File name: Pandora25s1_HoustonTX_20230405_L2Fit_fout2c6d20220503p1-8.txt File generation date: 20240927T062503.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v6d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20230405_L1_smca1c6d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20230405 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 4 for SO2 First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230405T151255.8Z 8495.633979 323 1 49.60 2 50.73 107.93 131.40 296.73 0.00 1 0.00 1 0 17 1.682e-02 7.925e-03 6.422e-03 2.999e-03 1.884854e-01 1.528670e-03 2.087880e-03 -6.000000e+00 9.687783e-03 228.68 -2.00 3.24 -2.00 316.53 0.00e+00 2.635798e-04 1.824673e-04 3.653642e-05 -6.000000e+00 4.358451e-04 287.31 -2.00 20.00 -2.00 315.73 0.00e+00 1.576 0.000 302.00 328.00 3 6.2014e+00 3.9936e-03 1.8098e-02 -6.0000e+00 2.4085e-02 1.3851e-02 4.4689e-03 8.9846e-03 -6.0000e+00 2.6091e-02 7.9503e-03 2.5940e-03 4.3710e-03 -6.0000e+00 1.5573e-02 -6.5607e-03 1.2250e-03 1.2315e-03 -6.0000e+00 6.7017e-03 1.8306e-04 4.5242e-04 8.7658e-05 1.4629e-05 -6.0000e+00 4.6023e-04 -2.8586e-02 3.1089e-04 11 8 0 10 0 0 100.00 24.62 0.56 -0.02859 -0.02519 85 18 1 5 0 583.450 27.15 20.01 24.62 32.48 28.6 1100.00 900000 3968 -4006 689 -3513 19 8139 -2691 9582 251 -3525 975 -2660 -1928 -1404 -1315 -458 705 -673 398 1192 767 -355 1326 -1527 1949 -982 59 -1177 -1947 2322 3421 796 1877 -3915 -866 -280 3621 -293 -2209 -1623 124 -724 -972 1097 348 -2278 -2071 204 -523 1485 -429 1049 1738 125 1672 1713 -483 101 -178 228 483 435 1259 -332 -244 -746 -869 934 619 608 1013 1234 -110 1828 400 -2327 -498 -724 -500 -1287 -1690 -1835 -136 -1036 -725 201 396 10 786 253 740 79 -461 -539 357 491 700 364 -207 181 -1728 -537 -973 425 -264 -945 -609 865 -158 563 380 598 40 -823 112 -243 -210 -579 -375 -133 60 833 626 207 818 -578 269 44 240 501 -259 -339 972 -163 -53 192 412 71 -241 -28 -814 -355 900000 766 -838 128 -608 3 1284 -520 1817 54 -763 205 -632 -508 -408 -409 -145 226 -225 136 409 262 -124 478 -589 750 -385 22 -406 -659 784 1209 306 723 -1492 -315 -110 1572 -154 -1341 -1052 82 -492 -666 736 234 -1534 -1351 127 -326 945 -294 739 1265 94 1263 1309 -376 77 -136 178 398 382 1148 -304 -208 -592 -670 744 546 578 996 1213 -107 1651 335 -1825 -365 -545 -410 -1168 -1663 -1902 -145 -1170 -865 249 504 13 974 296 801 80 -449 -543 383 571 877 478 -270 225 -2054 -608 -1131 521 -341 -1273 -845 1227 -235 864 589 900 58 -1105 142 -305 -272 -793 -542 -198 89 1205 880 281 1061 -728 334 57 324 701 -372 -492 1429 -251 -85 316 689 121 -404 -46 -1310 -560 SS 20230405T154012.5Z 8495.652923 336 1 48.65 2 45.18 113.19 136.42 302.58 0.00 1 0.00 1 0 17 6.352e-03 4.956e-03 9.289e-04 5.582e-04 1.621762e-01 2.860586e-04 1.832802e-03 -6.000000e+00 3.653315e-03 228.68 -2.00 3.24 -2.00 315.57 0.00e+00 1.765402e-04 2.773643e-05 1.857084e-05 -6.000000e+00 1.635761e-04 287.31 -2.00 20.00 -2.00 314.84 0.00e+00 1.417 0.000 302.00 328.00 3 3.5247e+00 7.3937e-04 1.6112e-02 -6.0000e+00 9.0832e-03 -1.4117e-02 8.2282e-04 7.7927e-03 -6.0000e+00 9.8401e-03 6.8863e-03 4.7136e-04 3.7926e-03 -6.0000e+00 5.8736e-03 -4.6088e-03 2.1276e-04 1.0639e-03 -6.0000e+00 2.5095e-03 3.3278e-03 -7.0362e-05 1.6008e-05 1.3813e-05 -6.0000e+00 1.7274e-04 -2.6945e-02 1.2007e-04 10 0 0 10 0 0 100.00 24.63 0.15 -0.02694 -0.02747 673 143 1 5 0 72.270 27.15 20.00 24.63 34.22 28.8 1100.00 -1858 -566 -853 -502 -1431 -427 262 881 1314 758 -596 -378 -180 -469 -32 -635 -74 342 441 891 748 169 884 245 224 324 363 323 189 841 1210 1502 1179 245 -1436 -1220 -1468 -534 -623 -772 -964 -884 -636 -898 -377 -493 -699 -549 -593 -248 399 507 684 797 594 635 706 527 563 561 621 930 1013 1212 514 -222 -412 -591 232 488 104 287 225 304 316 23 -307 -607 -165 -524 -777 -922 -1512 -1449 -828 -574 -199 25 279 415 316 326 89 454 287 348 480 660 307 -144 -276 -710 -506 -127 -274 -814 -494 -560 -221 412 226 195 59 -61 -222 17 82 94 124 223 -263 -84 34 171 300 514 99 712 635 454 425 5 18 168 139 38 -155 158 -24 -214 -243 -403 -571 -516 -165 -249 -134 -359 -101 66 245 378 226 -175 -112 -58 -170 -13 -259 -31 143 190 394 335 75 396 115 110 164 181 150 81 366 513 671 561 118 -654 -544 -718 -301 -399 -542 -733 -664 -488 -692 -288 -373 -540 -407 -424 -175 292 393 528 642 490 532 599 446 467 465 532 848 949 1188 498 -206 -350 -485 199 451 105 290 228 310 302 21 -261 -485 -135 -456 -755 -938 -1575 -1577 -959 -684 -249 31 348 520 366 358 92 447 293 372 564 816 388 -187 -337 -841 -569 -147 -332 -1053 -640 -756 -309 582 334 289 85 -84 -289 21 102 117 165 308 -379 -120 47 231 397 646 123 869 814 593 580 6 25 235 205 57 -241 252 -37 -341 -376 -606 -840 SS 20230405T155357.0Z 8495.662465 345 1 10.22 2 42.46 116.18 138.83 305.93 0.00 1 0.00 1 0 17 2.497e-02 1.347e-02 1.319e-02 7.727e-03 1.613283e-01 3.952737e-03 1.762474e-03 -6.000000e+00 1.437520e-02 228.68 -2.00 3.24 -2.00 315.60 0.00e+00 1.038462e-03 3.884642e-04 6.672536e-05 -6.000000e+00 6.434545e-04 287.31 -2.00 20.00 -2.00 314.89 0.00e+00 1.354 0.000 302.00 328.00 3 6.7431e+00 1.0217e-02 1.5504e-02 -6.0000e+00 3.5740e-02 3.5660e-02 1.1376e-02 7.7347e-03 -6.0000e+00 3.8709e-02 1.6097e-02 6.5168e-03 3.7014e-03 -6.0000e+00 2.3106e-02 -7.5136e-03 2.9565e-03 1.2880e-03 -6.0000e+00 9.8786e-03 1.3777e-04 1.7259e-04 2.2162e-04 1.3720e-05 -6.0000e+00 6.7886e-04 -2.7839e-02 2.8036e-04 12 9 9 12 9 1 99.90 24.63 0.42 -0.02784 -0.02654 3 4 1 5 0 2512.150 27.15 20.00 24.63 34.81 28.6 1100.00 85 3424 1554 3394 -6212 -8782 12528 -2336 11469 -4735 -1979 1235 -4717 -748 683 -4735 -1032 1323 -2010 1155 2352 5210 -347 3102 -2354 296 852 -869 -2483 -5545 2699 2000 4350 534 -4917 -1558 89 4019 188 -3516 1501 732 -1172 1151 -181 822 -2218 -2624 1716 -1038 865 -519 -680 2760 -812 1582 1434 -1082 -452 2601 514 -58 687 982 -720 -789 -1439 -716 3029 -154 -154 1635 1286 -230 1384 449 -2708 -1266 -3322 -559 -901 -2477 -2449 845 -1977 -128 639 722 479 1827 454 10 -389 -958 -2007 1379 -71 1817 674 838 25 -1516 -1731 -1313 1272 218 -1347 -264 916 -209 -277 1510 1994 288 -803 -951 -982 -1329 593 -1049 -275 982 292 54 942 165 -1183 150 -892 1364 689 -967 -398 1133 -949 -363 101 1450 -1150 1002 384 -1056 -197 23 938 435 867 -1543 -2134 2630 -619 2923 -1438 -571 348 -1525 -259 257 -1982 -428 548 -877 504 1026 2193 -155 1394 -1146 144 410 -400 -1083 -2419 1129 883 1985 254 -2302 -694 42 2088 116 -2518 1100 556 -921 892 -141 634 -1716 -1976 1213 -744 629 -400 -544 2225 -685 1323 1212 -930 -382 2143 442 -53 657 971 -713 -729 -1244 -596 2553 -145 -156 1686 1333 -235 1333 402 -2285 -1003 -2728 -487 -854 -2546 -2630 916 -2297 -154 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