File name: Pandora105s1_Helsinki_20250825_L2Fit_fwvt1c3d20210617p1-8.txt
File generation date: 20250825T222717.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c3p1-8
Local principal investigator: Jari Hovila
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 105
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora105_OF_v2d20201103.txt
Instrument calibration file used: Pandora105s1_CF_v3d20210617.txt
Level 1 file used: Pandora105s1_Helsinki_20250825_L1_smca1c3d20210617p1-8.txt
Full location name: FMI/Helsinki
Short location name: Helsinki
Country of location: Finland
Location latitude [deg]: 60.2037
Location longitude [deg]: 24.9612
Location altitude [m]: 97
Local noon date: 20250825
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction
Data caveats: None
First and last pixel inside fitting window: 1622 1772
Nominal wavelengths inside fitting window [nm]: 492.0899 492.2105 492.3310 492.4516 492.5721 492.6927 492.8132 492.9337 493.0542 493.1746 493.2951 493.4155 493.5359 493.6563 493.7767 493.8970 494.0174 494.1377 494.2580 494.3783 494.4986 494.6189 494.7391 494.8593 494.9795 495.0997 495.2199 495.3401 495.4602 495.5803 495.7005 495.8205 495.9406 496.0607 496.1807 496.3007 496.4208 496.5407 496.6607 496.7807 496.9006 497.0205 497.1405 497.2603 497.3802 497.5001 497.6199 497.7397 497.8595 497.9793 498.0991 498.2189 498.3386 498.4583 498.5780 498.6977 498.8174 498.9370 499.0567 499.1763 499.2959 499.4155 499.5351 499.6546 499.7742 499.8937 500.0132 500.1327 500.2521 500.3716 500.4910 500.6104 500.7298 500.8492 500.9686 501.0879 501.2073 501.3266 501.4459 501.5652 501.6844 501.8037 501.9229 502.0421 502.1613 502.2805 502.3997 502.5188 502.6380 502.7571 502.8762 502.9953 503.1143 503.2334 503.3524 503.4714 503.5904 503.7094 503.8284 503.9473 504.0662 504.1852 504.3041 504.4229 504.5418 504.6606 504.7795 504.8983 505.0171 505.1359 505.2546 505.3734 505.4921 505.6108 505.7295 505.8482 505.9668 506.0855 506.2041 506.3227 506.4413 506.5599 506.6784 506.7970 506.9155 507.0340 507.1525 507.2710 507.3894 507.5079 507.6263 507.7447 507.8631 507.9815 508.0998 508.2182 508.3365 508.4548 508.5731 508.6914 508.8096 508.9279 509.0461 509.1643 509.2825 509.4007 509.5188 509.6370 509.7551 509.8732 509.9913
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250825T062746.3Z 9368.269286 180 1 45.67 2 65.51 112.77 85.37 97.90 0.00 1 0.00 1 0 15 1.800e-03 1.791e-03 1.142e-03 1.139e-03 2.331513e+03 6.877643e+01 1.728875e+02 -6.000000e+00 1.002551e+02 278.60 -2.00 20.00 -2.00 505.27 0.00e+00 4.114878e-04 3.132738e-05 2.701723e-05 -6.000000e+00 5.056120e-05 278.60 -2.00 20.00 -2.00 500.43 0.00e+00 2.215757e-01 2.293606e-02 1.720875e-02 -6.000000e+00 3.639387e-02 231.40 -2.00 4.26 -2.00 502.03 0.00e+00 2.396 0.000 489.00 513.00 1 7.2003e+00 1.7517e-03 3.7344e-03 -6.0000e+00 2.7812e-03 1.4122e-02 4.5478e-04 4.5380e-04 -6.0000e+00 7.2602e-04 1.0198e-03 1.6670e-03 1.0698e-04 2.4294e-05 -6.0000e+00 1.7251e-04 9.9262e-03 3.1860e-05 12 1 1 12 1 1 99.99 16.95 0.11 0.00993 0.02149 18 4 1 4 0 2403.250 20.04 15.00 16.95 16.39 34.1 972.42 -279 -46 42 104 270 130 216 43 108 -18 -97 -175 -69 -166 -100 -117 -101 -43 -35 130 147 252 -2 74 39 413 195 -242 110 -185 -199 7 81 -45 86 137 -140 -154 0 -105 87 226 162 108 259 401 193 101 50 -143 -189 -257 -250 -175 -110 76 -131 -48 -239 29 -97 -22 -27 -49 -101 137 156 -229 -147 -196 -201 -455 -101 -289 -151 -136 -104 -146 -23 35 36 171 262 268 132 236 -104 113 -117 20 -258 85 -100 304 -45 75 -98 -62 -159 -135 -434 -238 -144 -449 -162 -162 -100 -293 174 -278 24 -82 -5 104 378 246 358 65 225 62 178 260 229 303 108 207 -43 346 183 0 151 234 82 229 -40 -60 -182 28 16 -298 -49 -40 85 -29 51 -193 -74 -145 -102 -144 900000 -267 -45 42 105 279 135 228 46 114 -19 -100 -180 -69 -166 -100 -117 -103 -44 -37 139 155 268 -2 78 42 434 204 -254 112 -185 -197 7 82 -47 91 144 -146 -161 0 -108 90 234 169 113 272 420 201 104 51 -143 -186 -247 -242 -169 -110 77 -135 -49 -243 30 -99 -22 -28 -50 -102 138 154 -225 -143 -191 -194 -443 -99 -284 -150 -133 -101 -140 -22 33 35 164 254 258 129 231 -102 111 -115 20 -257 85 -101 306 -44 74 -96 -59 -150 -125 -401 -223 -138 -442 -162 -162 -99 -285 169 -270 24 -82 -5 105 380 249 364 66 228 62 176 254 222 296 106 204 -42 339 179 0 146 224 78 215 -37 -57 -175 28 15 -296 -49 -40 85 -29 51 -194 -73 -142 -97 -136 900000
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SQ 20250825T063320.7Z 9368.273156 182 2 5.91 2 64.88 114.11 84.72 99.10 0.00 1 0.00 1 0 15 1.340e-03 1.325e-03 2.147e-04 2.142e-04 2.153841e+03 1.285780e+01 1.588597e+02 -6.000000e+00 7.465615e+01 278.60 -2.00 20.00 -2.00 505.29 0.00e+00 3.599310e-04 5.904985e-06 2.552728e-05 -6.000000e+00 3.763419e-05 278.60 -2.00 20.00 -2.00 500.49 0.00e+00 1.963451e-01 4.302985e-03 1.675355e-02 -6.000000e+00 2.709146e-02 231.40 -2.00 4.26 -2.00 502.08 0.00e+00 2.340 0.000 489.00 513.00 1 1.9688e+00 3.2861e-04 3.6377e-03 -6.0000e+00 2.0702e-03 8.9353e-03 8.5104e-05 4.3734e-04 -6.0000e+00 5.4034e-04 1.9287e-01 9.8097e-04 1.9916e-05 2.1150e-05 -6.0000e+00 1.2832e-04 6.7612e-03 7.6297e-05 10 0 0 10 0 0 99.19 16.93 0.20 0.00676 0.01357 737 144 1 4 0 7.990 20.04 15.01 16.93 16.54 34.1 973.74 -102 68 23 148 204 104 257 132 106 139 76 19 -112 -33 -31 7 61 10 19 75 -12 58 134 74 123 210 185 -140 22 -118 -157 41 28 8 28 27 -125 -116 -63 -57 -41 42 16 30 88 53 85 94 -5 -34 -144 -245 -104 -189 -134 -133 -51 -141 -50 -13 -46 67 38 33 -63 -31 -33 -167 -259 -198 -341 -299 -197 -226 -198 -110 25 -23 -5 142 90 103 189 114 157 128 36 33 -92 -129 -69 -144 -157 -67 -27 -73 31 -152 -131 -131 -235 -145 -144 -341 -231 -108 -178 -51 -51 -97 -67 -43 21 27 176 224 202 98 185 148 157 258 253 105 214 214 80 242 267 102 177 232 119 119 155 -13 -13 6 -40 -62 12 12 17 52 -65 -80 -129 -56 -103 -162 900000 -98 67 23 156 204 106 265 138 109 141 76 19 -118 -35 -32 7 60 10 20 79 -12 61 140 78 129 221 194 -145 22 -124 -162 43 27 8 30 28 -131 -120 -64 -58 -41 43 16 31 93 55 89 96 -5 -34 -148 -245 -104 -191 -130 -132 -52 -144 -51 -13 -47 68 39 34 -64 -31 -33 -161 -248 -187 -321 -282 -188 -219 -194 -106 23 -23 -5 140 83 96 178 108 150 124 35 32 -90 -126 -67 -144 -159 -68 -27 -72 30 -143 -121 -127 -228 -133 -137 -337 -233 -108 -177 -50 -49 -95 -66 -43 21 27 181 231 210 102 191 150 157 254 248 103 211 212 79 238 262 101 173 223 112 111 144 -13 -13 6 -40 -63 13 12 17 53 -67 -81 -130 -55 -99 -155 900000
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