File name: Pandora25s1_HoustonTX_20210629_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20240927T005424.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v6d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20210629_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20210629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210629T120309.4Z 7850.502192 361 1 14.63 2 83.14 67.16 47.07 206.89 0.00 1 0.00 1 0 17 1.039e-01 1.289e-02 4.616e-02 5.549e-03 4.022808e-01 2.853826e-03 4.385292e-03 -6.000000e+00 6.039508e-02 230.52 -2.00 3.24 -2.00 318.65 0.00e+00 -1.348726e-04 6.213308e-04 6.470086e-04 -6.000000e+00 2.747300e-03 293.37 -2.00 20.00 -2.00 317.74 0.00e+00 7.638 0.005 302.00 328.00 3 2.2456e-02 7.8570e-03 7.8227e-02 -6.0000e+00 1.5059e-01 5.4529e-01 9.0708e-03 2.1001e-02 -6.0000e+00 1.6284e-01 -5.6982e-02 6.1897e-03 9.4500e-03 -6.0000e+00 9.7427e-02 6.7233e-03 3.2445e-03 2.5778e-03 -6.0000e+00 4.1629e-02 1.5785e-04 6.5278e-04 1.5953e-04 2.7960e-05 -6.0000e+00 2.8275e-03 -8.4117e-03 3.0460e-04 12 9 9 12 41 1 -1427.18 24.03 0.42 -0.00841 -0.00351 3 3 1 5 0 3611.960 26.51 19.99 24.03 33.60 21.5 1003.62 28163 12274 -42159 -6918 -43907 -2669 9369 -15904 58759 21569 -39568 30610 -36714 6263 -13374 900000 3690 7925 11056 10952 8303 -1268 4446 -461 -10651 481 -8218 12198 261 -8470 13042 4313 7778 -2954 -13394 3837 2890 -2286 2492 -654 -3504 3327 -1796 -412 3188 4673 -4070 -4829 -1877 2212 -453 -201 252 2886 3483 2557 2664 -1045 859 874 248 2774 1279 303 1229 -1052 -1398 -1489 21 2996 231 1822 1311 -1831 2434 -206 -3288 -1299 -1957 -1248 -549 -1440 -2365 1182 -1690 -1312 155 151 -357 1928 -65 1066 -1148 680 98 258 -1420 494 401 -387 161 -1518 -1020 -1074 -1428 -544 -1019 -1020 240 3174 -181 1297 726 246 -946 355 -616 331 -382 -398 -393 1054 917 1020 -89 418 -1198 811 105 83 833 -376 -264 871 -143 -740 122 781 -957 306 -16 -249 -699 771 431 -2544 -283 -2313 -95 323 -791 1616 889 -2932 1262 -3322 447 -1337 900000 375 822 1173 1215 960 -160 556 -65 -1754 75 -1379 1613 37 -1325 1844 735 1412 -608 -2882 705 590 -572 710 -220 -1315 1233 -716 -164 1235 1794 -1676 -1995 -760 891 -199 -95 125 1485 1846 1402 1485 -599 476 481 141 1650 833 211 858 -712 -913 -975 14 2238 188 1517 1091 -1508 1829 -146 -2220 -848 -1360 -957 -462 -1324 -2309 1169 -1791 -1455 176 175 -416 2153 -70 1072 -1117 649 100 283 -1710 633 538 -519 207 -1851 -1188 -1269 -1781 -701 -1360 -1410 342 4690 -285 2068 1147 376 -1388 498 -867 477 -576 -622 -620 1629 1393 1511 -129 585 -1645 1107 152 127 1323 -617 -442 1487 -255 -1370 228 1473 -1832 573 -29 -442 -1222 SS 20210629T120359.9Z 7850.502777 363 1 6.29 2 82.97 67.26 47.15 207.14 0.00 1 0.00 1 0 17 4.324e-02 6.364e-03 2.212e-02 3.307e-03 3.895841e-01 1.691287e-03 4.255043e-03 -6.000000e+00 2.500346e-02 230.52 -2.00 3.24 -2.00 318.36 0.00e+00 8.385206e-04 3.396323e-04 1.478510e-04 -6.000000e+00 1.142010e-03 293.37 -2.00 20.00 -2.00 317.44 0.00e+00 7.486 0.005 302.00 328.00 3 -1.3491e+00 4.6146e-03 7.6579e-02 -6.0000e+00 6.2307e-02 4.7093e-01 5.2805e-03 2.0208e-02 -6.0000e+00 6.7372e-02 -2.7834e-02 3.4813e-03 9.1505e-03 -6.0000e+00 4.0303e-02 -3.3007e-03 1.8193e-03 2.6455e-03 -6.0000e+00 1.7232e-02 7.5527e-04 -5.1282e-04 9.4088e-05 2.8555e-05 -6.0000e+00 1.1773e-03 -2.3130e-03 1.4089e-05 12 1 1 12 1 1 3.51 24.03 0.36 -0.00231 -0.00617 7 14 1 5 0 763.780 26.51 19.99 24.03 33.58 21.5 1003.62 -19689 17097 -15943 19322 -18847 -1587 -9144 4191 7212 -672 -13615 4637 -1265 3395 5172 -15650 2027 -733 5186 -81 5503 1828 1965 -2990 -118 404 -3392 5057 72 -679 268 4296 -1235 2250 -4583 858 -3423 -563 1197 -1212 -3173 -604 311 -1453 1192 674 -544 -1234 637 -584 415 -265 469 1604 710 284 228 1742 -362 364 358 1596 1050 1257 318 536 -816 -109 628 15 913 21 546 -152 694 -710 -645 -792 -1070 -510 -941 -1425 -1063 -709 -992 -290 -386 357 271 581 514 1371 610 445 188 384 717 682 -286 -513 301 -1199 -624 -222 -550 -1068 -399 -958 237 66 367 196 157 86 -194 60 -460 325 -357 221 -432 -131 73 28 348 692 533 758 573 190 498 -215 71 50 166 67 164 253 -46 -221 -210 -309 -738 -1002 681 -886 728 -926 -66 -447 205 380 -40 -924 288 -97 295 514 -2079 245 -97 681 -12 764 263 294 -500 -20 72 -624 825 12 -116 50 854 -281 508 -1046 188 -856 -159 392 -458 -1312 -255 134 -642 519 296 -241 -548 280 -267 200 -137 254 904 415 170 139 1047 -218 217 220 1034 733 923 236 380 -565 -76 460 12 774 19 474 -129 554 -532 -455 -552 -789 -411 -831 -1355 -1057 -728 -1067 -324 -446 418 317 663 560 1410 604 439 196 429 861 876 -384 -686 385 -1466 -734 -264 -689 -1388 -533 -1323 337 99 571 310 245 129 -280 84 -645 466 -534 341 -675 -202 110 41 501 967 727 1040 826 289 785 -348 116 84 289 121 300 467 -85 -405 -376 -540 -1272 SS 20210629T120438.3Z 7850.503221 365 1 13.37 2 82.84 67.33 47.21 207.33 0.00 1 0.00 1 0 17 1.640e-02 4.769e-03 6.897e-03 1.127e-03 3.886699e-01 5.768787e-04 4.232516e-03 -6.000000e+00 9.482325e-03 230.52 -2.00 3.24 -2.00 318.24 0.00e+00 5.428847e-04 1.112606e-04 1.044808e-04 -6.000000e+00 4.331040e-04 293.37 -2.00 20.00 -2.00 317.30 0.00e+00 7.373 0.005 302.00 328.00 3 -2.4570e+00 1.5671e-03 7.5467e-02 -6.0000e+00 2.3629e-02 4.5477e-01 1.7888e-03 2.0021e-02 -6.0000e+00 2.5551e-02 -2.7842e-02 1.1633e-03 9.0947e-03 -6.0000e+00 1.5285e-02 -3.2039e-03 6.0501e-04 2.5324e-03 -6.0000e+00 6.5347e-03 2.5706e-03 -4.7737e-04 3.1980e-05 2.8015e-05 -6.0000e+00 4.4650e-04 -1.6469e-03 3.1196e-05 12 1 1 12 1 1 93.59 24.03 0.38 -0.00165 -0.00523 61 49 1 5 0 212.830 26.51 19.99 24.03 33.58 21.5 1003.56 -11693 2285 -5408 318 -6959 -3141 132 -3234 4548 -1562 -2912 -3496 -749 -3442 -192 1536 498 -158 -100 981 -90 438 -1069 1269 -1893 42 -1768 442 -1964 -604 562 1541 1027 -102 -2657 -1602 -1376 -1104 -611 -1168 -672 -759 112 -922 -83 -147 -545 -703 -671 480 316 1244 747 1005 379 1078 613 694 402 666 659 902 1157 1424 668 -117 -496 -508 527 715 493 311 288 163 420 -180 -550 -716 -407 -464 -968 -943 -1799 -1493 -960 -511 -129 192 234 687 682 373 320 345 535 341 567 472 144 -127 -327 -886 -481 -160 -367 -806 -630 -670 -333 239 116 167 30 24 -115 191 46 67 148 13 -35 -107 153 221 437 577 363 429 451 422 331 -22 -141 122 -14 26 -150 152 34 -79 -242 -435 -394 -602 113 -297 15 -329 -142 6 -184 268 -103 -197 -259 -64 -332 -21 186 65 -22 -15 150 -14 69 -179 223 -367 8 -355 82 -358 -112 115 325 241 -25 -624 -374 -359 -342 -213 -449 -282 -336 51 -429 -38 -68 -253 -326 -313 229 154 655 423 571 226 657 384 432 245 404 415 585 825 1037 492 -86 -347 -357 400 587 422 277 255 138 343 -140 -393 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