File name: Pandora25s1_HoustonTX_20220302_L2Fit_fout2c5d20210307p1-8.txt File generation date: 20240927T030234.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v5d20210307.txt Level 1 file used: Pandora25s1_HoustonTX_20220302_L1_smca1c5d20210307p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20220302 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0981 305.2388 305.3795 305.5202 305.6609 305.8015 305.9421 306.0828 306.2234 306.3640 306.5045 306.6451 306.7857 306.9262 307.0667 307.2072 307.3477 307.4882 307.6287 307.7691 307.9096 308.0500 308.1904 308.3308 308.4712 308.6115 308.7519 308.8922 309.0326 309.1729 309.3132 309.4535 309.5937 309.7340 309.8742 310.0144 310.1547 310.2949 310.4350 310.5752 310.7154 310.8555 310.9956 311.1358 311.2759 311.4160 311.5560 311.6961 311.8361 311.9762 312.1162 312.2562 312.3962 312.5362 312.6761 312.8161 312.9560 313.0959 313.2359 313.3758 313.5156 313.6555 313.7954 313.9352 314.0750 314.2148 314.3546 314.4944 314.6342 314.7740 314.9137 315.0535 315.1932 315.3329 315.4726 315.6123 315.7519 315.8916 316.0312 316.1709 316.3105 316.4501 316.5897 316.7292 316.8688 317.0083 317.1479 317.2874 317.4269 317.5664 317.7059 317.8454 317.9848 318.1243 318.2637 318.4031 318.5425 318.6819 318.8213 318.9606 319.1000 319.2393 319.3787 319.5180 319.6573 319.7965 319.9358 320.0751 320.2143 320.3536 320.4928 320.6320 320.7712 320.9104 321.0495 321.1887 321.3278 321.4670 321.6061 321.7452 321.8843 322.0234 322.1624 322.3015 322.4405 322.5796 322.7186 322.8576 322.9966 323.1356 323.2745 323.4135 323.5524 323.6914 323.8303 323.9692 324.1081 324.2469 324.3858 324.5247 324.6635 324.8023 324.9411 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220302T133355.3Z 8096.565223 56 1 44.37 2 80.59 103.79 84.27 108.43 0.00 1 0.00 1 0 17 7.980e-01 1.385e-02 2.533e-01 4.879e-03 6.803043e-01 2.816574e-03 7.212217e-03 -6.000000e+00 4.818861e-01 226.22 -2.00 3.24 -2.00 321.26 0.00e+00 5.941583e-03 1.434109e-03 1.594277e-03 -6.000000e+00 2.930110e-02 285.42 -2.00 20.00 -2.00 320.69 0.00e+00 5.819 0.002 302.00 328.00 3 2.5640e+00 9.8700e-03 6.6711e-02 -6.0000e+00 1.2033e+00 1.9291e-02 1.4389e-02 3.4405e-02 -6.0000e+00 1.3228e+00 -2.0829e-02 1.5380e-02 2.1727e-02 -6.0000e+00 7.6804e-01 -7.2814e-04 7.2128e-03 1.0552e-02 -6.0000e+00 3.5064e-01 6.4288e-05 -6.3746e-04 1.4528e-04 1.1582e-04 -6.0000e+00 2.4047e-02 -1.1762e-02 1.2980e-04 12 9 9 12 1 1 83.16 23.82 0.54 -0.01176 -0.01655 30 7 1 5 0 1425.710 26.32 19.99 23.82 16.93 23.8 1075.87 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -124814 900000 -142029 900000 -57882 900000 900000 900000 400638 900000 900000 -64235 21793 190208 -57046 -46233 -24042 204399 112962 -110357 900000 900000 72066 -19489 -59272 612638 178735 900000 32329 -2521 -14641 26384 47892 21369 12310 9442 -18306 -1807 44008 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-1003 -138 -120 -980 -1749 495 407 -379 -2355 1738 -1374 702 959 1418 -563 477 -726 -379 -305 -129 1029 -1401 1399 354 108 64 1442 -223 1231 413 220 -202 -1947 -1527 1593 -1200 -223 1180 803 256 -374 829 -1157 -444 SS 20220302T134253.9Z 8096.571457 61 1 49.36 2 78.70 104.99 82.47 109.56 0.00 1 0.00 1 0 25 3.387e-01 4.778e-03 1.396e-01 1.466e-03 5.879370e-01 7.995928e-04 6.209512e-03 -6.000000e+00 1.996609e-01 226.22 -2.00 3.24 -2.00 320.57 0.00e+00 2.108053e-03 3.307735e-04 7.414451e-04 -6.000000e+00 1.152734e-02 285.42 -2.00 20.00 -2.00 319.93 0.00e+00 4.929 0.001 302.00 328.00 3 1.5394e+00 2.5157e-03 5.6811e-02 -6.0000e+00 4.9623e-01 -8.1064e-02 3.3291e-03 2.9702e-02 -6.0000e+00 5.4349e-01 7.9272e-02 3.3371e-03 1.4822e-02 -6.0000e+00 3.1484e-01 -4.2998e-02 1.6543e-03 5.9435e-03 -6.0000e+00 1.4213e-01 4.7255e-04 -4.3381e-04 4.2914e-05 5.3025e-05 -6.0000e+00 9.7433e-03 -1.2262e-02 1.2940e-04 11 1 0 11 8 0 83.13 23.81 0.61 -0.01226 -0.01552 177 38 1 5 0 278.840 26.32 20.00 23.81 17.31 24.1 1079.85 900000 900000 900000 900000 900000 900000 900000 242848 900000 900000 900000 900000 205955 101072 53462 900000 80514 104608 18101 61206 26831 30993 5063 38276 -830 20357 7219 26620 17216 -6748 27711 14817 16981 -2250 -453 7898 10727 6475 1329 -5254 -1581 -25 96 -411 -1458 -418 -3713 -702 276 419 1917 1038 -1257 1337 -407 -911 -368 -2005 165 -1123 -761 -1744 772 151 211 -964 431 -1021 917 449 645 90 -728 457 1103 999 -1825 -142 -722 793 -681 -828 -1673 -490 -1025 -845 235 179 619 1015 871 866 1227 244 510 375 481 633 268 105 -117 -436 -436 -284 -460 -639 -837 -890 -516 1417 58 324 421 40 67 40 29 -44 -139 -267 -554 -337 33 -29 170 155 -39 350 365 178 -59 -163 -315 38 -231 57 -111 297 -50 15 57 52 1 900000 900000 900000 900000 900000 900000 900000 346 900000 900000 900000 900000 294 333 354 900000 555 635 278 662 419 473 106 641 -22 471 194 584 411 -220 768 549 710 -120 -23 375 553 415 109 -544 -177 -3 12 -53 -195 -57 -533 -101 41 67 333 202 -273 307 -100 -236 -98 -541 43 -293 -206 -520 253 55 80 -361 157 -388 374 208 325 48 -385 229 513 426 -751 -58 -325 406 -402 -545 -1195 -365 -809 -703 202 158 546 870 709 668 912 186 420 345 492 714 322 127 -136 -472 -445 -290 -497 -723 -987 -1101 -676 1977 88 505 659 61 98 57 41 -65 -213 -423 -882 -526 51 -43 246 218 -54 490 549 290 -102 -295 -588 74 -467 119 -237 640 -108 32 118 103 1 SS 20220302T134913.0Z 8096.575845 64 1 49.47 2 77.38 105.85 81.21 110.37 0.00 1 0.00 1 0 25 3.826e-01 4.243e-03 1.100e-01 1.027e-03 5.375029e-01 5.386130e-04 5.732933e-03 -6.000000e+00 2.216520e-01 226.22 -2.00 3.24 -2.00 320.12 0.00e+00 1.421146e-03 1.904397e-04 4.500114e-04 -6.000000e+00 1.048196e-02 285.42 -2.00 20.00 -2.00 319.44 0.00e+00 4.449 0.001 302.00 328.00 3 1.3665e+00 1.6082e-03 5.1250e-02 -6.0000e+00 5.4735e-01 -5.6030e-02 2.0119e-03 2.6386e-02 -6.0000e+00 5.9534e-01 5.3067e-02 1.8587e-03 1.3120e-02 -6.0000e+00 3.5265e-01 -3.2382e-02 9.5295e-04 4.5304e-03 -6.0000e+00 1.5321e-01 9.2427e-04 -4.0941e-04 2.9540e-05 4.4322e-05 -6.0000e+00 1.0751e-02 -1.2107e-02 1.2600e-04 10 0 0 10 0 0 67.36 23.81 0.52 -0.01211 -0.01518 272 58 1 5 0 181.830 26.32 20.00 23.81 17.72 24.1 1082.08 900000 900000 36235 900000 69923 900000 900000 137759 386377 61508 66511 55279 60437 21191 20367 7508 17834 15793 11254 11298 9102 315 5308 10262 -3535 5202 219 13794 2309 1796 4109 7777 4147 -1 -3766 3728 -33 2549 -952 -2991 -1529 -2181 -195 -2845 -528 -1500 -1950 -1911 -366 -854 621 -336 -366 837 87 315 -20 -550 -738 -206 -654 40 208 1474 511 0 136 -393 641 617 663 131 131 365 953 57 -970 -789 -362 68 -789 -838 -1509 -896 -824 -497 -74 561 554 1124 849 727 567 643 758 525 467 572 312 -152 -115 -639 -422 -659 -568 -840 -571 -811 -303 816 240 307 249 152 -150 13 6 19 -193 -150 -513 -168 -62 113 294 333 -144 359 372 86 195 -212 -166 -65 2 18 -127 88 62 100 28 -55 -134 900000 900000 165 900000 203 900000 900000 263 386 313 339 357 462 303 363 165 394 392 317 338 288 11 187 379 -163 234 11 562 104 87 227 486 308 0 -309 285 -3 244 -117 -447 -253 -391 -36 -554 -102 -299 -397 -399 -78 -180 143 -87 -104 254 28 106 -7 -193 -253 -70 -231 15 85 657 239 0 60 -178 316 350 389 81 80 213 543 29 -470 -381 -191 39 -535 -606 -1200 -751 -739 -449 -71 546 540 1053 788 628 465 533 690 517 499 694 392 -192 -144 -728 -468 -737 -648 -1021 -728 -1049 -422 1181 364 490 397 233 -226 19 8 28 -306 -239 -825 -263 -97 173 430 491 -204 519 565 139 343 -380 -311 -122 5 36 -268 188 134 211 56 -109 -257 SS 20220302T135444.1Z 8096.579677 67 1 49.52 2 76.23 106.61 80.11 111.09 0.00 1 0.00 1 0 25 1.264e-01 4.164e-03 2.958e-02 7.838e-04 4.972402e-01 4.016946e-04 5.346592e-03 -6.000000e+00 7.207665e-02 226.22 -2.00 3.24 -2.00 319.73 0.00e+00 1.181145e-03 1.241867e-04 4.039630e-04 -6.000000e+00 3.230272e-03 285.43 -2.00 20.00 -2.00 319.01 0.00e+00 4.102 0.001 302.00 328.00 3 1.2234e+00 1.1576e-03 4.7260e-02 -6.0000e+00 1.7829e-01 -4.2786e-02 1.3992e-03 2.4248e-02 -6.0000e+00 1.9353e-01 3.1631e-02 1.2000e-03 1.1912e-02 -6.0000e+00 1.1562e-01 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