File name: Pandora25s1_HoustonTX_20240324_L2Fit_fout2c1d20220503p1-8.txt File generation date: 20240325T063406.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v1d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20240324_L1_smca1c1d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20240324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240324T133859.9Z 8849.568749 253 1 49.56 2 73.64 97.52 110.27 285.30 0.00 1 0.00 1 0 25 8.023e-02 5.726e-03 1.953e-02 1.664e-03 4.239041e-01 8.490094e-04 4.606236e-03 -6.000000e+00 4.603843e-02 227.84 -2.00 3.24 -2.00 319.25 0.00e+00 4.583110e-04 2.194257e-04 1.519253e-04 -6.000000e+00 2.060691e-03 286.58 -2.00 20.00 -2.00 318.48 0.00e+00 3.492 0.000 302.00 328.00 3 3.2994e+00 2.3822e-03 4.0294e-02 -6.0000e+00 1.1426e-01 -1.0816e-02 2.7871e-03 2.0466e-02 -6.0000e+00 1.2384e-01 -8.0899e-03 2.0861e-03 1.0034e-02 -6.0000e+00 7.3943e-02 -9.5955e-04 1.0970e-03 2.8811e-03 -6.0000e+00 3.1654e-02 3.7333e-04 -4.3160e-04 4.8184e-05 3.1707e-05 -6.0000e+00 2.1808e-03 -3.2346e-02 1.2410e-04 10 0 0 10 0 0 99.97 23.47 0.25 -0.03235 -0.03559 88 19 1 5 0 563.110 26.11 20.00 23.47 24.40 31.0 1100.00 -57184 6439 -10887 -1452 -11913 -23357 44057 -26211 26467 -26296 -10195 -4758 -9211 -3416 -5543 -2056 -2660 4326 -1654 6305 -1622 2538 -9243 -520 -3680 2033 -2845 -1257 -3785 -1834 3807 3535 3116 -1751 -4344 -1484 635 5705 525 -2127 -1375 -888 -763 488 1329 465 -1708 -71 566 573 1180 661 553 1741 417 1516 1046 -658 558 -176 1034 47 1150 1112 1068 -506 37 -1033 696 558 970 460 233 45 801 928 -1886 -858 -606 -46 -1136 -714 -1400 -1289 -952 -1012 -166 60 104 680 713 882 748 278 401 365 300 414 384 -280 -321 -1160 -818 -347 -372 -637 -923 -638 -100 410 94 365 332 154 -20 309 204 83 -255 -278 -350 -107 239 200 422 324 165 784 562 430 154 65 -193 177 -170 -81 -125 285 -73 -136 75 -422 -345 -2155 154 -317 -37 -308 -653 725 -921 646 -1098 -377 -180 -424 -179 -348 -140 -197 321 -139 512 -144 220 -922 -52 -405 222 -329 -136 -403 -197 431 447 443 -269 -663 -218 101 1003 116 -556 -396 -266 -238 153 415 148 -556 -23 182 191 418 258 229 753 192 712 499 -319 266 -84 501 24 642 668 657 -305 21 -595 426 380 705 352 179 33 557 589 -1143 -509 -379 -32 -889 -608 -1268 -1216 -945 -1064 -178 66 116 735 727 850 692 256 391 385 346 517 506 -371 -410 -1400 -937 -400 -452 -807 -1217 -876 -142 619 149 593 537 239 -30 441 292 123 -394 -446 -565 -171 374 305 629 468 230 1097 834 678 258 112 -338 321 -318 -157 -248 569 -147 -272 147 -795 -641 SS 20240324T134939.3Z 8849.576150 256 1 49.67 2 71.35 98.94 112.45 286.79 0.00 1 0.00 1 0 25 2.277e-02 4.942e-03 6.331e-03 9.556e-04 3.760628e-01 4.868479e-04 4.126341e-03 -6.000000e+00 1.306467e-02 227.84 -2.00 3.24 -2.00 318.51 0.00e+00 2.189019e-04 1.002810e-04 1.136467e-04 -6.000000e+00 5.880119e-04 286.59 -2.00 20.00 -2.00 317.72 0.00e+00 3.088 0.000 302.00 328.00 3 2.8122e+00 1.3249e-03 3.5646e-02 -6.0000e+00 3.2424e-02 -2.2641e-02 1.5160e-03 1.8080e-02 -6.0000e+00 3.5155e-02 3.5102e-03 1.0296e-03 8.8401e-03 -6.0000e+00 2.0989e-02 -6.4630e-03 5.4004e-04 2.4824e-03 -6.0000e+00 9.0421e-03 9.5481e-04 -3.9048e-04 2.7626e-05 2.7311e-05 -6.0000e+00 6.2275e-04 -3.2059e-02 8.6364e-05 11 1 0 11 8 0 99.87 23.46 0.22 -0.03206 -0.03499 134 28 1 5 0 370.620 26.11 20.00 23.46 24.75 31.1 1100.00 900000 -2342 -2899 -5796 -1044 -12675 8291 -8961 4203 -7781 -5688 -2454 -6450 -1768 -4348 7361 -2583 2697 -1589 2425 -801 263 -3492 -82 -1009 -67 -1787 -2057 -472 -2870 2327 950 1891 -693 -2367 -1555 -1022 360 -361 -876 -1107 -483 -1036 129 131 506 -839 -358 -564 23 521 521 519 897 779 820 1159 551 838 287 927 660 1176 1448 852 -109 -148 -810 251 658 276 651 125 280 555 247 -833 -587 -741 -472 -963 -1008 -1509 -1444 -949 -889 -185 -92 358 431 542 474 402 235 392 264 392 517 307 -132 -235 -823 -602 -230 -462 -773 -669 -668 -196 970 201 255 264 110 8 23 201 -47 -39 -56 -338 -206 25 168 331 494 18 707 500 516 184 -10 -244 112 -41 61 -151 193 11 -188 -132 -237 -371 900000 -107 -138 -269 -42 -562 328 -469 218 -477 -346 -154 -486 -150 -438 743 -305 322 -207 318 -111 36 -513 -12 -165 -11 -309 -341 -74 -466 393 180 389 -151 -500 -323 -231 93 -111 -309 -426 -193 -430 54 55 212 -354 -150 -238 10 236 253 267 483 434 468 672 321 481 164 541 411 784 1022 612 -75 -98 -539 175 504 226 551 106 231 435 180 -573 -394 -521 -365 -819 -927 -1466 -1453 -996 -977 -210 -107 415 489 587 486 394 228 398 288 461 654 407 -175 -301 -1002 -702 -270 -572 -996 -888 -916 -278 1438 312 404 414 167 11 32 280 -67 -58 -86 -531 -321 39 251 481 697 25 973 721 784 292 -17 -406 191 -72 111 -281 361 22 -351 -241 -423 -651 SS 20240324T135506.8Z 8849.579940 260 1 9.03 2 70.18 99.68 113.56 287.56 0.00 1 0.00 1 0 25 2.836e-02 5.353e-03 1.244e-02 2.362e-03 3.568927e-01 1.196190e-03 3.935013e-03 -6.000000e+00 1.626987e-02 227.84 -2.00 3.24 -2.00 318.14 0.00e+00 3.706820e-04 2.206420e-04 9.776614e-05 -6.000000e+00 7.282979e-04 286.59 -2.00 20.00 -2.00 317.34 0.00e+00 2.917 0.000 302.00 328.00 3 3.0780e+00 3.2210e-03 3.3709e-02 -6.0000e+00 4.0381e-02 -1.4508e-02 3.6592e-03 1.7144e-02 -6.0000e+00 4.3770e-02 -5.9553e-03 2.3692e-03 8.3719e-03 -6.0000e+00 2.6133e-02 -1.3293e-03 1.2265e-03 2.3668e-03 -6.0000e+00 1.1185e-02 8.8271e-04 -4.7988e-04 6.7721e-05 2.6087e-05 -6.0000e+00 7.7098e-04 -3.1970e-02 7.8723e-05 12 1 1 12 1 1 99.04 23.46 0.21 -0.03197 -0.03558 15 19 1 5 0 563.710 26.11 20.00 23.46 25.10 31.2 1100.00 -18139 1582 -6888 557 -11063 -8347 6338 -8975 8058 -12440 -452 -7147 -4123 -2138 -1317 877 -654 990 1216 4262 -1297 2098 -4045 789 353 914 -149 -1045 -2174 -439 2219 2530 615 323 -2327 -779 -1254 566 39 -749 -824 -466 -391 -267 237 513 -844 -420 -266 255 -228 1986 267 1192 116 874 418 620 371 272 1111 198 1359 885 932 -476 99 -898 361 395 177 584 -44 142 574 796 -646 -918 -514 -16 -1217 -793 -1772 -1464 -850 -466 -53 -124 -29 488 411 603 422 227 247 317 259 645 455 -360 -224 -792 -645 -291 -102 -686 -945 -726 -63 251 190 534 10 127 -199 293 331 -117 -117 264 -481 -90 -59 158 530 485 395 873 352 569 422 -155 80 -3 -126 195 -5 94 -263 -181 -301 -330 -280 -1180 94 -460 33 -654 -468 332 -623 530 -1064 -35 -620 -380 -229 -164 120 -97 153 187 664 -218 340 -723 144 69 186 -31 -206 -411 -82 444 562 154 80 -587 -191 -323 169 14 -294 -357 -212 -185 -128 113 245 -406 -200 -126 123 -114 1051 148 694 71 548 259 398 233 170 712 133 954 675 720 -351 71 -643 264 317 151 519 -39 121 471 610 -476 -653 -371 -13 -1067 -746 -1754 -1522 -909 -517 -62 -145 -34 568 459 638 429 226 254 352 313 817 602 -479 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