File name: Pandora105s1_Helsinki_20250707_L2Fit_fout2c3d20210617p1-8.txt File generation date: 20250707T223836.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Jari Hovila Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 105 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora105_OF_v2d20201103.txt Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt Level 1 file used: Pandora105s1_Helsinki_20250707_L1_smca1c3d20210617p1-8.txt Full location name: FMI/Helsinki Short location name: Helsinki Country of location: Finland Location latitude [deg]: 60.2037 Location longitude [deg]: 24.9612 Location altitude [m]: 97 Local noon date: 20250707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction Data caveats: None First and last pixel inside fitting window: 199 340 Nominal wavelengths inside fitting window [nm]: 305.0824 305.2241 305.3658 305.5075 305.6491 305.7907 305.9323 306.0739 306.2155 306.3570 306.4986 306.6401 306.7816 306.9230 307.0645 307.2059 307.3473 307.4887 307.6300 307.7714 307.9127 308.0540 308.1953 308.3365 308.4778 308.6190 308.7602 308.9014 309.0426 309.1837 309.3248 309.4659 309.6070 309.7481 309.8892 310.0302 310.1712 310.3122 310.4532 310.5941 310.7351 310.8760 311.0169 311.1578 311.2986 311.4395 311.5803 311.7211 311.8619 312.0027 312.1434 312.2842 312.4249 312.5656 312.7063 312.8469 312.9876 313.1282 313.2688 313.4094 313.5500 313.6906 313.8311 313.9716 314.1121 314.2526 314.3931 314.5336 314.6740 314.8144 314.9548 315.0952 315.2356 315.3760 315.5163 315.6566 315.7969 315.9372 316.0775 316.2177 316.3580 316.4982 316.6384 316.7786 316.9188 317.0589 317.1991 317.3392 317.4793 317.6194 317.7595 317.8995 318.0396 318.1796 318.3196 318.4596 318.5996 318.7396 318.8795 319.0195 319.1594 319.2993 319.4392 319.5791 319.7189 319.8588 319.9986 320.1384 320.2782 320.4180 320.5577 320.6975 320.8372 320.9769 321.1166 321.2563 321.3960 321.5357 321.6753 321.8149 321.9546 322.0942 322.2338 322.3733 322.5129 322.6524 322.7919 322.9315 323.0710 323.2104 323.3499 323.4894 323.6288 323.7682 323.9076 324.0470 324.1864 324.3258 324.4651 324.6045 324.7438 324.8831 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250707T110129.2Z 9319.459366 469 1 2.98 2 38.22 193.62 131.65 70.12 0.00 1 0.00 1 0 33 1.086e-02 8.320e-03 4.908e-03 3.190e-03 1.908620e-01 1.728858e-03 2.852855e-03 -6.000000e+00 6.579883e-03 234.71 -2.00 4.26 -2.00 315.19 0.00e+00 1.546615e-04 1.373325e-04 2.247120e-05 -6.000000e+00 2.576163e-04 279.77 -2.00 20.00 -2.00 314.90 0.00e+00 1.272 0.000 302.00 328.00 3 3.2367e+00 4.5274e-03 1.7901e-02 -6.0000e+00 1.6798e-02 4.0553e-02 4.9911e-03 1.2348e-02 -6.0000e+00 1.8165e-02 -3.3229e-04 2.8374e-03 6.0033e-03 -6.0000e+00 1.0602e-02 -2.9466e-03 1.2271e-03 1.6469e-03 -6.0000e+00 4.3529e-03 4.7611e-03 -2.4912e-04 8.8428e-05 1.9568e-05 -6.0000e+00 2.8759e-04 1.0124e-02 -1.3238e-04 12 9 1 12 1 1 99.34 17.25 -0.09 0.01012 0.00825 3 13 1 5 0 741.660 20.35 15.00 17.25 999.00 -9.0 -9.00 -2424 -1283 11 1038 -2224 -168 -1236 -682 778 2959 -1969 -1299 -1986 -2211 145 -417 -281 -674 2151 594 1289 647 604 457 -30 975 2088 859 1384 2386 1670 794 1758 1359 -1837 -2109 -3591 -2195 -1978 -193 -1301 -400 -640 -489 -1193 500 -545 -188 -488 -270 1210 919 1269 417 828 1527 887 397 -60 -123 854 515 957 1996 117 -1209 -1536 -676 676 1060 193 277 236 891 445 173 -464 -996 -271 -610 -460 -515 -2067 -2035 -887 -599 -387 415 838 54 400 -133 -200 533 547 276 708 703 340 -374 -1258 -843 -666 700 -575 -500 -975 -1556 -256 332 846 353 265 -664 -390 -336 453 353 441 24 -241 -292 485 374 1094 210 769 1267 1342 1214 494 -47 -375 -334 38 -135 119 305 -264 -821 -549 -996 -744 -412 4 299 -597 -44 -346 -211 256 984 -658 -435 -735 -888 62 -186 -127 -314 1005 287 621 313 295 236 -16 527 1099 430 654 1130 827 408 942 725 -943 -1103 -2029 -1378 -1402 -144 -1019 -320 -514 -390 -957 397 -428 -144 -371 -204 945 750 1063 359 721 1328 784 347 -52 -109 771 482 929 1984 113 -1107 -1354 -591 635 1053 199 291 247 896 429 156 -396 -848 -243 -581 -469 -544 -2270 -2290 -1039 -728 -479 516 1033 65 454 -144 -205 551 596 317 857 883 436 -470 -1504 -964 -760 837 -720 -643 -1280 -2077 -350 468 1203 497 362 -864 -487 -412 559 453 589 34 -334 -400 646 485 1378 258 922 1559 1704 1587 658 -63 -512 -469 55 -198 179 459 -397 -1219 -804 -1432 SS 20250707T110544.9Z 9319.462325 472 1 27.16 2 38.35 195.20 131.18 71.16 0.00 1 0.00 1 0 25 1.023e-02 7.189e-03 2.645e-03 1.385e-03 1.904564e-01 7.489096e-04 2.848487e-03 -6.000000e+00 6.196423e-03 234.71 -2.00 4.26 -2.00 316.01 0.00e+00 -8.789293e-06 6.973584e-05 2.897313e-05 -6.000000e+00 2.426178e-04 279.77 -2.00 20.00 -2.00 315.68 0.00e+00 1.274 0.000 302.00 328.00 3 3.6643e+00 1.9759e-03 1.7924e-02 -6.0000e+00 1.5819e-02 3.6848e-02 2.1808e-03 1.2358e-02 -6.0000e+00 1.7107e-02 -3.7008e-04 1.2514e-03 6.0173e-03 -6.0000e+00 9.9842e-03 -2.8414e-03 5.5809e-04 1.6613e-03 -6.0000e+00 4.0993e-03 3.1075e-03 -4.7541e-04 3.9280e-05 1.8542e-05 -6.0000e+00 2.7086e-04 9.9434e-03 -1.5890e-04 12 9 1 12 1 1 99.99 17.26 -0.09 0.00994 0.00637 35 13 1 5 0 754.190 20.35 15.00 17.26 999.00 -9.0 -9.00 -2813 -398 1310 1024 -956 -1910 -2074 -695 436 1609 -449 -1694 -1950 -1813 183 198 10 -433 529 1347 897 350 29 239 145 1623 2389 2151 850 1345 852 910 2140 904 -2192 -3440 -3065 -2364 -1543 -1097 -1508 -854 -896 -465 -208 -146 -220 -163 -533 -104 760 321 659 587 750 1063 974 649 672 399 652 753 1167 1899 170 -501 -533 -741 610 549 282 91 403 868 544 253 -332 -795 39 -504 -329 -1037 -2266 -1862 -983 -587 -352 -6 464 335 483 153 -52 660 480 263 676 1008 309 -369 -758 -1224 -854 443 -632 -836 -840 -625 27 293 460 299 33 -312 -529 -71 154 130 699 115 -460 -178 136 66 805 80 408 1331 1187 834 289 -86 -339 110 297 -151 -91 325 -283 -392 -476 -889 -641 -94 301 214 -180 -353 -416 -156 107 394 -107 -422 -545 -569 63 72 4 -164 205 535 360 138 12 103 65 739 1043 868 324 505 340 388 965 402 -921 -1485 -1481 -1223 -941 -748 -1090 -631 -673 -346 -154 -107 -156 -112 -356 -70 540 242 519 478 619 892 827 543 553 331 566 646 1067 1783 154 -444 -441 -613 558 517 281 93 402 825 519 216 -260 -611 32 -474 -312 -1067 -2449 -2107 -1189 -696 -435 -7 567 419 553 158 -54 692 500 300 844 1262 397 -453 -931 -1400 -972 542 -840 -1066 -1115 -856 38 442 711 452 47 -405 -686 -89 198 177 944 165 -662 -250 184 93 1065 101 489 1650 1580 1173 387 -115 -468 160 457 -240 -148 536 -467 -629 -738 -1339 SS 20250707T111053.5Z 9319.465897 475 1 50.41 2 38.53 197.09 130.60 72.41 0.00 1 0.00 1 0 25 9.726e-03 7.022e-03 2.696e-04 1.450e-04 1.898092e-01 7.792134e-05 2.818213e-03 -6.000000e+00 5.892050e-03 234.71 -2.00 4.26 -2.00 315.98 0.00e+00 -1.784203e-05 7.291708e-06 2.999595e-05 -6.000000e+00 2.306783e-04 279.77 -2.00 20.00 -2.00 315.66 0.00e+00 1.277 0.000 302.00 328.00 3 -1.0648e-01 2.0561e-04 1.7883e-02 -6.0000e+00 1.5042e-02 1.6442e-02 2.2727e-04 1.2282e-02 -6.0000e+00 1.6266e-02 -1.5579e-03 1.3020e-04 5.9671e-03 -6.0000e+00 9.4933e-03 -2.3987e-03 5.7852e-05 1.6355e-03 -6.0000e+00 3.8982e-03 1.3588e-01 -2.6235e-04 4.0794e-06 1.8447e-05 -6.0000e+00 2.5746e-04 9.5110e-03 -1.3094e-04 11 8 0 10 0 0 99.23 17.27 -0.05 0.00951 0.00754 1915 373 1 5 0 26.220 20.35 15.01 17.27 999.00 -9.0 -9.00 -2431 -241 1390 1168 -689 -1895 -1957 -638 1048 1191 -710 -1944 -2165 -1728 -626 -146 -236 -9 421 1190 968 535 262 471 646 1593 1983 1662 836 1065 1012 1196 1895 621 -1823 -2683 -2824 -2462 -1568 -1112 -1248 -933 -696 -744 -156 -107 -76 -175 -481 -177 756 480 847 752 737 1020 1163 811 543 291 738 818 1243 1744 255 -416 -772 -680 604 502 280 204 360 674 505 341 -430 -592 -115 -553 -683 -1221 -2238 -1753 -998 -609 -490 45 464 221 441 165 -136 578 673 258 642 965 172 -389 -728 -1059 -576 494 -495 -715 -764 -788 -237 336 403 193 -26 -288 -399 174 260 280 600 59 -435 -204 207 218 840 193 375 1319 1138 787 349 -63 -292 119 300 -222 -52 241 -324 -435 -518 -829 -582 -60 337 257 -136 -370 -414 -151 269 310 -180 -514 -641 -573 -208 -51 -84 -3 157 456 374 204 103 195 280 700 839 716 338 426 428 539 827 268 -811 -1222 -1317 -1358 -1018 -740 -878 -674 -511 -543 -113 -77 -53 -128 -343 -127 526 354 651 600 596 841 968 666 439 237 629 751 1218 1625 247 -363 -629 -554 545 509 277 207 356 691 476 287 -363 -490 -95 -514 -701 -1255 -2411 -1976 -1205 -725 -609 56 571 277 505 171 -141 603 701 296 804 1218 223 -482 -898 -1215 -657 607 -613 -923 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