File name: Pandora25s1_HoustonTX_20240109_L2Fit_fout2c1d20220503p1-8.txt File generation date: 20240113T032845.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v1d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20240109_L1_smca1c1d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20240109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240109T140745.7Z 8774.588724 97 1 49.44 2 81.29 121.74 68.49 144.61 0.00 1 0.00 1 0 25 5.335e-01 7.293e-03 2.136e-01 1.886e-03 8.253252e-01 1.032832e-03 8.503682e-03 -6.000000e+00 3.048697e-01 224.33 -2.00 3.24 -2.00 321.47 0.00e+00 3.552080e-03 5.675675e-04 9.911834e-04 -6.000000e+00 1.407561e-02 285.24 -2.00 20.00 -2.00 320.94 0.00e+00 6.231 0.003 302.00 328.00 3 3.5187e-01 3.7661e-03 7.3773e-02 -6.0000e+00 7.5156e-01 1.1207e-01 5.7369e-03 4.1727e-02 -6.0000e+00 8.1826e-01 -1.0270e-01 6.2849e-03 2.3683e-02 -6.0000e+00 4.8833e-01 2.8057e-02 2.8907e-03 9.8720e-03 -6.0000e+00 2.1051e-01 3.3728e-04 -4.1960e-04 4.9139e-05 1.1126e-04 -6.0000e+00 1.4899e-02 -2.3612e-02 7.2253e-05 11 8 0 10 0 0 18.42 21.53 0.32 -0.02361 -0.02676 237 50 1 5 0 208.570 24.56 20.00 21.53 11.51 29.4 977.99 -137072 900000 -318237 900000 -271527 5896 900000 -201398 -83819 -197589 -153669 -86599 -85828 -114699 -34693 900000 95302 -68602 15969 -29208 9032 -54024 -83029 -49572 -41344 -8342 -55603 -14954 -75460 16712 -20494 12558 -16683 7705 -32789 22296 -11331 29888 5794 -2907 1772 -141 3777 -1420 11493 -2842 1008 -5087 8881 917 4715 902 -1388 5415 2821 4633 1484 2463 -1977 3856 791 2885 497 5444 1635 1503 1647 -1730 3818 814 3852 2119 1904 -547 3005 -807 -3698 -2970 438 696 -1333 -325 -2074 -763 -1075 -12 -659 514 -235 1358 514 435 -464 -368 -596 -678 202 237 572 -105 -10 -1083 -680 -781 -409 -1088 -848 -1026 -732 1744 379 277 185 349 -248 187 -195 110 -342 217 -230 -74 208 360 259 370 93 287 387 59 340 -196 -387 -152 -213 -144 -60 378 99 214 68 -76 -489 -252 900000 -4308 900000 -2133 11 900000 -1043 -154 -1255 -693 -246 -330 -805 -145 900000 175 -676 75 -229 50 -569 -1263 -605 -511 -79 -874 -155 -1475 151 -343 189 -401 157 -975 388 -311 659 186 -124 82 -7 200 -82 597 -177 63 -365 601 75 425 89 -157 633 364 620 212 347 -282 509 112 450 93 1117 375 346 386 -447 978 250 1264 737 651 -179 857 -215 -1040 -810 134 258 -601 -168 -1130 -438 -661 -8 -449 355 -163 889 317 255 -270 -227 -424 -571 187 253 630 -117 -11 -1085 -612 -696 -388 -1100 -905 -1188 -886 2359 555 439 300 553 -378 274 -289 170 -560 363 -378 -116 311 520 382 529 130 421 616 103 661 -395 -833 -333 -500 -356 -144 920 240 523 155 -170 -1049 SS 20240109T142123.9Z 8774.598193 102 1 49.53 2 78.79 123.71 66.90 147.24 0.00 1 0.00 1 0 25 2.328e-01 4.431e-03 6.490e-02 8.372e-04 6.833741e-01 4.363239e-04 7.159409e-03 -6.000000e+00 1.316610e-01 224.33 -2.00 3.24 -2.00 320.64 0.00e+00 1.326102e-03 1.858764e-04 4.082552e-04 -6.000000e+00 5.940780e-03 285.24 -2.00 20.00 -2.00 320.01 0.00e+00 4.967 0.001 302.00 328.00 3 2.6468e-01 1.3835e-03 5.9116e-02 -6.0000e+00 3.2430e-01 4.8773e-02 1.8481e-03 3.3080e-02 -6.0000e+00 3.5263e-01 -2.5599e-02 1.8408e-03 1.7136e-02 -6.0000e+00 2.1095e-01 -2.8847e-03 9.0686e-04 6.0040e-03 -6.0000e+00 9.0722e-02 1.3933e-03 -1.3620e-04 2.2268e-05 6.1063e-05 -6.0000e+00 6.3252e-03 -2.3967e-02 7.2728e-05 10 0 0 10 0 0 -2.50 21.50 0.29 -0.02397 -0.02499 510 108 1 5 0 97.100 24.56 20.00 21.50 12.51 29.9 983.71 32219 -81604 -99292 -64029 -83762 -97258 -36505 -91390 -24513 -79915 -74328 -53937 -57438 -40244 -35879 30975 -20280 -8897 -19264 -2588 -17423 -8010 -27402 -8407 -13405 -6815 -14560 -11350 -18073 -13781 -1937 -4004 -911 -2825 -6707 -5424 -3957 38 -982 -2855 1250 -123 -378 148 323 -241 -2267 -247 -439 -319 254 1331 493 1805 1192 1653 1089 134 545 529 938 573 1973 2422 1879 193 1 -664 556 825 792 789 414 745 482 24 -1568 -1478 -805 -785 -1089 -810 -1524 -1501 -827 -675 112 266 749 810 919 513 299 155 64 169 255 763 413 32 -125 -643 -809 -386 -675 -876 -714 -623 -345 588 243 335 216 130 -9 58 -6 -42 -35 -66 -313 -208 222 231 284 261 2 438 333 304 125 -50 -191 -131 -102 -35 -173 160 52 17 19 -59 -193 47 -440 -689 -303 -451 -611 -140 -709 -112 -698 -661 -462 -601 -463 -503 296 -336 -147 -386 -47 -375 -159 -712 -202 -371 -189 -444 -327 -558 -453 -69 -176 -45 -140 -333 -269 -218 2 -79 -281 134 -14 -47 19 42 -32 -317 -33 -62 -49 43 254 105 414 293 425 291 36 141 135 248 169 611 843 692 71 0 -257 237 405 400 415 215 363 230 10 -644 -622 -381 -413 -675 -538 -1118 -1169 -684 -594 96 235 656 724 764 402 227 122 57 164 271 925 517 41 -156 -723 -880 -420 -745 -1024 -880 -779 -472 851 374 546 356 208 -14 88 -9 -66 -56 -111 -517 -330 353 356 420 372 2 627 537 530 229 -95 -380 -277 -219 -76 -387 362 117 37 40 -123 -389 SS 20240109T142737.1Z 8774.602513 105 1 49.45 2 77.68 124.64 66.21 148.48 0.00 1 0.00 1 0 25 2.473e-01 4.461e-03 8.893e-02 6.389e-04 6.324504e-01 3.295793e-04 6.700087e-03 -6.000000e+00 1.398500e-01 224.33 -2.00 3.24 -2.00 320.30 0.00e+00 1.351146e-03 1.254451e-04 3.324259e-04 -6.000000e+00 6.310394e-03 285.24 -2.00 20.00 -2.00 319.65 0.00e+00 4.550 0.001 302.00 328.00 3 2.2546e-01 1.0013e-03 5.4283e-02 -6.0000e+00 3.4447e-01 4.4899e-02 1.2760e-03 3.0347e-02 -6.0000e+00 3.7457e-01 -2.2029e-02 1.2049e-03 1.5468e-02 -6.0000e+00 2.2407e-01 -3.2906e-03 6.0994e-04 5.2731e-03 -6.0000e+00 9.6363e-02 2.2569e-03 -1.2565e-04 1.7235e-05 5.3859e-05 -6.0000e+00 6.7191e-03 -2.3946e-02 6.1226e-05 10 0 0 10 0 0 23.08 21.50 0.28 -0.02395 -0.02489 657 139 1 5 0 75.250 24.46 20.00 21.50 12.70 29.6 984.20 216641 -45473 -65833 -48286 -62163 -65458 -42684 -68241 -34824 -70618 -35223 -40820 -32387 -34302 -16882 -4366 -13383 -9468 -6064 -53 -10905 -4600 -14876 -5248 -11919 -2891 -8263 -4774 -13383 -6512 -1310 -1260 -454 -991 -3292 -5381 -1751 -1660 -606 -2616 -591 -1400 -518 80 165 -428 -1077 -415 -830 501 457 1599 420 1921 945 1301 878 664 294 510 683 741 1645 2011 1562 50 157 -795 576 740 824 769 635 672 171 -255 -1081 -1270 -863 -648 -937 -737 -1635 -1458 -1021 -525 -87 302 779 828 851 669 356 131 168 124 240 513 409 23 -209 -638 -679 -301 -750 -940 -722 -579 -287 439 332 318 214 171 -97 56 132 2 5 -158 -325 -51 108 224 240 304 25 557 453 294 76 -86 -154 -60 -39 0 -227 213 -14 -75 -27 -60 -195 135 -288 -548 -325 -447 -493 -314 -684 -286 -904 -337 -481 -448 -622 -323 -88 -334 -252 -169 -1 -348 -139 -534 -190 -461 -109 -333 -180 -548 -273 -62 -72 -30 -69 -225 -379 -134 -153 -63 -332 -83 -213 -82 13 27 -72 -187 -74 -157 101 103 369 108 529 279 401 280 211 91 156 216 259 650 828 674 21 66 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