File name: Pandora105s1_Helsinki_20241003_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20241003T221731.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20241003_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20241003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241003T065409.9Z 9042.287614 133 1 50.14 2 74.72 129.00 80.12 125.78 0.00 1 0.00 1 0 25 3.371e-01 2.192e-02 2.736e-01 1.852e-02 4.909684e-01 1.014405e-02 7.127996e-03 -6.000000e+00 1.971397e-01 224.91 -2.00 4.26 -2.00 320.34 0.00e+00 4.676132e-03 3.008483e-03 3.201060e-04 -6.000000e+00 9.087941e-03 272.56 -2.00 20.00 -2.00 320.01 0.00e+00 3.724 0.001 302.00 328.00 3 4.4852e+00 2.8594e-02 4.8057e-02 -6.0000e+00 4.9176e-01 2.0043e-01 3.4323e-02 3.1106e-02 -6.0000e+00 5.3721e-01 -1.0120e-01 3.2641e-02 1.6267e-02 -6.0000e+00 3.1465e-01 3.3758e-02 1.7216e-02 5.0132e-03 -6.0000e+00 1.3203e-01 7.9089e-05 -5.6201e-03 5.5460e-04 5.4947e-05 -6.0000e+00 9.0021e-03 2.1671e-02 -9.1190e-04 12 8 8 10 0 0 99.99 16.73 0.12 0.02167 -0.02056 23 4 1 5 0 2179.700 19.96 15.01 16.73 13.12 31.9 1015.85 -96435 -68370 900000 -19581 900000 -114469 -1392 -113025 900000 10308 900000 -77124 -52914 900000 25299 253329 -26878 87603 8787 62764 -26584 54630 -9160 900000 -14332 35040 12241 -8280 -3703 654 29514 4365 33650 22085 34746 -10489 90781 -19176 4935 -6219 -2264 -2502 6215 -11818 15342 3999 10117 -2969 6876 12816 -7937 9468 6268 16554 -4478 19170 -5541 9472 -7265 4763 1070 904 -5503 -381 -1626 1562 1467 -2369 3235 -4164 1026 -488 2432 -1187 3393 1686 10048 -1580 -2334 -1471 -903 2041 -4663 558 -3309 4557 -734 2522 -888 2645 -5000 2842 -6771 1734 93 54 3853 -2552 485 -1892 2043 -4435 2653 -390 -212 -1182 865 -2449 813 -1465 784 404 1131 11 -1774 451 -222 904 361 908 -2030 1478 -77 3412 -78 181 -1533 537 -164 2597 1258 -981 -184 -1848 674 -20 613 -1318 1393 -379 535 -1499 -2898 -1752 900000 -353 900000 -3978 -25 -4756 900000 186 900000 -3033 -2040 900000 684 4568 -1454 1740 388 1748 -1721 1631 -522 900000 -960 1528 655 -519 -222 41 1632 349 2276 1675 2183 -1037 3863 -2781 675 -1074 -405 -477 1128 -2571 2617 778 1887 -636 1380 2565 -2136 2329 1705 4340 -1473 5178 -1918 2788 -2467 1441 357 336 -2410 -173 -736 642 589 -1024 1508 -2359 585 -286 1337 -642 1589 734 3829 -701 -1192 -855 -591 1430 -3676 439 -2897 3912 -692 2327 -832 2284 -4311 2105 -5307 1335 81 54 4129 -3211 612 -2363 2233 -4709 2547 -415 -242 -1414 1064 -3261 1142 -2311 1284 668 1786 17 -2546 618 -315 1341 574 1472 -3308 2265 -116 4785 -109 243 -2038 757 -259 4313 2232 -1831 -354 -3836 1452 -44 1378 -3064 3103 -820 1099 -2989 SS 20241003T070422.1Z 9042.294700 136 1 50.24 2 73.76 131.45 79.17 128.10 0.00 1 0.00 1 0 25 7.212e-02 5.617e-03 1.022e-02 5.630e-04 4.644632e-01 2.967650e-04 6.561681e-03 -6.000000e+00 4.214577e-02 224.91 -2.00 4.26 -2.00 319.94 0.00e+00 4.782395e-04 8.115277e-05 3.012040e-04 -6.000000e+00 1.710530e-03 272.56 -2.00 20.00 -2.00 319.63 0.00e+00 3.516 0.001 302.00 328.00 3 -3.9746e-01 8.2235e-04 4.5154e-02 -6.0000e+00 1.0512e-01 4.4129e-02 9.6944e-04 2.8945e-02 -6.0000e+00 1.1451e-01 -1.5844e-02 8.9418e-04 1.5198e-02 -6.0000e+00 6.7340e-02 -4.2809e-03 4.7803e-04 4.7470e-03 -6.0000e+00 2.8211e-02 1.4349e-02 -4.2918e-04 1.6463e-05 4.4757e-05 -6.0000e+00 1.9043e-03 1.2557e-02 -2.4178e-05 10 0 0 10 0 0 99.92 16.74 -0.04 0.01256 0.00933 957 186 1 5 0 52.430 19.96 15.00 16.74 13.28 32.1 1017.13 -29633 -14118 -23515 -17928 -31580 -24434 -30885 -19631 -16987 -21182 -14353 -21474 -12525 -13923 -4446 -7834 -2862 -5261 -948 -3790 -2749 -4934 -3932 -4607 -2275 -1035 -1787 -1590 -5339 -2275 -2904 -399 -1001 479 -4316 -3752 -4895 -3255 -2093 -740 -789 -528 215 -60 904 222 694 117 -111 -531 1162 608 1072 757 1024 966 1471 1237 751 335 404 795 1332 2273 847 394 -684 -448 52 696 445 753 749 1075 845 439 -435 -989 -567 -931 -790 -1301 -1949 -1884 -957 -624 -174 415 917 807 995 811 114 443 251 -52 263 778 224 -92 -510 -844 -841 260 -667 -872 -970 -791 -442 143 324 207 244 -73 -135 59 205 16 237 -293 -496 -336 314 239 779 199 265 1146 888 659 175 -8 -439 -90 27 -275 -71 326 -177 -145 -163 -418 -467 -213 -407 -276 -506 -366 -551 -364 -347 -477 -306 -549 -356 -489 -170 -350 -131 -267 -49 -211 -154 -282 -236 -306 -159 -75 -129 -109 -369 -163 -241 -37 -105 50 -439 -389 -585 -464 -359 -145 -168 -118 49 -14 210 53 164 28 -27 -139 331 190 359 271 378 371 573 474 282 126 161 351 650 1187 441 192 -330 -223 30 403 275 472 456 677 485 229 -217 -510 -331 -632 -551 -1008 -1602 -1632 -883 -609 -177 423 915 762 869 659 90 367 234 -55 311 1015 304 -120 -608 -913 -889 294 -817 -1115 -1305 -1123 -623 221 528 338 382 -107 -203 87 310 24 369 -473 -786 -513 505 369 1156 282 367 1703 1472 1091 305 -15 -827 -179 58 -603 -157 735 -396 -310 -330 -812 SS 20241003T071320.6Z 9042.300932 143 1 2.73 2 72.94 133.62 78.36 130.15 0.00 1 0.00 1 0 25 5.164e-02 6.941e-03 1.856e-02 1.886e-03 4.444575e-01 9.839754e-04 6.452455e-03 -6.000000e+00 3.017892e-02 224.91 -2.00 4.26 -2.00 318.92 0.00e+00 7.818433e-04 2.063304e-04 2.046413e-04 -6.000000e+00 1.224800e-03 272.56 -2.00 20.00 -2.00 318.62 0.00e+00 3.357 0.001 302.00 328.00 3 -7.0577e-02 2.6402e-03 4.3170e-02 -6.0000e+00 7.5275e-02 5.1186e-02 2.9986e-03 2.7591e-02 -6.0000e+00 8.1997e-02 -3.0224e-02 2.2937e-03 1.4057e-02 -6.0000e+00 4.8218e-02 5.2421e-03 1.2349e-03 4.1988e-03 -6.0000e+00 2.0201e-02 1.2281e-02 -3.0889e-04 5.2573e-05 3.9876e-05 -6.0000e+00 1.3635e-03 1.2264e-02 -2.0950e-05 12 9 1 12 1 1 98.96 16.75 -0.01 0.01226 0.00994 35 130 1 5 0 75.500 19.96 15.00 16.75 13.66 31.7 1018.98 -26897 10565 -13027 593 -15867 -14659 -12292 -15076 -5837 -23495 1056 -23906 -4563 -14630 3618 -7466 3013 -2335 6159 -1777 3659 -1285 -3243 -284 -2898 2361 -2665 2451 -5903 1574 -3659 1549 -1212 3143 -3628 -2321 -4150 -1670 -2219 -1422 -466 -959 825 -1022 838 -12 1314 -968 1251 -1160 1570 178 1078 1206 847 1273 1882 1255 572 1187 -204 1559 803 2547 785 804 -702 -34 27 475 261 460 823 671 749 -86 -71 -1719 -527 -1226 -494 -1613 -1949 -2146 -1115 -516 -163 169 725 576 552 698 97 518 312 82 426 851 -169 -34 -548 -942 -1120 190 -854 -718 -928 -737 -174 312 524 279 145 -17 22 -92 300 -32 397 -478 -521 -214 282 334 887 470 162 1164 1002 707 324 87 -516 208 -35 -326 -203 389 -375 -351 -237 -508 -885 266 -431 16 -458 -418 -380 -554 -220 -1110 39 -1271 -242 -1039 255 -660 257 -226 579 -190 375 -138 -374 -35 -355 286 -335 306 -778 204 -521 238 -214 534 -615 -398 -824 -391 -634 -425 -149 -325 284 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