -2427 -1184 -1911 -678 -233 -1157 -1648 -332 -888 352 -1669 -168 -281 -195 -122 548 374 -1151 346 -756 -724 -375 1105 -1185 -386 -389 966 -353 420 834 -161 174 327 -84 445 768 331 408 793 569 -361 857 1227 885 565 1448 893 47 679 342 1059 1544 1161 -164 -177 -450 1040 891 670 1109 1136 -266 1497 581 -163 660 628 -1039 -1537 -163 -1651 -233 -1534 -27 1252 957 1903 463 -140 -100 -1036 -717 -1395 -392 144 525 606 -96 -787 -1082 -1364 -1551 -1120 -2110 -1128 -1628 -498 -818 1416 2025 -180 -579 -777 -1600 -662 950 -76 421 102 -366 1407 720 2048 1014 758 1422 670 1140 1205 -1035 505 -152 -61 -873 669 301 -335 31 80 -2549 SS 20240924T054527.1Z 9033.239897 266 1 50.45 2 79.24 110.84 38.38 226.85 0.00 1 0.00 1 0 25 3.902e-01 8.372e-03 1.805e-01 4.207e-03 6.253271e-01 2.317245e-03 8.426501e-03 -6.000000e+00 2.295145e-01 226.48 -2.00 4.26 -2.00 321.19 0.00e+00 5.537015e-04 8.793973e-04 7.220235e-04 -6.000000e+00 9.255358e-03 274.11 -2.00 20.00 -2.00 320.87 0.00e+00 5.157 0.003 302.00 328.00 3 1.2018e+00 6.9559e-03 6.4710e-02 -6.0000e+00 5.7454e-01 8.1902e-02 9.5700e-03 4.0759e-02 -6.0000e+00 6.2503e-01 -1.0477e-01 1.1091e-02 2.2846e-02 -6.0000e+00 3.6710e-01 3.2012e-02 5.5354e-03 7.6464e-03 -6.0000e+00 1.5336e-01 5.3518e-04 -5.2618e-04 1.2285e-04 7.5146e-05 -6.0000e+00 1.0300e-02 1.0380e-02 3.7495e-05 11 8 0 10 0 0 24.04 17.13 0.14 0.01038 0.00643 95 19 1 5 0 530.520 20.25 15.01 17.13 22.17 32.7 1033.13 -109717 -155234 -148790 -87250 -133817 -127674 -177479 -99461 -111154 -107169 -69090 -98328 -8657 -76661 49886 -53354 22127 -59632 4501 -34080 -1322 -15519 14242 -27222 14343 -25108 -29336 -36820 -28986 -33699 -7399 27058 -14207 13757 -17299 8192 -28339 7039 -8600 6362 -5980 2579 7324 3205 7626 4889 3412 1899 4714 751 11236 1566 4053 1300 4643 3838 4070 1100 1513 691 3286 1177 1278 4991 1345 4401 -3740 3101 -461 1272 242 2628 -374 1766 -429 455 -202 -1506 -919 -2074 211 -1947 -125 -2579 -991 -817 -228 -27 1586 1264 1369 -461 -252 -449 540 -360 -273 1000 470 88 -867 -745 -1764 14 -798 -436 -1908 -693 -468 164 473 208 335 21 -371 267 491 -161 655 -317 -463 59 845 -72 776 176 484 485 1252 438 -137 -310 -544 -220 -111 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