File name: Pandora105s1_Helsinki_20241030_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20241031T000520.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20241030_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20241030 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241030T064801.7Z 9069.283354 164 1 50.29 2 83.84 132.60 69.70 152.53 0.00 1 0.00 1 0 25 4.883e-01 2.079e-02 3.964e-01 1.402e-02 9.515479e-01 8.387384e-03 1.246520e-02 -6.000000e+00 2.813835e-01 220.79 -2.00 4.26 -2.00 322.38 0.00e+00 8.167242e-03 3.767712e-03 1.782792e-03 -6.000000e+00 1.158352e-02 267.83 -2.00 20.00 -2.00 322.03 0.00e+00 8.380 0.015 302.00 328.00 3 -7.5804e-01 2.7945e-02 1.0293e-01 -6.0000e+00 6.9579e-01 1.2557e+00 3.6471e-02 6.0279e-02 -6.0000e+00 7.6013e-01 -1.6184e+00 3.6570e-02 3.4052e-02 -6.0000e+00 4.4846e-01 6.5171e-01 1.8435e-02 1.2267e-02 -6.0000e+00 1.8943e-01 1.1504e-04 -1.7031e-03 3.9826e-04 1.7160e-04 -6.0000e+00 1.2896e-02 9.0431e-03 -1.2088e-05 12 8 8 10 0 0 0.23 16.84 0.26 0.00904 -0.00375 80 16 1 5 0 628.450 20.04 14.99 16.84 13.59 32.4 999.21 -30190 -23448 -25377 -95423 -128362 -126495 -104934 -141406 95236 -102220 -19570 -57532 -1432 124321 900000 102613 -4728 -12623 69734 23117 -14759 25197 126639 6211 -10605 -2472 -44685 4382 -47575 -22057 -8542 118785 25385 268973 22429 82707 -29092 79404 81516 81318 43301 80187 81773 10806 4853 10893 152147 -3402 37938 29934 17664 6333 46722 18121 46814 2482 27435 11134 18628 3772 11063 -4899 25354 41316 31563 7699 5380 23971 8252 17454 14589 19541 21812 7533 -5883 -13363 -5113 26 328 4014 452 1683 7752 2927 4685 2429 5509 294 2907 -280 -88 -4104 -1905 -1328 -5260 -4010 -1140 1743 -1159 414 -1603 -4087 -5250 -2141 -2285 -5001 -3654 -3519 -2922 -1897 -1416 -307 137 -1450 152 -1200 -1197 -721 1736 1276 1983 2235 2340 1351 916 3051 967 2170 886 1703 553 583 -1199 -772 503 380 13 378 -2 -655 361 -2505 -600 -466 -505 -3320 -5104 -4401 -2869 -5623 1302 -2668 -268 -1072 -20 1699 900000 1403 -129 -392 953 488 -422 438 1731 131 -264 -55 -1444 90 -1478 -663 -280 1624 798 3677 644 1244 -1432 1520 1783 2001 1657 2192 2236 591 279 596 2080 -233 1815 1678 1256 554 2938 1610 3200 268 2288 1035 1502 340 968 -569 2530 4010 3495 1063 780 3080 1421 3102 2812 3579 3667 1318 -1037 -2302 -811 4 66 944 129 543 2533 1052 1748 973 2222 126 1184 -111 -33 -1548 -721 -564 -2783 -2499 -812 1397 -1024 349 -1249 -2838 -3423 -1431 -1646 -3876 -2987 -3175 -3031 -2282 -1913 -436 196 -2058 205 -1619 -1681 -1067 2635 1939 2822 2996 3067 1756 1173 3699 1202 3068 1514 3324 1204 1359 -3050 -2112 1452 1124 40 1134 -5 -1799 897 -5944 SS 20241030T065914.0Z 9069.291135 167 1 50.07 2 82.84 135.15 69.15 155.39 0.00 1 0.00 1 0 17 5.839e-01 2.051e-02 3.062e-01 6.814e-03 8.694434e-01 4.010973e-03 1.142670e-02 -6.000000e+00 3.394582e-01 220.79 -2.00 4.26 -2.00 322.13 0.00e+00 7.945082e-03 1.796883e-03 1.534559e-03 -6.000000e+00 1.470411e-02 267.83 -2.00 20.00 -2.00 321.79 0.00e+00 7.398 0.010 302.00 328.00 3 -6.9459e-01 1.3153e-02 9.1627e-02 -6.0000e+00 8.3957e-01 7.4389e-01 1.8734e-02 5.6011e-02 -6.0000e+00 9.1800e-01 -9.9261e-01 2.1089e-02 3.2513e-02 -6.0000e+00 5.4136e-01 4.1181e-01 1.0219e-02 1.1700e-02 -6.0000e+00 2.3191e-01 3.1474e-04 -1.2177e-03 1.9867e-04 1.5230e-04 -6.0000e+00 1.5591e-02 7.3222e-03 5.8150e-05 12 8 8 10 0 0 97.08 16.83 0.06 0.00732 -0.00183 127 25 1 5 0 394.150 19.96 15.01 16.83 14.00 32.4 1002.89 900000 -199805 900000 -149275 900000 -231075 168123 -172471 -353 -103141 42917 -139457 -38967 -73551 -67676 72674 -43979 900000 -78445 205763 -90463 900000 -101814 92844 -40277 59660 -83183 11022 -83314 -14550 -9691 -36625 35399 -22240 75360 -13986 187752 1593 221678 -4506 57304 10085 85700 -501 49213 17803 21482 26283 26331 43799 7526 50684 15565 44736 19078 44701 6979 43082 14004 26775 8040 17869 12702 21541 15545 11919 15851 3139 17115 5609 17108 6189 16291 1599 12630 -7823 7031 -2324 2187 2802 3102 926 -2232 -15 -2310 3260 -2145 5668 -895 5776 -1783 1894 -3613 -2373 -6215 -2906 -2599 -1243 -1017 -2000 474 -2496 53 -2959 -193 -4070 -854 -3700 -1155 -2036 540 -557 -426 -433 -1470 -527 -678 743 -190 1804 161 2310 574 2204 1123 2466 -192 905 1067 1366 918 671 70 -558 643 -637 288 -68 763 -965 3 -2340 900000 -6149 900000 -2612 900000 -7390 1116 -3330 -2 -1058 285 -2440 -329 -1154 -1266 482 -849 900000 -2414 1366 -3057 900000 -3686 616 -851 515 -2660 146 -2614 -290 -232 -1260 752 -778 1000 -446 1246 56 1471 -209 1712 509 2105 -29 1764 898 1084 1343 1433 2180 609 2961 1405 3237 1849 3442 787 3260 1348 2222 848 1945 1695 3003 2384 1859 2430 583 3181 1212 3849 1423 3536 367 2314 -1599 1232 -491 530 816 1054 334 -893 -6 -1033 1454 -1052 2599 -430 2707 -846 836 -1710 -1238 -3630 -1944 -2026 -1101 -959 -1849 388 -1838 39 -2385 -148 -3394 -735 -3592 -1251 -2578 744 -816 -626 -617 -2023 -710 -950 1086 -295 2751 237 3151 778 2877 1593 3329 -266 1281 1779 2590 1912 1491 166 -1440 1749 -1801 813 -195 2112 -2544 8 -5368 SS 20241030T072912.7Z 9069.311953 178 1 50.22 2 80.39 142.07 67.97 163.13 0.00 1 0.00 1 0 25 5.260e-01 7.678e-03 1.315e-01 2.127e-03 7.310593e-01 1.203478e-03 9.803805e-03 -6.000000e+00 3.029565e-01 220.79 -2.00 4.26 -2.00 321.56 0.00e+00 2.761404e-03 4.899699e-04 1.041523e-03 -6.000000e+00 1.247338e-02 267.82 -2.00 20.00 -2.00 321.23 0.00e+00 5.714 0.005 302.00 328.00 3 -6.8016e-01 3.7221e-03 7.2667e-02 -6.0000e+00 7.4909e-01 1.5727e-01 5.4761e-03 4.7598e-02 -6.0000e+00 8.1783e-01 -1.4435e-01 6.6774e-03 2.8160e-02 -6.0000e+00 4.8230e-01 4.6842e-02 3.2688e-03 9.9638e-03 -6.0000e+00 2.0406e-01 1.8214e-03 -3.3288e-04 6.2126e-05 1.0980e-04 -6.0000e+00 1.3855e-02 6.6490e-03 5.3122e-05 11 8 0 10 0 0 -12.27 16.84 -0.03 0.00665 0.00415 373 73 1 5 0 134.600 19.96 15.03 16.84 14.80 32.6 1007.94 -206045 -181541 -146675 -190512 -157796 -206799 -83197 -193193 -68142 -190413 -94325 -145810 -97436 -117940 -57313 -80868 -46616 -59743 -25313 -42925 -39611 -23353 -32298 -9852 -52866 -5048 -59478 -22879 -56783 -7855 -33502 -4011 -9003 -7196 -17019 -12630 -8031 -12129 -2751 -4425 4915 -3614 7554 -1637 5244 -2673 4044 -821 3593 -190 1931 3336 4639 1704 3183 5490 1588 3384 -678 4871 -1187 2582 2039 6433 2124 3169 226 1650 1066 2716 2960 2693 3374 387 2040 -1505 -48 -3375 122 -1736 207 -1645 -1552 -2081 -377 -495 260 609 1088 1403 529 1021 -1452 -295 -1179 -359 -688 862 225 242 -769 -992 -1171 -299 -709 -1338 -838 -1203 -363 -130 519 -68 506 -213 -61 -361 145 -9 476 41 -245 79 418 543 721 429 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