File name: Pandora105s1_Helsinki_20241114_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20241115T002725.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20241114_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20241114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241114T075444.5Z 9084.329681 321 1 50.34 2 82.87 149.10 106.61 349.75 0.00 1 0.00 1 0 17 5.551e-01 1.783e-02 3.198e-01 8.389e-03 7.766922e-01 4.742228e-03 1.033128e-02 -6.000000e+00 3.172554e-01 218.74 -2.00 4.26 -2.00 321.88 0.00e+00 3.771905e-03 2.044477e-03 1.285855e-03 -6.000000e+00 1.324037e-02 265.14 -2.00 20.00 -2.00 321.53 0.00e+00 7.426 0.010 302.00 328.00 3 -2.4561e-01 1.5083e-02 8.7999e-02 -6.0000e+00 7.8112e-01 5.4882e-01 2.1939e-02 5.0667e-02 -6.0000e+00 8.5423e-01 -7.0117e-01 2.5165e-02 3.0227e-02 -6.0000e+00 5.0457e-01 2.8797e-01 1.2277e-02 1.0908e-02 -6.0000e+00 2.1610e-01 2.2683e-04 -9.7384e-04 2.4272e-04 1.2939e-04 -6.0000e+00 1.4698e-02 7.1583e-03 3.0322e-05 12 8 8 10 0 0 2.83 16.68 0.14 0.00716 -0.00016 93 18 1 5 0 541.210 19.85 15.01 16.68 11.37 32.2 1017.29 900000 -124533 46500 -188145 -141362 -138664 -56192 -232066 -189626 -179200 -210416 -70428 -74019 8582 -44015 9783 -12921 284448 -32676 71782 -68612 -18521 -73748 -11111 -74919 -19577 27243 -32690 29545 -21173 124967 -4745 47100 -13615 45598 -19557 29471 11300 23645 -6424 9579 15042 29618 7636 18218 20583 17798 39624 10974 38421 14476 15624 9321 27239 7989 21498 21365 17493 15183 6898 6768 12814 8524 13259 8863 2189 9448 4061 11464 7601 8937 4846 9081 7386 7425 -3116 1499 -2137 -2701 1234 804 253 -2977 219 -1493 889 -589 980 1599 4538 -256 -1740 -3841 -2330 -2707 -1506 -1596 -1297 -159 -98 -2574 -3090 -1143 -1573 -1345 -3651 -2008 -1823 -1628 -1227 -105 924 -949 -235 -61 186 -487 353 990 1835 567 1609 703 1766 1283 578 498 799 1241 1146 782 -923 -98 -484 677 -233 -376 388 412 -539 -472 -1144 900000 -1481 380 -4057 -1682 -1546 -460 -7764 -4511 -3997 -6570 -628 -880 70 -622 104 -190 2326 -668 587 -1836 -318 -2084 -200 -2696 -416 356 -749 362 -485 1022 -136 924 -501 858 -704 723 397 890 -378 525 824 1453 468 1013 1145 1048 1977 772 2231 1208 1431 991 2606 967 2356 2376 1960 1664 807 836 1687 1352 2266 1624 417 1700 820 2475 1946 2405 1375 2362 1800 1621 -688 311 -498 -751 396 301 108 -1412 106 -784 482 -338 560 892 2331 -129 -857 -1941 -1281 -1749 -1126 -1384 -1282 -164 -99 -2398 -2552 -875 -1291 -1186 -3445 -1982 -1957 -1977 -1700 -159 1446 -1504 -357 -88 264 -719 547 1610 2982 893 2389 1030 2497 1779 777 665 1197 2161 2255 1678 -2127 -238 -1151 1701 -606 -992 1026 1067 -1458 -1184 -2715 SS 20241114T080550.1Z 9084.337385 324 1 50.14 2 82.19 151.66 106.76 352.44 0.00 1 0.00 1 0 17 5.527e-01 1.467e-02 2.420e-01 5.467e-03 7.367760e-01 3.102832e-03 9.840290e-03 -6.000000e+00 3.172907e-01 218.74 -2.00 4.26 -2.00 321.76 0.00e+00 8.369887e-03 1.324241e-03 1.149449e-03 -6.000000e+00 1.341220e-02 265.14 -2.00 20.00 -2.00 321.42 0.00e+00 6.870 0.008 302.00 328.00 3 -2.9202e-01 9.7627e-03 8.1770e-02 -6.0000e+00 7.8175e-01 3.7629e-01 1.4219e-02 4.7577e-02 -6.0000e+00 8.5552e-01 -4.4233e-01 1.6811e-02 2.8091e-02 -6.0000e+00 5.0654e-01 1.7989e-01 8.1866e-03 1.0064e-02 -6.0000e+00 2.1778e-01 4.1226e-04 -7.1408e-04 1.6135e-04 1.1676e-04 -6.0000e+00 1.4732e-02 6.9829e-03 3.2418e-05 12 8 8 10 0 0 42.55 16.68 -0.05 0.00698 0.00162 131 26 1 5 0 382.680 19.85 14.99 16.68 11.62 32.2 1018.98 900000 -166197 900000 -210194 -134998 -197224 -170589 -159338 -187829 -100730 -202669 61414 -172753 900000 -130141 900000 -110746 103508 -85304 99940 -62315 22884 -35353 -6304 25736 -1218 18357 -27752 70843 -37320 -7293 -37596 86752 -48225 64732 -23599 34243 -14136 34121 9513 14467 16230 6509 20401 -7422 34386 -7208 28069 -3009 27278 775 33882 7241 19452 5117 13934 10625 9350 8190 5353 8909 1632 16573 4064 11894 786 7449 -1949 8093 2268 9528 4793 5939 4023 1750 216 -5171 500 -4892 2312 -2456 1766 -3725 705 -2395 829 -575 1987 279 737 -33 -1185 -1278 -3823 -1088 -2299 168 -1505 1374 -1615 1372 -1960 -755 -1509 -109 -1558 -1544 -1500 -1387 488 -628 397 -240 178 -1766 486 -885 721 156 722 552 1027 724 615 1325 398 420 695 1387 69 1003 -417 316 -446 471 -434 116 37 130 -78 -414 -1121 900000 -1960 900000 -3745 -1053 -2776 -1947 -1788 -3037 -735 -4087 327 -4108 900000 -3441 900000 -3244 551 -2288 532 -1426 217 -621 -88 285 -18 226 -515 522 -898 -163 -1372 1102 -2340 981 -838 793 -611 1097 452 716 842 392 1091 -537 1703 -563 1633 -253 1846 77 2700 821 2099 662 1704 1360 1180 1011 678 1162 261 2638 828 2297 165 1478 -451 1948 636 2746 1468 1722 1100 440 50 -1253 124 -1517 799 -1033 805 -1851 353 -1319 469 -344 1174 165 427 -18 -625 -674 -2271 -734 -1770 146 -1518 1423 -1664 1244 -1683 -607 -1304 -100 -1514 -1535 -1619 -1686 663 -949 616 -370 262 -2515 666 -1274 1082 249 1156 848 1498 1034 888 1852 539 565 1047 2321 132 2047 -908 723 -1103 1189 -1138 305 100 340 -200 -991 -2542 SS 20241114T081638.1Z 9084.344885 327 1 50.32 2 81.58 154.18 106.86 355.07 0.00 1 0.00 1 0 33 5.128e-01 1.129e-02 1.832e-01 4.098e-03 7.082191e-01 2.242326e-03 9.514273e-03 -6.000000e+00 2.930364e-01 218.74 -2.00 4.26 -2.00 321.51 0.00e+00 5.313374e-03 9.270776e-04 9.916319e-04 -6.000000e+00 1.216116e-02 265.14 -2.00 20.00 -2.00 321.19 0.00e+00 6.434 0.007 302.00 328.00 3 -3.1312e-01 6.9268e-03 7.6924e-02 -6.0000e+00 7.2151e-01 2.7706e-01 9.9842e-03 4.5314e-02 -6.0000e+00 7.8882e-01 -2.7979e-01 1.1820e-02 2.6494e-02 -6.0000e+00 4.6582e-01 1.0533e-01 5.8013e-03 9.3452e-03 -6.0000e+00 1.9789e-01 6.5568e-04 -6.3409e-04 1.1685e-04 9.5784e-05 -6.0000e+00 1.3506e-02 7.0289e-03 3.0600e-05 12 9 8 11 8 0 6.68 16.70 0.04 0.00703 0.00226 172 33 1 5 0 292.470 19.85 15.00 16.70 11.93 32.2 1021.08 -232565 -128215 -225490 -93403 -110350 -194079 -152559 -148423 -64457 -176400 -82959 -162461 -83007 -134517 -53003 -78999 -23508 -43448 -53797 -75234 9663 -53888 3207 -45373 -38693 -39583 -13915 -33902 -37548 -7487 -39583 3853 -18371 25410 -20574 9594 -23012 574 2668 14088 -2314 9862 8035 1892 4729 3919 12431 1592 9773 3427 11861 3082 10689 7227 10489 8487 4771 6631 7123 1249 4396 8113 1183 8909 873 5025 -1137 839 325 5598 2946 3790 1974 2848 1766 921 126 -2046 211 -341 1196 -503 -1568 -2293 -1184 -1440 269 384 1377 762 829 -437 -1081 -1338 -1266 -645 -1417 544 51 836 -554 -863 -2353 -768 -1519 -1308 -1174 -958 -757 -233 781 89 255 -335 -734 -672 354 -193 1093 99 118 346 858 556 1214 458 89 1059 813 803 210 17 -582 -292 -99 -70 31 514 128 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