File name: Pandora25s1_HoustonTX_20240427_L2Fit_fout2c9d20230101p1-8.txt File generation date: 20241218T062708.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20240427_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20240427 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240427T135124.2Z 8883.577363 263 1 49.51 2 63.16 88.53 89.55 236.67 0.00 1 0.00 1 0 17 1.449e-01 1.783e-02 5.423e-02 7.576e-03 3.373349e-01 3.932779e-03 3.671017e-03 -6.000000e+00 8.485659e-02 230.11 -2.00 3.24 -2.00 318.70 0.00e+00 -1.829749e-03 8.284432e-04 9.814439e-05 -6.000000e+00 3.819568e-03 288.89 -2.00 20.00 -2.00 317.85 0.00e+00 2.203 0.000 302.00 328.00 3 6.2920e+00 1.0802e-02 2.7446e-02 -6.0000e+00 2.1148e-01 2.6421e-02 1.2402e-02 1.6324e-02 -6.0000e+00 2.2860e-01 2.5442e-02 8.1997e-03 8.0058e-03 -6.0000e+00 1.3641e-01 -1.2244e-02 4.2346e-03 2.6758e-03 -6.0000e+00 5.8602e-02 6.8808e-05 -1.8920e-04 2.3024e-04 2.8558e-05 -6.0000e+00 4.0802e-03 -5.8494e-03 0.0000e+00 12 9 8 11 8 0 99.95 24.40 0.02 -0.00585 -0.00727 105 22 1 5 0 471.440 26.94 20.00 24.40 31.35 31.6 1100.00 900000 6689 -8676 24953 -18535 4616 113251 -1927 70179 8704 -15529 57866 -25302 22957 -19443 -24523 3714 20825 -2735 3354 6569 -4018 -12958 608 -5747 1662 -1190 -3507 9041 -7160 16702 9740 7734 2708 -8786 10826 10716 38126 1105 -2495 -4192 8036 -5006 1999 3649 1924 -8323 -4363 3473 -2703 1593 -2142 -249 668 3102 1423 7403 -8308 1009 -3846 660 -2625 -27 1162 -1775 -674 -1106 857 3769 536 1878 2963 -180 -2208 2575 4586 -3684 427 2147 2450 748 -2990 -1321 796 -479 -3552 857 -159 -41 1032 358 1906 548 -1041 -841 2634 -747 1484 -760 -877 516 -996 -823 -898 860 336 -1379 -1725 757 -38 618 -1118 542 -146 119 920 -324 187 -365 -863 -1298 616 1056 1953 -506 939 231 1701 -324 -482 -276 -721 -206 3309 -678 -1099 57 753 251 -984 1032 -2195 729 900000 357 -536 1117 -1093 222 2469 -118 2632 567 -1252 2662 -2588 1775 -2437 -3513 440 2230 -374 452 878 -591 -2137 95 -1012 286 -210 -603 1319 -1200 2420 1633 1430 540 -1859 1907 2049 6632 317 -854 -1599 2883 -2080 786 1414 756 -3555 -1775 1309 -1096 657 -984 -120 336 1587 760 3825 -4960 544 -2146 362 -1579 -17 781 -1241 -442 -687 516 2341 383 1447 2364 -149 -1792 1878 2993 -2374 254 1311 1658 576 -2627 -1224 759 -490 -3976 968 -187 -48 1172 384 1870 507 -950 -803 2665 -861 1843 -1025 -1186 657 -1193 -928 -1022 1026 426 -1850 -2422 1091 -59 1002 -1889 888 -229 175 1263 -443 262 -542 -1362 -2103 976 1626 2890 -732 1288 306 2209 -451 -720 -434 -1181 -344 5529 -1230 -2098 111 1480 498 -1947 1941 -4097 1291 SS 20240427T141903.0Z 8883.596563 281 1 2.26 2 57.16 91.97 94.48 239.89 0.00 1 0.00 1 0 17 7.478e-03 5.265e-03 3.402e-03 1.424e-03 2.645618e-01 7.373720e-04 2.939121e-03 -6.000000e+00 4.374934e-03 230.11 -2.00 3.24 -2.00 316.64 0.00e+00 1.318527e-04 9.164410e-05 4.441642e-05 -6.000000e+00 1.959174e-04 288.89 -2.00 20.00 -2.00 315.83 0.00e+00 1.837 0.000 302.00 328.00 3 1.7703e+00 1.9346e-03 2.2380e-02 -6.0000e+00 1.0904e-02 -1.1194e-02 2.1621e-03 1.2685e-02 -6.0000e+00 1.1787e-02 -4.1532e-03 1.2582e-03 6.1716e-03 -6.0000e+00 7.0340e-03 -2.7015e-04 5.9839e-04 1.7062e-03 -6.0000e+00 3.0005e-03 1.0461e-02 -1.7218e-04 4.1595e-05 2.0813e-05 -6.0000e+00 2.0940e-04 2.4304e-04 0.0000e+00 12 1 1 12 1 1 99.99 24.41 0.27 0.00024 -0.00105 38 182 1 5 0 57.790 26.94 20.00 24.41 32.64 31.7 1100.00 -361 -1014 -2294 -2031 -2416 -2106 445 -342 586 -481 39 -248 -502 -201 -125 -608 131 272 339 1295 147 115 668 651 201 -27 -975 -941 -348 674 1552 1900 1161 -756 -1839 -930 -1207 71 43 -356 -676 -721 -755 -905 -655 -522 -685 -608 -538 275 199 1169 900 846 502 695 803 384 670 827 1100 1179 1334 820 441 -208 -214 -264 644 470 -68 98 -240 231 -64 114 -182 -396 19 -582 -844 -1175 -1503 -1619 -1077 -670 -428 -260 163 129 203 370 479 704 1075 393 528 457 29 -314 -220 -582 -18 191 -635 -867 -447 -578 -218 224 -32 120 -30 123 95 497 558 317 158 9 -616 -227 119 226 289 700 326 1054 674 214 300 -127 -202 121 -8 59 -186 193 -207 -291 -275 -227 -334 -56 -173 -372 -328 -352 -297 65 -57 107 -86 7 -46 -104 -48 -34 -168 38 81 105 411 48 38 221 228 75 -10 -353 -342 -118 223 540 714 445 -301 -699 -345 -491 33 23 -208 -410 -458 -494 -598 -431 -342 -442 -382 -332 169 129 808 627 621 382 540 634 304 519 636 869 950 1165 730 395 -183 -174 -210 537 422 -64 97 -239 221 -60 101 -146 -317 16 -516 -805 -1188 -1568 -1778 -1205 -770 -518 -325 204 157 238 413 510 720 1144 443 635 564 38 -415 -274 -698 -21 226 -788 -1104 -593 -776 -306 323 -47 180 -44 174 128 648 716 423 217 13 -909 -332 169 320 403 926 427 1361 887 292 433 -183 -299 185 -12 94 -306 324 -342 -488 -446 -366 -525 SS 20240427T142829.6Z 8883.603120 284 1 49.50 2 55.11 93.20 96.20 240.93 0.00 1 0.00 1 0 17 3.117e-02 6.050e-03 5.795e-03 1.733e-03 2.546412e-01 8.917908e-04 2.822120e-03 -6.000000e+00 1.824701e-02 230.11 -2.00 3.24 -2.00 317.53 0.00e+00 1.735627e-05 1.363929e-04 7.282931e-05 -6.000000e+00 8.169436e-04 288.89 -2.00 20.00 -2.00 316.67 0.00e+00 1.743 0.000 302.00 328.00 3 4.6802e+00 2.3737e-03 2.1363e-02 -6.0000e+00 4.5478e-02 6.4096e-04 2.6733e-03 1.2265e-02 -6.0000e+00 4.9151e-02 1.5147e-02 1.6054e-03 5.9706e-03 -6.0000e+00 2.9333e-02 -1.0234e-02 7.9344e-04 1.6496e-03 -6.0000e+00 1.2519e-02 6.2715e-04 3.7811e-05 5.1890e-05 1.9556e-05 -6.0000e+00 8.7280e-04 -3.2456e-03 0.0000e+00 11 1 0 11 8 0 100.00 24.42 0.06 -0.00325 -0.00296 340 72 1 5 0 145.570 26.94 19.99 24.42 33.47 31.6 1100.00 32239 -2474 -5244 -2297 -3660 -1345 7302 -710 6582 -2175 629 1388 -792 604 -1422 -6464 -199 964 -1682 656 -1102 229 -1035 1751 -418 999 -1395 -259 193 1207 1982 2556 2129 -1139 -1840 234 1119 1932 411 -1375 -1665 -964 -1074 -935 46 -312 -1703 -1028 105 19 638 780 263 1188 510 969 624 -182 559 682 465 770 759 528 69 -537 119 -271 1257 565 50 149 50 -169 805 858 -704 164 597 123 -651 -994 -1631 -820 -809 -664 -557 -32 165 276 380 522 531 320 648 347 533 490 -11 -492 -88 -631 -226 -182 -486 -910 -915 -792 -84 1688 -28 4 -44 208 -165 532 244 113 -83 -213 -639 -58 164 202 362 438 263 691 428 -82 101 -211 -282 405 93 -158 -67 447 -109 -116 -60 -348 -268 2581 -290 -637 -255 -374 -131 702 -82 778 -289 81 184 -119 101 -272 -1398 -43 211 -391 154 -267 55 -257 446 -114 278 -394 -69 48 295 505 696 623 -350 -541 67 342 676 171 -664 -873 -524 -599 -525 25 -174 -946 -556 56 10 351 456 163 761 338 652 427 -125 378 458 321 563 594 436 58 -422 87 -195 936 467 44 139 47 -154 690 675 -515 114 425 96 -566 -943 -1646 -857 -891 -773 -676 -40 206 336 437 558 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