File name: Pandora25s1_HoustonTX_20210525_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20240927T003948.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v6d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210525_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210525T115443.4Z 7815.496335 339 1 50.70 2 84.58 68.84 105.62 259.47 0.00 1 0.00 1 0 17 2.066e-01 1.792e-02 8.517e-02 4.563e-03 4.355985e-01 2.374889e-03 4.762484e-03 -6.000000e+00 1.208194e-01 230.99 -2.00 3.24 -2.00 319.40 0.00e+00 1.517772e-03 6.462798e-04 8.317469e-04 -6.000000e+00 5.451626e-03 290.91 -2.00 20.00 -2.00 318.57 0.00e+00 9.220 0.009 302.00 328.00 3 -8.1290e-01 6.7477e-03 9.4145e-02 -6.0000e+00 3.0174e-01 6.9758e-01 7.9926e-03 2.3230e-02 -6.0000e+00 3.2632e-01 -4.7969e-02 6.0371e-03 1.0751e-02 -6.0000e+00 1.9403e-01 -7.0987e-03 3.1482e-03 3.1728e-03 -6.0000e+00 8.3020e-02 7.1652e-05 2.1036e-04 1.3319e-04 3.5942e-05 -6.0000e+00 5.7269e-03 -7.6596e-03 3.8187e-04 12 8 8 10 0 0 99.95 23.81 0.74 -0.00766 -0.00608 20 4 1 5 0 2534.590 26.32 20.01 23.81 32.67 20.5 1030.20 900000 107091 -38510 34452 -59435 29815 900000 -14806 46597 1074 -52555 145510 -69525 -27972 -9466 -2255 4090 34097 2868 15130 24384 11863 9310 -4737 -21997 -19016 -11682 25237 -6413 -7092 6002 22508 6825 -4905 -12832 7405 29786 7827 3252 -2319 -1066 4734 8553 2579 8302 -825 -6813 -6427 8496 -757 10176 100 -2027 -5268 2112 2789 6406 -230 2467 -3646 955 -952 43 786 -3663 1545 -4901 1772 2908 1818 497 2662 522 909 3906 39 -5388 -990 183 386 -3713 -1334 -2708 3848 -1501 -3850 860 -916 -140 2466 709 -73 95 -2866 -18 811 -480 1104 1027 -625 1325 -1996 -1023 -2150 -1363 -1181 -1694 -1134 691 6492 75 1125 767 -102 -470 25 -724 -647 -1152 -864 -1069 684 880 869 606 431 28 282 475 -68 186 -1136 -379 863 -902 -483 1119 677 19 239 147 -1775 286 900000 883 -1291 559 -2111 457 900000 -422 835 31 -2549 1208 -5075 -1665 -561 -141 261 1767 211 1039 1569 858 718 -447 -2594 -2280 -1314 1930 -635 -731 612 2223 867 -721 -1936 922 3319 1257 653 -570 -285 1265 2290 741 2281 -249 -2174 -2049 2391 -240 3152 37 -816 -2318 905 1224 2776 -106 1084 -1680 436 -477 23 458 -2256 866 -2791 956 1674 1186 355 1937 385 643 2509 24 -3167 -550 108 256 -2870 -1113 -2435 3428 -1478 -4084 915 -1014 -154 2579 708 -68 84 -2596 -17 839 -554 1379 1358 -832 1656 -2382 -1147 -2463 -1647 -1490 -2231 -1550 980 9398 120 1840 1243 -160 -700 36 -1032 -953 -1784 -1393 -1743 1084 1360 1307 880 607 39 387 693 -108 308 -1963 -668 1556 -1722 -957 2229 1374 38 480 285 -3379 524 SU 20210525T120533.0Z 7815.503854 413 1 49.93 2 82.37 70.08 107.85 260.61 0.00 1 0.00 1 0 17 9.736e-03 4.164e-03 4.573e-03 5.743e-04 3.867035e-01 2.937011e-04 4.192896e-03 -6.000000e+00 5.640422e-03 230.99 -2.00 3.24 -2.00 318.68 0.00e+00 3.625660e-04 6.391794e-05 1.174152e-04 -6.000000e+00 2.544428e-04 290.91 -2.00 20.00 -2.00 317.80 0.00e+00 6.993 0.004 302.00 328.00 3 -2.2597e+00 8.0987e-04 7.1843e-02 -6.0000e+00 1.4084e-02 4.1075e-01 9.3114e-04 1.9862e-02 -6.0000e+00 1.5229e-02 -1.7180e-02 6.3641e-04 9.1058e-03 -6.0000e+00 9.0926e-03 -8.4336e-03 3.3405e-04 2.5256e-03 -6.0000e+00 3.8749e-03 3.0737e-03 -4.8503e-04 1.6556e-05 2.7201e-05 -6.0000e+00 2.6506e-04 -3.8363e-03 2.3196e-05 10 0 0 10 0 0 99.89 23.83 0.33 -0.00384 -0.00748 684 145 1 5 0 72.240 26.32 19.98 23.83 32.76 20.5 1030.79 4568 -543 2639 524 1448 -3514 4316 1304 2448 925 -1272 399 -989 -1161 -167 277 -233 491 -655 1050 498 -196 236 70 -1149 -71 -793 -480 -928 -545 815 1427 1370 -275 -2160 -2040 -1416 -731 -762 -1143 -1130 -1042 -862 -865 -542 -486 -1188 -830 -856 -430 503 588 428 601 487 714 702 433 520 427 602 1078 1337 1372 653 -132 -464 -371 572 807 421 398 261 516 457 112 -381 -551 -252 -453 -714 -751 -1416 -1346 -927 -607 -127 151 396 568 559 432 329 344 512 305 354 602 274 -195 -360 -633 -409 -172 -446 -758 -581 -627 -292 228 211 123 73 -7 -120 103 115 49 105 94 -344 -122 112 165 341 397 194 498 474 345 246 -129 -155 64 23 55 -127 160 17 -76 -75 -247 -376 155 -21 104 20 53 -125 156 56 115 47 -67 22 -66 -93 -14 27 -24 54 -77 127 62 -25 31 10 -176 -11 -126 -72 -133 -80 132 257 273 -57 -432 -410 -295 -180 -228 -377 -409 -397 -340 -345 -216 -195 -477 -331 -343 -178 223 284 209 312 264 398 400 246 289 237 346 669 863 955 460 -88 -295 -236 393 598 342 337 220 414 357 79 -247 -370 -172 -355 -605 -674 -1376 -1379 -965 -674 -141 173 451 650 593 443 314 326 523 334 416 754 367 -259 -470 -758 -481 -208 -556 -1003 -770 -877 -415 349 332 198 115 -10 -172 146 162 70 159 145 -539 -187 174 246 504 561 262 679 699 533 389 -213 -264 110 43 102 -242 310 33 -144 -137 -448 -663 SU 20210525T120926.0Z 7815.506551 421 1 8.01 2 81.58 70.52 108.65 261.02 0.00 1 0.00 1 0 17 8.349e-02 1.013e-02 3.963e-02 5.949e-03 3.711415e-01 3.043917e-03 4.051944e-03 -6.000000e+00 4.836920e-02 230.99 -2.00 3.24 -2.00 318.30 0.00e+00 4.462554e-04 5.941887e-04 1.206966e-04 -6.000000e+00 2.182059e-03 290.91 -2.00 20.00 -2.00 317.42 0.00e+00 6.418 0.003 302.00 328.00 3 7.8069e-01 8.2784e-03 6.6131e-02 -6.0000e+00 1.2078e-01 4.0022e-01 9.4486e-03 1.8955e-02 -6.0000e+00 1.3060e-01 -1.5786e-02 6.2172e-03 8.7265e-03 -6.0000e+00 7.7974e-02 -9.8406e-03 3.2358e-03 2.3944e-03 -6.0000e+00 3.3229e-02 2.5863e-04 -7.9563e-04 1.6988e-04 2.6474e-05 -6.0000e+00 2.2732e-03 -4.3409e-03 -5.2079e-06 12 9 9 12 1 1 999.00 23.83 0.34 -0.00434 -0.01032 2 4 1 5 0 2612.530 26.32 19.99 23.83 32.87 20.5 1031.95 -34843 14168 7882 -5302 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