File name: Pandora105s1_Helsinki_20250602_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20250602T223242.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20250602_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20250602 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250602T024819.9Z 9284.116897 190 1 51.39 2 81.25 59.96 106.32 345.01 0.00 1 0.00 1 0 25 4.709e-01 2.208e-02 3.929e-01 1.617e-02 8.253547e-01 9.784095e-03 1.092428e-02 -6.000000e+00 2.895339e-01 233.11 -2.00 4.26 -2.00 321.92 0.00e+00 4.467103e-03 4.055808e-03 1.199106e-03 -6.000000e+00 1.250953e-02 275.36 -2.00 20.00 -2.00 321.58 0.00e+00 6.208 0.006 302.00 328.00 3 1.7955e+00 3.1236e-02 8.3214e-02 -6.0000e+00 7.3846e-01 6.8467e-01 4.3153e-02 5.5881e-02 -6.0000e+00 8.0105e-01 -8.8480e-01 4.7130e-02 3.1076e-02 -6.0000e+00 4.6151e-01 3.6575e-01 2.3061e-02 1.0426e-02 -6.0000e+00 1.8948e-01 7.5862e-05 -1.8696e-03 4.7557e-04 1.2546e-04 -6.0000e+00 1.3027e-02 5.4294e-03 -3.0380e-05 12 8 8 10 0 0 15.64 17.07 0.34 0.00543 -0.00862 22 4 1 5 0 2335.390 20.14 15.01 17.07 18.89 34.0 988.79 -66219 -38639 -158131 900000 900000 900000 -161990 900000 900000 -199706 -157918 900000 -153298 -137410 -68640 10605 -15721 -26009 7253 -55839 900000 71721 -96143 -10690 85238 -39838 -28827 302 -74618 80069 -16925 7204 19379 94087 19715 -7193 4185 68901 57716 71992 10159 38373 45674 70722 158106 -11257 52695 -22453 28788 6652 21026 22603 58809 30946 26029 27495 32811 24667 23959 28814 22330 22944 18990 9988 811 30736 3678 6495 5717 7500 -135 9311 10192 5622 8494 2969 -6492 -1250 9975 -1507 1103 41 -1816 -3844 -1467 -2469 5305 3340 2086 1039 -1574 -2243 -3073 -429 -6489 -5115 711 1036 -1593 -1174 -2741 -848 -4006 -5337 -2046 -1746 -2798 -3548 -1146 609 1358 362 2235 -1224 1254 -2677 -327 -1088 1642 313 500 696 2750 1798 474 137 1681 666 944 1266 1188 1406 -899 -6 -61 -25 -959 -133 477 82 -464 -1514 -1043 -608 -3800 900000 900000 900000 -3309 900000 900000 -7139 -3763 900000 -5088 -4970 -1591 167 -275 -546 114 -1685 900000 1129 -4163 -216 1342 -1147 -726 5 -2820 1261 -495 198 541 1481 514 -243 139 1468 1657 2067 571 1709 2009 2424 2489 -871 2269 -2091 1746 530 1685 1922 3894 2826 2599 2878 3297 2604 2430 2722 2358 2709 2682 1694 155 4356 691 1260 1247 1839 -38 2497 2591 1377 1810 605 -1425 -280 2365 -482 400 17 -805 -1831 -749 -1307 2793 1816 1128 539 -784 -1076 -1487 -222 -4180 -3816 580 939 -1580 -1161 -2507 -671 -3068 -4394 -1756 -1562 -2683 -3724 -1327 794 1951 535 3321 -1821 1734 -3788 -468 -1660 2577 502 766 1012 3813 2449 637 178 2120 949 1565 2368 2420 3028 -2102 -15 -157 -67 -2604 -361 1264 212 -1112 -3419 SS 20250602T035149.8Z 9284.160993 224 1 45.04 2 74.02 73.07 107.51 0.55 0.00 1 0.00 1 0 25 1.894e-01 9.219e-03 1.900e-01 5.968e-03 5.067349e-01 3.286464e-03 7.020675e-03 -6.000000e+00 1.142076e-01 233.11 -2.00 4.26 -2.00 320.40 0.00e+00 1.164651e-03 9.944213e-04 3.896078e-04 -6.000000e+00 4.492088e-03 275.36 -2.00 20.00 -2.00 320.08 0.00e+00 3.571 0.001 302.00 328.00 3 3.4188e+00 9.4122e-03 4.8772e-02 -6.0000e+00 2.9044e-01 6.7189e-02 1.1370e-02 3.3097e-02 -6.0000e+00 3.1432e-01 -2.6221e-02 1.1265e-02 1.7231e-02 -6.0000e+00 1.8367e-01 4.2212e-03 5.8908e-03 5.3016e-03 -6.0000e+00 7.5756e-02 2.7140e-04 -3.1185e-04 1.7604e-04 5.2678e-05 -6.0000e+00 5.0035e-03 5.1556e-03 -5.4987e-06 12 9 1 12 1 1 99.96 17.06 0.09 0.00516 0.00281 18 4 1 5 0 2369.920 20.14 15.00 17.06 18.14 34.0 984.09 -81029 -34465 -56301 7950 -63803 -19800 -8332 125692 2124 19348 -17640 -68809 34788 -47144 32767 -36492 36071 -28960 11062 -8537 35060 8756 9051 -5108 -10044 30773 6454 -3 -6090 120 -6869 12223 8440 2034 -13351 8962 2346 894 -12142 -566 -2572 1976 1485 3244 -429 -3527 3544 -3374 -1890 -2772 -1534 -2249 2854 2955 2383 15 6316 -2519 5050 -1894 -55 2618 2132 1549 1079 1664 -951 636 -1012 2536 -611 1834 1233 921 -2916 998 -916 -3151 -2292 -991 -1253 -2346 -1254 -2068 -53 -1320 1293 730 2212 844 1436 -331 831 325 -46 -766 302 1107 954 450 -1146 -798 -1913 959 -900 -52 -1788 -694 -455 212 620 209 102 -341 122 -1182 365 -740 662 -339 14 -687 953 470 511 190 -303 815 1066 585 169 73 -927 409 -382 336 -254 799 -364 154 -649 -345 -1256 -389 -825 60 -884 -179 -76 731 23 187 -252 -1792 410 -1499 581 -1446 770 -1258 348 -346 950 304 332 -237 -529 1144 305 0 -306 6 -434 736 599 157 -1110 617 196 91 -1720 -83 -420 325 256 554 -77 -667 629 -655 -371 -582 -354 -573 745 823 694 5 1880 -806 1480 -594 -18 923 834 663 460 670 -385 263 -485 1320 -350 1048 689 492 -1475 444 -395 -1429 -1174 -576 -829 -1721 -963 -1687 -45 -1207 1205 693 2062 756 1199 -262 625 259 -42 -778 338 1356 1217 560 -1324 -840 -1997 1035 -1064 -64 -2304 -937 -660 333 1031 352 167 -529 179 -1708 535 -1147 1078 -573 24 -1101 1476 711 746 269 -417 1187 1711 1017 311 140 -1834 850 -845 751 -581 1836 -834 339 -1381 -706 SS 20250602T041752.9Z 9284.179085 237 1 50.03 2 70.89 78.47 107.41 6.97 0.00 1 0.00 1 0 25 7.399e-02 6.031e-03 6.418e-02 3.560e-03 4.361850e-01 1.941571e-03 6.152980e-03 -6.000000e+00 4.460834e-02 233.11 -2.00 4.26 -2.00 319.95 0.00e+00 7.433717e-05 5.121914e-04 2.679744e-04 -6.000000e+00 1.755096e-03 275.37 -2.00 20.00 -2.00 319.63 0.00e+00 3.018 0.001 302.00 328.00 3 2.9835e+00 5.4502e-03 4.1550e-02 -6.0000e+00 1.1344e-01 4.1272e-02 6.3405e-03 2.8295e-02 -6.0000e+00 1.2278e-01 6.5423e-03 5.5992e-03 1.4412e-02 -6.0000e+00 7.1748e-02 -1.2263e-02 2.9672e-03 4.3089e-03 -6.0000e+00 2.9584e-02 7.7821e-04 -4.6225e-04 1.0549e-04 4.2621e-05 -6.0000e+00 1.9560e-03 5.1297e-03 -7.0420e-05 10 0 0 10 0 0 99.94 17.03 -0.09 0.00513 0.00166 108 21 1 5 0 463.180 20.14 15.01 17.03 18.13 34.1 984.54 -25556 -29947 -40136 25028 -8032 22039 -27612 -8667 -11783 -20319 -26284 -14930 -11330 4168 -7031 9277 -5109 998 30 -13149 -637 -5149 -1773 -2043 -2064 3050 2141 -5961 -2588 -49 578 -1122 -187 709 343 -6999 -4133 -2262 -4365 -1001 -2822 -738 -1136 1065 -1541 1136 -1081 411 -183 2037 -509 1157 -330 318 1411 2172 1714 351 1821 -147 357 1025 1468 1980 1477 -290 -451 -1051 994 1392 1193 935 349 981 1373 913 -75 -1076 -473 -925 -850 -729 -2139 -1891 -1122 -374 -500 383 1165 514 906 527 -96 354 -92 -395 -7 575 336 -202 -382 -806 -304 6 -707 -920 -1085 -719 -274 488 263 329 118 -92 -394 -212 429 -13 146 38 -730 -211 475 309 909 250 98 969 1033 347 333 -197 -204 42 115 -315 -148 518 -217 -103 -320 -467 -441 -603 -934 296 -120 248 -550 -169 -265 -526 -728 -406 -357 136 -299 383 -257 51 2 -862 -38 -317 -113 -141 -154 230 161 -462 -187 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