File name: Pandora25s1_HoustonTX_20220222_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20240927T030327.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20220222_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220222T135834.9Z 8088.582349 264 1 49.26 2 77.36 109.53 62.25 227.83 0.00 1 0.00 1 0 33 1.355e+00 7.411e-02 1.683e-01 6.617e-03 4.875483e-01 3.638487e-03 6.383912e-03 -6.000000e+00 7.718443e-01 225.70 -2.00 3.24 -2.00 319.72 0.00e+00 6.305358e-02 1.147649e-03 7.042283e-03 -6.000000e+00 3.882638e-02 285.11 -2.00 20.00 -2.00 319.41 0.00e+00 4.443 0.001 302.00 328.00 3 3.9279e+00 1.0327e-02 4.7220e-02 -6.0000e+00 1.9141e+00 9.5405e-01 1.1401e-02 4.0154e-02 -6.0000e+00 2.0879e+00 -1.4667e+00 5.9534e-03 8.2815e-03 -6.0000e+00 1.2407e+00 7.3944e-01 3.4668e-03 2.4467e-02 -6.0000e+00 5.4190e-01 5.1286e-05 -4.8727e-02 1.7980e-04 5.4642e-04 -6.0000e+00 3.7942e-02 5.7395e-02 -9.2725e-03 12 8 8 10 0 0 100.00 23.92 0.64 0.05739 -0.30876 53 11 1 5 0 929.170 26.41 19.98 23.92 27.64 24.7 1100.00 -14283 675415 427128 900000 321760 361111 900000 257408 900000 155787 119018 304017 203857 294221 272275 900000 298154 535099 325006 324241 288773 189053 137981 155528 75069 89031 74652 146885 139978 97658 288407 173990 154397 142126 108802 171940 138584 116646 75793 46246 40320 57945 55119 58895 67217 79424 62185 65415 82680 66978 68815 50967 43127 38720 26343 10592 6362 -20423 -1025 1958 15030 8103 17762 16593 12697 14722 6921 10428 11621 5219 883 -5885 -13578 -14265 -9452 -11384 -20662 -8314 1127 4452 313 -4744 -8408 -129 -9678 -12602 -9115 -10756 -9951 -9176 -7983 -11242 -11898 -11389 -12058 -6182 -2979 616 -1450 923 2157 338 -3570 -3709 -1126 -3276 -4198 -3179 1925 699 1464 1833 1914 977 417 -360 1668 3140 3626 3711 4223 6287 6211 4528 3793 6062 5190 4294 1347 1897 3035 2560 1752 2034 -2004 -2130 -2169 -2864 -4110 -3163 -2718 900000 900000 -13772 4353 6790 900000 7968 4461 900000 4675 900000 4747 5309 3444 8387 7142 9719 900000 9798 3449 8258 7669 8081 10523 9340 6902 5735 5564 5328 5966 7124 9086 5813 11070 12110 11388 10394 8806 9502 9801 9287 7389 6801 8691 9177 10200 11639 13058 12469 12981 14034 13350 14033 12607 11551 10538 7473 3203 1866 -7321 -309 616 4696 3083 6998 7176 5715 6159 2965 4277 5029 2616 480 -3394 -8038 -7906 -4577 -5107 -9624 -3599 513 2313 192 -3338 -6420 -94 -8080 -11364 -8321 -10280 -9514 -8486 -6855 -9206 -9238 -8861 -10411 -5842 -3164 721 -1874 1178 2585 376 -3795 -3920 -1231 -3857 -5246 -4188 2613 1047 2354 3063 3184 1577 642 -535 2438 4732 5760 6203 7129 10258 9843 7059 5723 8653 7206 5998 2068 3180 5421 4815 3409 4054 -4282 -4730 -4903 -6569 -9561 -7183 -5896 900000 900000 SS 20220222T151113.8Z 8088.632798 303 1 49.53 2 63.08 121.01 74.84 240.08 0.00 1 0.00 1 0 17 1.128e-02 4.626e-03 2.480e-03 7.627e-04 2.513331e-01 3.824931e-04 2.816023e-03 -6.000000e+00 6.420570e-03 225.70 -2.00 3.24 -2.00 317.50 0.00e+00 1.391741e-04 5.851995e-05 5.113126e-05 -6.000000e+00 2.879025e-04 285.11 -2.00 20.00 -2.00 316.72 0.00e+00 2.196 0.000 302.00 328.00 3 3.0509e+00 1.0099e-03 2.4860e-02 -6.0000e+00 1.5865e-02 -1.7571e-02 1.1394e-03 1.1961e-02 -6.0000e+00 1.7227e-02 1.7709e-02 6.9113e-04 5.8755e-03 -6.0000e+00 1.0294e-02 -9.6955e-03 3.4522e-04 1.6700e-03 -6.0000e+00 4.4199e-03 2.1305e-03 -8.6751e-05 2.2345e-05 1.9251e-05 -6.0000e+00 3.0658e-04 -1.3737e-02 1.3785e-04 10 0 0 10 0 0 100.00 23.89 0.25 -0.01374 -0.01439 835 177 1 5 0 59.160 26.41 20.01 23.89 30.12 25.0 1100.00 -9564 571 -1673 -273 -3042 -575 1231 2182 3118 543 -692 -258 329 -147 665 60 613 -362 813 574 1004 -213 190 405 109 891 51 1101 15 223 1416 2123 1285 421 -2021 -967 -1611 -791 -695 -1079 -1019 -1007 -480 -1218 -444 -733 -658 -827 -318 -612 441 608 453 956 416 742 712 352 258 672 393 868 1076 1149 550 -153 -313 -466 332 726 419 266 244 250 696 10 -361 -595 -206 -475 -499 -677 -1441 -1338 -861 -550 -253 160 268 532 416 365 172 394 431 237 353 610 352 -221 -210 -731 -728 -329 -341 -742 -570 -600 -231 541 293 197 149 49 -253 -21 -79 12 -12 29 -305 -109 25 140 350 540 206 510 630 419 314 -44 -2 33 108 91 -107 155 -45 -131 -180 -288 -445 -1096 64 -195 -31 -313 -56 126 250 374 70 -89 -34 49 -25 129 12 129 -80 185 136 240 -51 47 105 30 253 15 290 4 55 365 589 389 131 -604 -282 -518 -296 -298 -518 -533 -551 -269 -693 -250 -414 -364 -447 -168 -326 245 363 286 634 274 498 487 241 173 447 271 641 862 939 450 -121 -230 -335 253 598 379 252 231 228 590 8 -262 -429 -154 -385 -436 -655 -1444 -1406 -963 -634 -307 201 336 643 467 388 174 385 442 258 411 785 466 -291 -270 -871 -850 -392 -425 -987 -763 -842 -340 810 465 308 234 72 -353 -29 -105 16 -17 44 -468 -166 37 206 488 745 270 663 868 598 474 -66 -3 52 176 155 -190 271 -79 -236 -314 -484 -731 SS 20220222T151551.2Z 8088.636009 306 1 17.92 2 62.22 121.86 75.69 240.75 0.00 1 0.00 1 0 25 2.278e-01 1.121e-02 4.553e-02 5.798e-03 2.518214e-01 2.915301e-03 2.794309e-03 -6.000000e+00 1.298037e-01 225.70 -2.00 3.24 -2.00 317.01 0.00e+00 -5.926775e-04 3.960023e-04 9.338152e-05 -6.000000e+00 5.817451e-03 285.11 -2.00 20.00 -2.00 316.25 0.00e+00 2.134 0.000 302.00 328.00 3 5.9392e+00 7.6277e-03 2.4306e-02 -6.0000e+00 3.2074e-01 6.8746e-02 8.5872e-03 1.1909e-02 -6.0000e+00 3.4815e-01 -6.1689e-03 5.1140e-03 5.8335e-03 -6.0000e+00 2.0804e-01 -1.7040e-03 2.5107e-03 1.7035e-03 -6.0000e+00 8.9408e-02 1.2188e-04 8.1299e-04 1.6721e-04 1.9453e-05 -6.0000e+00 6.1877e-03 -1.5997e-02 3.2781e-04 12 9 9 12 33 1 99.98 23.88 0.54 -0.01600 -0.00989 4 3 1 5 0 3548.750 26.41 20.00 23.88 30.31 24.8 1100.00 262542 12080 -9275 53 -1487 -1988 -7491 -4266 28431 -9332 -613 -4146 -2203 -357 4756 -2372 5057 3037 5443 2669 3945 -1067 -5486 -283 -5940 683 -2505 3787 -957 -1380 5868 -1135 591 -111 -6461 -2603 4818 -1178 231 -1457 -292 494 2144 29 1455 36 -2752 -1430 637 -2071 1456 -933 -433 2615 1446 1484 1912 -1482 1539 -842 -810 -2209 705 -463 137 -1232 -1021 -409 1342 1240 1545 1255 537 1071 1550 732 -3754 -1386 -115 -42 -448 -1231 -2134 1487 -575 -950 -207 425 -177 1137 795 16 -1087 -853 -1569 -746 -76 556 1050 -17 183 -353 -741 -1147 1084 379 -950 -1021 1246 772 627 1642 702 2 -564 -1592 -1400 -203 -207 -503 -83 -43 525 -48 939 703 -393 289 -131 57 175 -502 -1437 851 -397 25 711 485 -283 512 -95 -722 -37 2976 1520 -1441 7 -180 -234 -989 -613 3338 -1625 -97 -698 -404 -73 1039 -597 1236 781 1416 734 1088 -306 -1676 -87 -2018 226 -849 1145 -283 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