File name: Pandora25s1_HoustonTX_20210310_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20240926T115622.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v6d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210310_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210310T140714.2Z 7739.588359 456 1 50.44 2 71.47 105.86 61.26 141.03 0.00 1 0.00 1 0 17 2.325e-02 8.164e-03 5.446e-03 2.197e-03 2.434338e-01 1.109502e-03 2.667913e-03 -6.000000e+00 1.327235e-02 226.75 -2.00 3.24 -2.00 316.70 0.00e+00 1.404109e-04 1.397515e-04 7.839065e-05 -6.000000e+00 5.946741e-04 285.75 -2.00 20.00 -2.00 315.93 0.00e+00 3.107 0.000 302.00 328.00 3 4.4793e+00 2.8942e-03 3.2844e-02 -6.0000e+00 3.2867e-02 1.5862e-01 3.2486e-03 1.1676e-02 -6.0000e+00 3.5670e-02 -1.3463e-03 1.9073e-03 5.5941e-03 -6.0000e+00 2.1304e-02 -7.5274e-03 9.1705e-04 1.5760e-03 -6.0000e+00 9.1228e-03 2.0363e-04 1.0103e-03 6.3197e-05 1.8173e-05 -6.0000e+00 6.3195e-04 -4.4608e-03 2.7872e-04 11 9 0 11 32 0 99.99 23.23 0.49 -0.00446 0.00313 15 3 1 5 0 3361.860 25.90 20.00 23.23 28.10 18.4 1072.33 14564 3048 -4966 1155 -8102 -1675 7902 -2380 8548 -1539 -4850 -3965 -4841 1102 -4147 2117 -2170 1325 1715 3492 3138 3694 1321 558 -2174 935 -310 -2406 103 -3000 4287 -587 465 -1757 -5466 -1062 -311 -198 -208 -1028 -375 54 196 -88 913 298 -3007 -1290 233 -112 79 -1464 -311 1264 1400 1336 1265 16 510 -55 818 -3 1978 1864 -20 -383 -1728 -1079 192 581 272 1033 1407 619 1422 204 -1967 -927 -871 -537 -809 -1806 -1788 -277 -122 -855 -128 244 645 824 203 -613 -603 -453 -944 309 123 1082 1070 149 -178 -1019 -369 -404 -988 270 -743 -537 512 349 217 1326 550 -626 16 -592 -236 -553 198 80 -158 308 -32 723 199 254 -712 272 -260 411 238 -145 -310 555 -407 -45 -42 271 139 47 53 -470 -211 1912 476 -840 171 -1178 -224 1040 -385 1372 -280 -895 -753 -1032 251 -1106 573 -631 386 514 1064 968 1128 423 189 -785 338 -112 -837 33 -984 1392 -212 177 -688 -2085 -389 -123 -89 -109 -605 -234 34 128 -58 595 195 -1980 -822 145 -70 51 -1018 -224 930 1051 1019 976 13 389 -42 637 -3 1711 1678 -18 -326 -1411 -864 161 529 264 1023 1386 597 1295 174 -1583 -717 -698 -466 -764 -1836 -1896 -300 -139 -1021 -157 306 806 1002 236 -672 -623 -458 -996 345 147 1374 1409 195 -224 -1224 -428 -479 -1239 348 -994 -738 722 511 329 2008 818 -897 22 -772 -306 -738 274 117 -233 451 -46 1013 271 335 -914 347 -346 569 340 -211 -458 834 -637 -72 -69 450 232 78 86 -746 -330 SU 20210310T152945.8Z 7739.645668 834 1 9.51 2 54.93 119.69 52.55 161.12 0.00 1 0.00 1 0 17 1.006e-02 6.692e-03 4.057e-03 2.720e-03 1.781836e-01 1.391453e-03 2.007577e-03 -6.000000e+00 5.736212e-03 226.76 -2.00 3.24 -2.00 315.06 0.00e+00 1.615810e-04 1.224469e-04 2.263969e-05 -6.000000e+00 2.572921e-04 285.75 -2.00 20.00 -2.00 314.41 0.00e+00 1.735 0.000 302.00 328.00 3 4.6842e+00 3.5598e-03 1.9179e-02 -6.0000e+00 1.4205e-02 5.3089e-02 3.9609e-03 8.4686e-03 -6.0000e+00 1.5424e-02 4.5907e-04 2.2711e-03 4.1257e-03 -6.0000e+00 9.2113e-03 -4.0959e-03 1.0119e-03 1.1584e-03 -6.0000e+00 3.9391e-03 7.2914e-04 -4.5008e-04 7.7311e-05 1.5346e-05 -6.0000e+00 2.7374e-04 -3.8811e-03 -8.0855e-05 12 9 1 12 1 1 90.36 23.31 0.32 -0.00388 -0.00726 4 6 1 5 0 1865.750 25.90 20.00 23.31 29.38 18.7 1081.36 -4829 -831 -1314 -784 -2801 590 124 146 918 705 -3292 -2281 -493 291 129 3266 1087 1102 1072 1877 1482 198 35 582 482 389 -574 1197 350 191 2309 1490 836 -394 -2736 -976 -1605 161 -507 -56 -918 -161 -1042 -681 -398 -612 -1344 -1322 -447 -355 -261 -160 1348 983 633 749 1241 648 461 46 829 1646 1146 1216 350 -406 -1131 -1538 -96 937 69 358 591 173 636 -498 -650 -844 -388 -902 -487 -974 -1732 -872 -979 -488 76 4 635 735 525 -324 -487 -464 -178 389 70 793 273 81 -287 -721 -292 -375 -608 -740 -120 -631 170 66 873 965 469 -214 -119 -456 -226 -242 113 576 -173 -127 449 356 396 774 194 170 -167 427 328 -120 -285 10 85 185 -132 91 0 -50 -217 -224 -745 -1615 -282 -445 -246 -812 163 36 47 314 246 -1159 -811 -187 119 57 1485 511 527 523 931 741 99 18 306 261 215 -315 616 172 92 1134 768 452 -214 -1438 -504 -891 99 -350 -42 -725 -129 -854 -558 -324 -496 -1077 -1035 -341 -270 -205 -131 1119 840 549 656 1092 571 402 40 737 1520 1110 1210 345 -380 -1010 -1352 -87 908 71 375 617 177 624 -461 -564 -709 -333 -830 -477 -1010 -1866 -960 -1124 -581 93 6 790 894 611 -359 -510 -474 -186 429 81 975 347 102 -349 -840 -331 -435 -740 -930 -154 -832 229 91 1235 1367 651 -286 -151 -558 -275 -302 146 775 -238 -175 606 471 508 962 235 204 -208 548 432 -161 -384 14 120 269 -195 136 0 -75 -319 -324 -1066 SU 20210310T155603.1Z 7739.663924 912 1 6.12 2 50.10 125.29 51.03 168.55 0.00 1 0.00 1 0 17 1.643e-02 9.462e-03 7.179e-03 5.040e-03 1.689400e-01 2.582118e-03 1.873440e-03 -6.000000e+00 9.369563e-03 226.76 -2.00 3.24 -2.00 314.81 0.00e+00 6.014923e-04 2.177552e-04 4.913662e-05 -6.000000e+00 4.201129e-04 285.75 -2.00 20.00 -2.00 314.20 0.00e+00 1.556 0.000 302.00 328.00 3 5.1665e+00 6.5939e-03 1.7370e-02 -6.0000e+00 2.3202e-02 6.3149e-02 7.3303e-03 7.9759e-03 -6.0000e+00 2.5192e-02 -2.0215e-03 4.1992e-03 3.8682e-03 -6.0000e+00 1.5045e-02 -1.1295e-03 1.8566e-03 1.1752e-03 -6.0000e+00 6.4353e-03 5.4213e-04 -1.9122e-04 1.4268e-04 1.4631e-05 -6.0000e+00 4.4689e-04 -3.1586e-03 1.5262e-05 12 9 9 12 1 1 999.00 23.35 0.36 -0.00316 -0.00460 1 4 1 5 0 2971.960 26.00 20.00 23.35 30.61 18.7 1087.73 -13718 -108 190 1766 -3214 -1243 1616 -701 5753 -548 695 -904 3265 691 1577 -712 360 966 2804 3279 629 1600 596 -223 -1626 1144 -1914 1389 -1010 -1172 1558 1337 -261 1004 -2923 -438 -571 429 543 -1186 1135 -253 -1351 -261 -853 179 -1293 -451 267 158 1074 776 -170 1108 432 973 513 -25 -451 -896 961 779 1072 1311 197 -689 -1283 -1341 637 573 444 700 1373 422 282 -1051 -974 -1606 -1392 -1673 -248 -1149 -2137 -1174 -694 -401 575 560 -257 1063 509 -808 -243 -770 -379 -64 66 433 1175 515 132 -1177 -86 -71 -524 447 -451 -227 -162 174 404 819 535 132 -386 -1043 -1042 -463 397 28 -179 484 1035 1044 437 635 -419 721 -199 124 310 -238 129 908 -466 -535 100 502 211 438 -424 -342 -1664 -5366 -40 70 593 -1019 -378 506 -244 2039 -207 254 -340 1282 301 738 -354 180 490 1430 1702 334 837 318 -123 -935 657 -1107 745 -523 -598 801 717 -148 562 -1595 -233 -326 270 383 -923 910 -209 -1140 -219 -716 149 -1064 -360 207 123 853 641 -145 964 382 866 461 -23 -402 -801 868 734 1055 1322 198 -654 -1159 -1189 581 562 457 737 1438 435 280 -983 -854 -1363 -1207 -1552 -243 -1196 -2313 -1298 -797 -478 703 697 -322 1293 593 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