File name: Pandora105s1_Helsinki_20241210_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20241211T000223.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20241210_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20241210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241210T083841.9Z 9110.360208 162 1 50.07 2 85.37 158.29 107.10 46.23 0.00 1 0.00 1 0 25 5.117e-01 7.310e-02 4.716e-01 6.591e-02 8.559061e-01 3.890910e-02 1.170201e-02 -6.000000e+00 2.975549e-01 217.68 -2.00 4.26 -2.00 321.57 0.00e+00 -3.085019e-03 1.086600e-02 6.834241e-04 -6.000000e+00 1.362299e-02 262.60 -2.00 20.00 -2.00 321.16 0.00e+00 10.435 0.029 302.00 328.00 3 -9.3737e-01 1.1347e-01 1.1680e-01 -6.0000e+00 7.3327e-01 2.1156e+00 1.2865e-01 5.0359e-02 -6.0000e+00 8.0492e-01 -1.8825e+00 8.4539e-02 2.6414e-02 -6.0000e+00 4.7164e-01 5.6760e-01 4.7427e-02 8.7558e-03 -6.0000e+00 1.9954e-01 1.6927e-05 -2.8677e-05 1.8638e-03 1.0845e-04 -6.0000e+00 1.3976e-02 7.9020e-03 1.0878e-05 12 8 8 10 0 0 39.31 16.48 0.87 0.00790 0.00769 22 4 1 5 0 2275.640 19.75 15.00 16.48 7.94 32.1 1046.98 79707 10260 900000 45579 149348 638 900000 20171 900000 53566 71401 -36321 5469 135045 -22970 113649 35206 900000 -18414 68884 -2055 75670 -57229 900000 -26814 900000 900000 93034 900000 -28752 -18243 -14542 99503 10338 1971 135743 46843 40201 10914 -34834 91334 7738 165851 -1230 223806 66445 80183 -50638 55177 -8721 37993 900000 6990 50538 -36632 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5002 -17627 3974 -11774 11525 -8754 -712 4909 5049 13368 -4134 1088 -14453 -3086 -8134 8783 -4837 13545 8380 6252 11482 8262 -1895 -5353 2460 -2203 10783 -13208 5971 -10819 4014 -8060 9485 -3474 8550 -4092 3105 -7106 -3681 2267 -7027 -1986 -4255 -3700 -9329 9114 -1890 6962 5999 4734 2508 -1871 -5772 SS 20241210T092438.4Z 9110.392111 175 1 50.97 2 83.76 168.78 102.60 56.64 0.00 1 0.00 1 0 25 4.889e-01 3.685e-02 3.958e-01 2.588e-02 7.667953e-01 1.488651e-02 1.028585e-02 -6.000000e+00 2.843048e-01 217.68 -2.00 4.26 -2.00 321.82 0.00e+00 2.858513e-03 5.823971e-03 1.023013e-03 -6.000000e+00 1.282671e-02 262.60 -2.00 20.00 -2.00 321.46 0.00e+00 8.301 0.015 302.00 328.00 3 4.3456e-01 4.6357e-02 9.4434e-02 -6.0000e+00 6.9932e-01 1.1596e+00 5.6046e-02 4.6982e-02 -6.0000e+00 7.6805e-01 -1.3116e+00 4.9559e-02 2.5887e-02 -6.0000e+00 4.5206e-01 5.0263e-01 2.6150e-02 8.9961e-03 -6.0000e+00 1.9206e-01 4.4415e-05 1.4579e-06 7.6253e-04 1.1220e-04 -6.0000e+00 1.3052e-02 6.5271e-03 4.8853e-05 12 8 8 10 0 0 98.19 16.50 0.29 0.00653 0.00654 25 5 1 5 0 2038.560 19.75 15.00 16.50 7.15 32.0 1039.42 61228 900000 -71091 37552 900000 900000 -103140 -62313 -86136 36007 102645 900000 900000 26116 900000 33729 900000 -22836 900000 16169 64118 -61171 170894 -64505 32364 3138 68826 8789 32610 96811 113824 225923 68901 61027 56041 90675 -40842 70531 10330 62021 -24122 900000 -9716 108197 6081 103151 32880 98030 173485 -1293 60012 12778 59493 11732 68587 11562 82603 -7514 76037 17735 58375 15470 46523 30689 26572 23849 -8250 21177 -6794 25410 5141 16410 3594 46183 10638 18317 -18339 -9508 1987 3374 -3501 1037 5147 -8927 5107 -7921 7115 -3708 2547 -2813 6183 -14704 -5281 -1521 -177 -1074 -3487 1401 -2195 1706 -5659 -936 -4567 -2375 -6124 -3426 -6506 -1014 -4130 -165 -336 2584 -2572 -357 -1040 -77 287 813 3784 -2535 4169 1347 7102 -309 8766 -846 754 -1052 1989 785 -561 2251 -817 1284 -131 -120 -1183 494 -1596 640 -1357 -553 1542 900000 -5060 946 900000 900000 -6776 -2866 -5188 907 2585 900000 900000 837 900000 1313 900000 -1699 900000 796 1835 -5672 4304 -6498 1260 162 1816 390 1095 2438 2867 5690 2644 2488 2151 2392 -4161 2876 904 3645 -3397 900000 -1224 4282 656 4206 2721 4350 4369 -171 4750 1762 5494 1843 6251 1900 6637 -1415 6128 2361 5660 2449 6137 5263 4780 4233 -2028 4089 -1980 6034 1572 4487 1056 8087 2360 3575 -4817 -2463 541 1076 -1381 440 2234 -4679 2468 -4588 3678 -2148 1353 -1488 2795 -7848 -2578 -790 -106 -756 -2906 1265 -2164 1557 -5029 -700 -3368 -1834 -5280 -3008 -6266 -1008 -4805 -211 -475 3688 -3834 -501 -1398 -101 391 1168 5568 -3997 5880 1866 9551 -437 11050 -1129 988 -1589 3394 1455 -1143 4703 -1870 3090 -341 -322 -3230 1342 -4321 1591 -3356 -1276 SS 20241210T093619.2Z 9110.400223 178 1 50.09 2 83.51 171.48 101.37 59.22 0.00 1 0.00 1 0 17 4.481e-01 1.714e-02 3.441e-01 1.061e-02 7.887067e-01 6.058419e-03 1.053105e-02 -6.000000e+00 2.550132e-01 217.68 -2.00 4.26 -2.00 321.99 0.00e+00 7.854252e-03 2.600068e-03 1.292935e-03 -6.000000e+00 1.062724e-02 262.60 -2.00 20.00 -2.00 321.65 0.00e+00 8.040 0.013 302.00 328.00 3 -5.8490e-01 1.9375e-02 9.3435e-02 -6.0000e+00 6.2655e-01 7.6675e-01 2.6582e-02 5.0295e-02 -6.0000e+00 6.8549e-01 -9.0786e-01 2.9272e-02 2.9096e-02 -6.0000e+00 4.0508e-01 3.6429e-01 1.4469e-02 1.0433e-02 -6.0000e+00 1.7245e-01 1.6733e-04 -1.2425e-03 3.0977e-04 1.3145e-04 -6.0000e+00 1.1803e-02 7.2435e-03 1.7950e-05 12 8 8 10 0 0 -24.71 16.50 0.11 0.00724 -0.00209 90 18 1 5 0 556.410 19.75 15.00 16.50 7.51 32.2 1042.90 -154114 -77464 -144185 -14749 -187558 -49704 -139105 -81859 -111933 11435 -148961 -101519 -56931 -69173 152402 -11154 126247 -18807 34558 -58936 7014 -56376 34956 -59506 9553 -18345 -24828 -28384 45517 57793 50319 137400 -32300 -821 46811 -23 -43651 -5688 -12016 44412 -4198 29021 32549 17853 7125 16058 47828 25883 51834 9684 47191 10695 36619 5546 20387 12799 8982 2003 8306 7523 8524 25431 7722 21286 11424 19017 6869 14358 5312 2003 733 8726 354 5559 -1225 -6173 -5644 -3599 -2221 -2962 277 -1744 116 -386 3787 -1116 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