File name: Pandora25s1_HoustonTX_20230831_L2Fit_fout2c9d20230101p1-8.txt File generation date: 20241218T033102.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20230831_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20230831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230831T124654.7Z 8643.532577 225 1 35.71 2 80.32 85.55 94.58 261.34 0.00 1 0.00 1 0 25 4.444e-01 1.999e-02 1.711e-01 4.353e-03 6.648769e-01 2.373536e-03 7.582799e-03 -6.000000e+00 2.615342e-01 228.98 -2.00 3.24 -2.00 321.08 0.00e+00 9.044163e-03 1.129228e-03 3.353905e-03 -6.000000e+00 1.219760e-02 294.09 -2.00 20.00 -2.00 320.37 0.00e+00 5.667 0.002 302.00 328.00 3 2.0910e+00 8.2301e-03 6.5602e-02 -6.0000e+00 6.5086e-01 2.7048e-01 1.0872e-02 3.4492e-02 -6.0000e+00 7.0487e-01 -4.1523e-01 9.2243e-03 2.1028e-02 -6.0000e+00 4.1886e-01 1.7707e-01 4.4595e-03 9.2177e-03 -6.0000e+00 1.7956e-01 1.1665e-04 -1.5765e-03 1.2219e-04 1.4122e-04 -6.0000e+00 1.2662e-02 7.8275e-03 0.0000e+00 12 9 9 12 1 1 88.95 24.76 0.30 0.00783 -0.00402 33 10 1 5 0 1049.990 27.26 20.00 24.76 32.99 30.1 1100.00 -245685 900000 -133270 32069 -119843 -32047 900000 -112129 900000 -121783 -177504 80554 -78075 -48225 -28212 -57158 14935 165337 62593 3479 61796 -7660 -58502 2090 -38775 -4122 -32055 -5523 -446 -35450 65242 39286 38002 10669 5458 45419 46456 168090 23559 13359 5904 36230 14934 28734 30524 13020 6507 861 28654 7147 29387 10347 13985 17108 15189 8400 15923 -6440 5530 749 6411 5011 5708 2543 471 5792 3862 2258 9249 4817 3868 5593 2288 -677 3637 489 -6003 -2369 1020 535 -1302 -2792 -1771 238 -200 -2742 23 59 -1553 476 -386 454 -1172 -1711 -2942 -867 -2506 -516 -1497 -1204 -942 -1712 -1310 -1641 -48 -1503 -2013 -1921 165 -1059 27 524 231 207 396 557 268 206 -2 -22 113 1663 1033 1039 973 1952 713 2101 712 898 558 200 99 876 -17 -754 26 126 -107 -643 -127 -1347 -690 -13484 900000 -3094 147 -2128 -238 900000 -1992 900000 -2633 -6650 342 -1676 -1004 -607 -1890 283 822 887 89 920 -215 -2673 57 -1601 -127 -1283 -169 -13 -1586 1366 1241 1384 526 272 1545 1694 2289 1455 1050 549 2713 1428 2488 2654 1364 744 107 2891 937 3447 1601 2272 2900 2747 1665 2993 -1477 1109 156 1312 1140 1458 745 148 1714 1150 702 2943 1802 1594 2361 986 -285 1361 171 -2098 -813 376 231 -661 -1619 -1107 155 -138 -2045 17 46 -1236 363 -281 310 -786 -1179 -2249 -739 -2458 -558 -1761 -1431 -1072 -1814 -1288 -1605 -49 -1627 -2294 -2315 210 -1491 42 832 373 326 602 821 395 315 -3 -37 188 2666 1619 1589 1448 2804 1011 3007 1118 1545 1035 391 201 1850 -39 -1752 61 301 -257 -1514 -286 -2945 -1458 SS 20230831T125506.7Z 8643.538272 229 1 49.54 2 78.54 86.55 96.26 262.34 0.00 1 0.00 1 0 25 2.249e-01 5.897e-03 9.621e-02 1.809e-03 5.897725e-01 9.642828e-04 6.311600e-03 -6.000000e+00 1.319164e-01 228.98 -2.00 3.24 -2.00 320.50 0.00e+00 2.720459e-03 3.925958e-04 2.820533e-04 -6.000000e+00 6.033778e-03 294.09 -2.00 20.00 -2.00 319.72 0.00e+00 4.863 0.001 302.00 328.00 3 1.7742e+00 3.0751e-03 5.6163e-02 -6.0000e+00 3.2741e-01 3.6254e-04 3.9822e-03 2.9148e-02 -6.0000e+00 3.5415e-01 -1.4776e-02 3.5837e-03 1.4702e-02 -6.0000e+00 2.1145e-01 -1.5436e-03 1.7959e-03 6.0138e-03 -6.0000e+00 9.0430e-02 3.8788e-04 -8.7240e-04 5.1763e-05 5.7539e-05 -6.0000e+00 6.3800e-03 7.3039e-03 0.0000e+00 11 1 0 11 8 0 15.04 24.75 0.33 0.00730 0.00075 115 24 1 5 0 430.760 27.26 20.01 24.75 33.23 30.4 1100.00 -139236 -27629 -52819 19949 -47515 -70561 900000 -65170 83037 -63377 -97322 52080 -71136 -12209 -43547 -419 -9354 28232 -6886 3229 8355 -7230 -24227 -6644 -5516 -3980 -4004 -8348 -1747 -19749 13225 8400 4116 -2727 -8568 6648 6338 21525 -2076 -1413 -4621 3658 -2866 1097 -610 691 -3018 -2340 3224 -835 5613 211 610 1264 1926 1019 2442 -2590 -183 -1495 817 192 9 980 -273 1579 564 -97 1820 1947 651 1104 -73 203 803 -123 -2284 -668 411 -634 -356 -1334 -1508 -646 -621 -1050 118 271 101 680 997 1283 1074 627 -127 572 203 199 -242 -410 -267 -541 -392 -378 -468 -1163 -825 -786 2 -103 266 279 386 132 235 396 438 224 -328 -442 -531 -7 -28 134 45 638 163 987 297 267 274 -121 86 262 -36 -268 -231 51 -194 -291 120 -265 242 -1961 -155 -404 73 -315 -587 900000 -648 223 -754 -1688 250 -1374 -171 -1008 -8 -207 486 -177 80 204 -207 -856 -217 -192 -145 -148 -315 -62 -890 514 400 232 -173 -559 380 402 1405 -203 -162 -609 479 -419 159 -91 105 -484 -384 524 -150 1045 46 143 318 509 282 686 -763 -52 -426 236 61 3 379 -112 622 220 -39 785 944 348 612 -41 109 398 -57 -1004 -291 193 -344 -220 -924 -1127 -505 -512 -917 107 251 94 613 853 1037 840 498 -110 547 216 234 -303 -519 -324 -615 -420 -405 -527 -1377 -1015 -1013 3 -151 416 453 629 211 360 589 649 342 -524 -730 -882 -11 -45 207 68 935 234 1432 463 451 492 -227 166 525 -76 -583 -512 113 -437 -644 257 -549 487 SS 20230831T130109.9Z 8643.542476 232 1 49.62 2 77.23 87.29 97.50 263.07 0.00 1 0.00 1 0 25 1.405e-01 5.529e-03 4.027e-02 1.239e-03 5.410225e-01 6.496324e-04 5.824065e-03 -6.000000e+00 8.182097e-02 228.98 -2.00 3.24 -2.00 320.05 0.00e+00 2.240929e-03 2.262629e-04 2.055648e-04 -6.000000e+00 3.763422e-03 294.09 -2.00 20.00 -2.00 319.22 0.00e+00 4.400 0.001 302.00 328.00 3 1.5950e+00 1.9599e-03 5.0960e-02 -6.0000e+00 2.0299e-01 6.6681e-04 2.4345e-03 2.6465e-02 -6.0000e+00 2.1947e-01 -1.2998e-02 2.0548e-03 1.3149e-02 -6.0000e+00 1.3153e-01 -2.5358e-03 1.0595e-03 4.7525e-03 -6.0000e+00 5.6483e-02 7.5503e-04 -8.2915e-04 3.5511e-05 4.7122e-05 -6.0000e+00 3.9370e-03 7.6787e-03 0.0000e+00 11 1 0 11 8 0 -5.23 24.76 0.29 0.00768 0.00145 174 37 1 5 0 285.140 27.26 20.00 24.76 33.48 30.3 1100.00 -79730 -10462 -44882 -9737 -42651 -58997 64089 -38212 46285 -44805 -39721 1290 -22531 -6652 -14802 -15381 -5397 7087 -3042 -2034 -3161 279 -12210 -735 -8971 -794 -8825 -3703 -5721 -8581 4774 691 3352 -1164 -2985 -205 2254 6796 130 -1276 -1249 -616 -212 -351 750 942 -2143 -910 910 393 1667 685 765 1968 417 706 140 -1332 -590 -553 303 515 1417 740 392 686 988 -78 1846 1050 671 552 219 -221 568 409 -1595 -163 -438 -327 -1030 -899 -1735 -1063 -760 -763 -75 168 327 1002 1012 1057 1149 501 555 214 72 241 -296 -500 -212 -570 -324 -323 -910 -1248 -998 -667 -46 1319 -143 158 242 393 198 622 463 164 -379 -451 -676 -281 -118 154 237 363 90 1047 493 221 76 -78 20 271 -18 -163 -62 50 -260 -275 35 -146 107 -1188 -90 -574 -84 -477 -778 296 -515 330 -785 -696 17 -467 -148 -440 -497 -176 243 -115 -80 -130 11 -585 -34 -490 -42 -515 -199 -310 -512 290 51 275 -105 -266 -18 213 733 17 -202 -221 -116 -42 -71 153 196 -467 -200 203 87 404 186 227 622 141 249 51 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