File name: Pandora25s1_HoustonTX_20231106_L2Fit_fout2c1d20220503p1-8.txt File generation date: 20231107T065844.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v1d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20231106_L1_smca1c1d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20231106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231106T134337.4Z 8710.571961 258 1 43.25 2 77.79 116.64 14.14 201.09 0.00 1 0.00 1 0 25 1.992e-01 9.377e-03 8.964e-02 3.083e-03 5.320113e-01 1.611944e-03 5.713865e-03 -6.000000e+00 1.148142e-01 225.61 -2.00 3.24 -2.00 320.12 0.00e+00 -4.671540e-04 5.683660e-04 2.328675e-04 -6.000000e+00 5.369143e-03 289.39 -2.00 20.00 -2.00 319.38 0.00e+00 4.588 0.001 302.00 328.00 3 3.1252e+00 4.8364e-03 5.2105e-02 -6.0000e+00 2.8397e-01 2.8988e-02 6.0470e-03 2.5605e-02 -6.0000e+00 3.0865e-01 -1.2335e-02 5.2822e-03 1.2746e-02 -6.0000e+00 1.8324e-01 2.9730e-03 2.7006e-03 3.6456e-03 -6.0000e+00 7.9336e-02 1.3646e-04 -3.8100e-04 8.8833e-05 4.1394e-05 -6.0000e+00 5.6106e-03 -3.4020e-02 2.3883e-04 12 9 9 12 9 1 99.86 24.79 0.34 -0.03402 -0.03688 29 7 1 5 0 1441.490 27.26 20.00 24.79 26.58 30.2 1059.91 900000 24303 -84102 900000 -73290 -51951 900000 -32617 900000 -17059 -80471 120014 -74247 22249 -38980 -17586 1706 41277 13555 7998 8701 -7769 -1844 -3719 -8957 -773 -17303 -23551 -2651 -14139 16837 -137 12182 -3140 -20971 4517 8072 41627 1003 -2316 -8113 5610 -2524 7128 3255 9226 -6142 -4652 7572 -1327 6513 -3057 2298 -117 4229 1921 5099 -4879 2661 -5013 1622 1110 1140 307 -1027 -106 -651 313 -379 1540 558 1622 1063 -175 2037 2760 -3701 1301 -253 413 -93 -2262 -1013 -440 -451 -1337 94 -82 382 567 1022 980 406 -430 -680 256 -696 869 230 -309 -197 -1163 -700 -1365 42 -556 -688 -1496 358 -308 395 632 826 81 161 297 -82 -259 -114 -208 -780 373 201 604 -175 961 -250 1050 143 639 282 11 -545 319 -124 -165 80 384 20 -396 -141 -775 291 900000 156 -1588 900000 -1123 -649 900000 -430 900000 -241 -2133 534 -2462 369 -1377 -590 53 965 439 287 320 -335 -79 -179 -490 -42 -1106 -1542 -139 -860 875 -10 863 -272 -2071 350 666 2974 127 -357 -1476 961 -487 1283 613 1668 -1294 -984 1473 -294 1467 -828 642 -36 1318 636 1689 -1772 885 -1763 552 410 467 139 -487 -49 -291 141 -185 834 332 998 656 -105 1123 1382 -1829 611 -129 239 -61 -1686 -803 -365 -394 -1243 90 -81 376 544 927 839 335 -358 -609 252 -764 1036 293 -397 -243 -1347 -760 -1493 47 -668 -859 -1965 490 -454 619 1023 1336 128 244 432 -120 -388 -177 -337 -1277 596 314 921 -261 1381 -352 1480 217 1040 488 21 -1014 610 -247 -342 168 818 43 -838 -288 -1538 560 SS 20231106T134820.0Z 8710.575231 261 1 49.54 2 76.88 117.33 14.55 205.26 0.00 1 0.00 1 0 25 7.361e-02 4.638e-03 1.247e-02 6.789e-04 4.988919e-01 3.470455e-04 5.415972e-03 -6.000000e+00 4.190790e-02 225.61 -2.00 3.24 -2.00 319.64 0.00e+00 8.377265e-04 1.054879e-04 3.387367e-04 -6.000000e+00 1.913552e-03 289.39 -2.00 20.00 -2.00 318.87 0.00e+00 4.292 0.001 302.00 328.00 3 8.1118e-01 9.9971e-04 4.8815e-02 -6.0000e+00 1.0337e-01 -5.7884e-03 1.2034e-03 2.4133e-02 -6.0000e+00 1.1215e-01 6.1236e-04 9.7719e-04 1.1804e-02 -6.0000e+00 6.7198e-02 -5.3586e-03 5.1236e-04 3.6405e-03 -6.0000e+00 2.8994e-02 1.9316e-03 -4.6988e-04 1.9189e-05 3.8222e-05 -6.0000e+00 1.9996e-03 -3.3605e-02 1.5350e-04 10 0 0 10 0 0 95.39 24.79 0.27 -0.03360 -0.03714 411 87 1 5 0 120.510 27.26 20.00 24.79 26.69 30.2 1060.65 -25712 -20012 -35447 -17279 -33331 -29496 -10314 -30228 -10225 -15704 -24290 -14067 -14476 -9191 -7129 -6800 -1789 -464 -3102 -3030 -1618 -4369 -2873 -3903 -3773 -1379 -3850 -3667 -5044 -2653 -778 -51 179 -1018 -4688 -2539 -2074 -1004 -975 -1519 -1027 -698 176 -158 807 711 -250 -162 428 -25 810 807 1028 1239 612 952 679 543 486 544 582 892 1554 1674 1067 504 255 -272 248 607 436 509 453 446 490 -3 -719 -867 -668 -646 -853 -836 -1608 -1363 -1213 -710 -329 267 392 646 690 863 306 432 337 269 351 535 287 -103 -214 -704 -611 -350 -550 -900 -556 -618 -253 -32 136 287 270 247 -23 144 105 43 -222 -157 -506 -161 5 241 306 474 179 734 656 498 472 111 -73 -26 44 -56 -189 78 -68 -147 -122 -173 -311 -362 -306 -672 -263 -546 -460 -145 -599 -189 -332 -580 -335 -422 -315 -292 -297 -82 -23 -169 -174 -94 -263 -179 -269 -281 -106 -309 -283 -382 -206 -68 -5 20 -124 -568 -299 -269 -142 -169 -316 -239 -173 42 -39 198 178 -64 -42 113 -7 245 270 374 485 238 383 282 226 198 219 242 404 783 874 581 266 138 -150 139 389 291 356 317 298 321 -2 -395 -502 -393 -442 -636 -705 -1410 -1263 -1137 -709 -346 289 423 674 671 820 276 389 331 284 402 659 384 -132 -273 -863 -690 -396 -673 -1118 -724 -816 -358 -48 211 466 436 382 -35 215 156 64 -351 -250 -821 -255 8 370 450 699 254 1048 981 794 817 196 -135 -47 86 -113 -391 158 -139 -304 -242 -336 -587 SS 20231106T135429.1Z 8710.579503 264 1 49.51 2 75.70 118.25 15.18 210.37 0.00 1 0.00 1 0 25 5.005e-02 4.690e-03 7.825e-03 5.843e-04 4.648632e-01 2.969663e-04 5.056614e-03 -6.000000e+00 2.850268e-02 225.61 -2.00 3.24 -2.00 319.31 0.00e+00 6.983146e-04 8.048494e-05 1.786937e-04 -6.000000e+00 1.301264e-03 289.39 -2.00 20.00 -2.00 318.50 0.00e+00 3.960 0.001 302.00 328.00 3 8.8770e-01 8.3729e-04 4.5105e-02 -6.0000e+00 7.0305e-02 -2.1041e-03 9.8981e-04 2.2285e-02 -6.0000e+00 7.6268e-02 -1.3196e-03 7.6094e-04 1.0973e-02 -6.0000e+00 4.5699e-02 -4.3467e-03 4.0177e-04 3.2732e-03 -6.0000e+00 1.9723e-02 2.5400e-03 -2.5388e-04 1.6633e-05 3.5539e-05 -6.0000e+00 1.3595e-03 -3.4388e-02 1.8788e-04 10 0 0 10 0 0 82.35 24.78 0.26 -0.03439 -0.03630 474 101 1 5 0 104.430 27.26 20.00 24.78 26.99 30.2 1062.88 -25863 -14343 -15266 -11571 -19861 -20197 -9615 -17792 -7012 -12828 -16990 -10052 -11853 -7887 -5398 -370 -2398 281 -1111 -828 -1153 -714 -1386 -1602 -3164 -1485 -2488 -3182 -2807 -2384 -27 393 973 -487 -2336 -3176 -2718 -615 -904 -1120 -876 -510 -379 163 213 45 -561 -334 -314 -95 828 752 665 1107 896 970 969 518 622 457 658 708 1550 1737 1220 385 122 -424 130 560 362 526 198 457 385 33 -504 -609 -573 -516 -746 -905 -1682 -1543 -1028 -784 -286 109 386 647 667 658 396 341 278 181 243 471 221 -186 -246 -631 -672 -280 -557 -933 -614 -670 -241 451 180 218 270 237 -2 168 172 80 -39 -146 -491 -197 -22 172 312 498 171 832 602 523 334 36 -34 95 -27 -22 -225 81 -61 -170 -145 -225 -289 -555 -313 -355 -249 -423 -425 -198 -457 -184 -384 -547 -330 -476 -373 -276 -21 -151 19 -80 -62 -90 -56 -113 -143 -310 -151 -259 -320 -271 -238 -3 49 127 -68 -318 -432 -406 -107 -193 -285 -231 -143 -111 48 64 14 -172 -103 -99 -31 293 294 263 469 401 450 462 248 291 212 314 368 836 1029 750 228 70 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