File name: Pandora105s1_Helsinki_20241118_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20241119T093718.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20241118_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20241118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241118T080155.1Z 9088.334666 362 1 50.20 2 83.42 150.84 77.19 304.15 0.00 1 0.00 1 0 17 4.858e-01 2.045e-02 3.881e-01 1.063e-02 1.105725e+00 6.288040e-03 1.418311e-02 -6.000000e+00 2.795020e-01 218.57 -2.00 4.26 -2.00 322.42 0.00e+00 2.993080e-03 2.938995e-03 2.294737e-03 -6.000000e+00 1.153222e-02 264.74 -2.00 20.00 -2.00 322.08 0.00e+00 7.944 0.013 302.00 328.00 3 -1.0315e+00 2.1050e-02 1.0517e-01 -6.0000e+00 6.8882e-01 1.4464e+00 2.9420e-02 6.9913e-02 -6.0000e+00 7.5410e-01 -1.7901e+00 3.1293e-02 4.1147e-02 -6.0000e+00 4.4530e-01 7.0495e-01 1.5456e-02 1.5260e-02 -6.0000e+00 1.8813e-01 1.8135e-04 -1.6366e-03 2.7471e-04 2.0658e-04 -6.0000e+00 1.2819e-02 6.2177e-03 4.1487e-06 12 9 8 11 8 0 10.65 16.49 0.14 0.00622 -0.00608 119 23 1 5 0 421.780 19.75 15.00 16.49 8.29 31.9 963.40 -104266 59667 -77096 61112 -111029 -2228 -174072 85787 -96557 3057 87916 -149641 -27846 -65453 211987 -53919 900000 -49888 100277 -48451 55954 -77589 30523 3571 133560 98255 -35137 59508 -48511 1722 -31796 125681 -19666 126948 -28410 8487 -39237 47247 -2715 32058 12688 55179 3212 36518 -569 37295 31531 -12920 32452 25895 112129 37219 55229 32494 91340 32558 54247 41186 32629 26680 17017 38787 10173 42940 8614 25705 1099 25041 17145 32323 15622 25423 9617 6490 18808 -4554 -2548 1421 7499 7067 2414 -2728 6587 -4636 6317 1062 6645 855 5306 4721 1139 -4273 -3438 -2840 -4099 -2659 -2363 -665 -1272 467 -3265 245 -5818 2793 -3785 0 -4718 -2735 -3395 -3437 -1029 -591 302 -756 -709 -1030 -649 -193 1945 17 2746 507 3610 735 1398 1383 680 940 1516 1066 213 464 -147 11 -338 191 -303 993 -293 448 -1248 -1587 -2850 619 -1671 634 -2407 -23 -6399 889 -1729 32 911 -5218 -367 -1604 2198 -1677 900000 -1693 1040 -1553 580 -2779 374 61 1385 1019 -828 617 -1308 32 -1055 1303 -723 1316 -1119 220 -1749 1029 -115 1097 566 1659 163 1287 -28 1276 1177 -804 1379 1289 2674 2084 2806 2223 3599 2363 3150 2562 2030 1660 1200 2493 1023 3606 1072 2692 154 2986 2542 4658 2802 4112 1695 1050 2340 -647 -359 216 1314 1524 646 -888 2117 -1745 2233 412 2515 343 1975 1664 392 -1528 -1276 -1204 -2134 -1643 -1722 -555 -1150 404 -2634 163 -3752 1729 -2684 0 -3777 -2393 -3512 -4237 -1419 -795 411 -1030 -1026 -1481 -965 -301 3090 26 3945 695 4686 967 1794 1717 859 1381 2693 2221 455 1067 -368 29 -977 561 -894 2894 -837 1169 -3292 -3849 SS 20241118T081302.7Z 9088.342393 365 1 50.08 2 82.78 153.40 78.27 306.28 0.00 1 0.00 1 0 17 5.589e-01 1.806e-02 2.961e-01 7.094e-03 1.055740e+00 4.154898e-03 1.360523e-02 -6.000000e+00 3.192026e-01 218.57 -2.00 4.26 -2.00 322.32 0.00e+00 -2.419322e-03 1.933039e-03 2.121606e-03 -6.000000e+00 1.325449e-02 264.74 -2.00 20.00 -2.00 321.99 0.00e+00 7.346 0.010 302.00 328.00 3 -8.9215e-01 1.3933e-02 9.8800e-02 -6.0000e+00 7.8567e-01 1.0024e+00 2.1985e-02 6.9548e-02 -6.0000e+00 8.5900e-01 -1.2747e+00 2.5561e-02 4.3413e-02 -6.0000e+00 5.0733e-01 5.0577e-01 1.2143e-02 1.6298e-02 -6.0000e+00 2.1565e-01 3.2104e-04 -1.2863e-03 1.8518e-04 1.8662e-04 -6.0000e+00 1.4718e-02 5.8628e-03 1.9878e-05 12 8 8 10 0 0 13.46 16.50 0.01 0.00586 -0.00380 162 32 1 5 0 309.050 19.75 15.01 16.50 8.69 31.9 966.34 -83472 -158906 -61482 -181888 -142879 -123029 -115937 -208909 -139978 -225052 -173072 -217252 122656 -117111 -56456 -29377 -45489 -12385 -35610 -31715 -81688 -20820 -53571 -42301 -104545 -5670 -98032 -55344 -41884 -60574 -33679 -31236 -8362 -22199 3557 4888 4128 7145 45499 32583 64190 30301 47752 15208 20992 16079 528 32299 8167 39356 33795 39730 29298 44922 36763 47705 33112 29295 17745 35563 15522 27333 15250 30657 7941 18731 17653 14897 22216 16134 16847 14288 12033 7429 2129 -1381 7165 -2487 438 -3477 4290 2398 2782 3332 2718 3574 4181 3605 1659 2797 512 -765 -5031 -2943 -3622 -2257 -2895 -1661 -1886 -578 -1405 -2766 -2656 -2827 -1183 -1636 -2229 -3733 -2285 -1223 -230 -1148 -376 -214 -359 -743 141 533 291 1064 916 1545 1495 1843 1840 1547 -77 1265 855 961 369 -34 -467 -346 616 156 182 160 209 -509 -837 -1604 -577 -2098 -425 -2745 -1258 -851 -802 -4072 -1496 -5944 -2830 -6421 848 -2062 -674 -345 -692 -146 -542 -461 -1865 -245 -926 -731 -3287 -75 -3119 -1072 -695 -1383 -745 -821 -202 -630 71 95 89 178 944 901 1421 985 1321 568 726 589 23 1117 390 1524 1590 1979 1783 2548 2390 2904 2359 2067 1301 2066 1138 2023 1498 2990 1022 2164 2161 2040 3273 2879 3169 2767 2239 1300 345 -210 1011 -432 90 -904 1223 806 1012 1267 1096 1493 1796 1561 711 1118 198 -294 -2105 -1378 -2055 -1510 -2293 -1369 -1671 -540 -1191 -2047 -1802 -2020 -892 -1295 -1898 -3584 -2524 -1437 -304 -1646 -544 -304 -492 -1011 197 781 444 1590 1403 2203 2082 2514 2459 2000 -102 1913 1566 1852 795 -79 -1177 -941 1772 461 539 475 599 -1362 -2036 -3621 SS 20241118T082351.4Z 9088.349900 368 1 50.31 2 82.20 155.90 79.30 308.36 0.00 1 0.00 1 0 17 6.875e-01 1.586e-02 2.894e-01 5.204e-03 1.002585e+00 3.051931e-03 1.298107e-02 -6.000000e+00 3.926943e-01 218.57 -2.00 4.26 -2.00 322.24 0.00e+00 3.882903e-03 1.409717e-03 1.979260e-03 -6.000000e+00 1.630154e-02 264.74 -2.00 20.00 -2.00 321.91 0.00e+00 6.880 0.008 302.00 328.00 3 -8.3941e-01 1.0244e-02 9.3104e-02 -6.0000e+00 9.6659e-01 7.7653e-01 1.6359e-02 6.6178e-02 -6.0000e+00 1.0566e+00 -9.6606e-01 1.9572e-02 4.1270e-02 -6.0000e+00 6.2408e-01 3.8484e-01 9.2399e-03 1.5456e-02 -6.0000e+00 2.6539e-01 4.9740e-04 -8.6066e-04 1.4211e-04 1.9057e-04 -6.0000e+00 1.8093e-02 5.3307e-03 7.4770e-05 12 9 8 11 8 0 99.27 16.52 0.02 0.00533 -0.00114 208 41 1 5 0 241.830 19.75 15.00 16.52 9.05 31.8 967.90 -74750 -253913 -16881 -211742 -176111 -173608 -196535 -251333 -240613 -235653 -183315 -181180 -183662 -24161 -134987 19773 -114018 161828 -87324 47437 -89201 -13450 -71956 -49616 -77053 -63719 -56595 -66073 -48557 -67381 138 -42324 67167 -23431 78454 7840 81384 -16097 33986 32021 24993 2848 18491 14023 140 28969 -1537 43082 -3409 49851 8842 50763 13867 37878 17335 28234 13182 32047 14965 20231 7558 9395 18823 11699 17504 5047 14686 4159 16915 5828 13813 8232 12859 2956 2845 919 -1834 78 1266 2326 -393 4905 100 2219 -1171 2831 1425 2674 2541 2037 -252 -1009 -3391 -3126 -2513 -3706 -1464 -1933 611 -1734 89 -2816 -573 -2085 -1030 -2709 -1253 -2671 -1899 -1018 -988 -217 -417 -129 -1072 666 -638 598 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