File name: Pandora25s1_HoustonTX_20240715_L2Fit_fwvt1c9d20230101p1-8.txt File generation date: 20241218T074030.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20240715_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20240715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 1709 1859 Nominal wavelengths inside fitting window [nm]: 492.0722 492.1924 492.3125 492.4327 492.5528 492.6729 492.7930 492.9131 493.0332 493.1532 493.2732 493.3932 493.5132 493.6332 493.7532 493.8731 493.9931 494.1130 494.2329 494.3528 494.4726 494.5925 494.7123 494.8321 494.9519 495.0717 495.1915 495.3112 495.4309 495.5507 495.6704 495.7900 495.9097 496.0293 496.1490 496.2686 496.3882 496.5078 496.6273 496.7469 496.8664 496.9859 497.1054 497.2249 497.3444 497.4638 497.5832 497.7026 497.8220 497.9414 498.0608 498.1801 498.2995 498.4188 498.5381 498.6573 498.7766 498.8958 499.0151 499.1343 499.2535 499.3727 499.4918 499.6110 499.7301 499.8492 499.9683 500.0874 500.2064 500.3255 500.4445 500.5635 500.6825 500.8015 500.9204 501.0394 501.1583 501.2772 501.3961 501.5150 501.6338 501.7527 501.8715 501.9903 502.1091 502.2279 502.3466 502.4654 502.5841 502.7028 502.8215 502.9402 503.0588 503.1775 503.2961 503.4147 503.5333 503.6518 503.7704 503.8889 504.0075 504.1260 504.2444 504.3629 504.4814 504.5998 504.7182 504.8366 504.9550 505.0734 505.1917 505.3101 505.4284 505.5467 505.6650 505.7832 505.9015 506.0197 506.1379 506.2561 506.3743 506.4925 506.6106 506.7288 506.8469 506.9650 507.0830 507.2011 507.3192 507.4372 507.5552 507.6732 507.7912 507.9091 508.0271 508.1450 508.2629 508.3808 508.4987 508.6165 508.7344 508.8522 508.9700 509.0878 509.2056 509.3233 509.4411 509.5588 509.6765 509.7942 509.9119 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240715T193306.7Z 8962.814661 3 1 0.01 2 16.99 244.25 99.36 106.98 0.00 1 0.00 1 0 15 3.645e-03 3.653e-03 2.814e-03 2.809e-03 2.185531e+03 1.727174e+02 1.615929e+02 -6.000000e+00 2.100649e+02 294.24 -2.00 20.00 -2.00 505.24 0.00e+00 5.755849e-04 7.905936e-05 3.473247e-05 -6.000000e+00 1.046952e-04 294.24 -2.00 20.00 -2.00 500.42 0.00e+00 -4.551868e-02 5.512472e-02 1.283074e-02 -6.000000e+00 7.171498e-02 230.03 -2.00 3.24 -2.00 502.01 0.00e+00 1.045 0.000 489.00 513.00 1 2.1608e-01 4.2430e-03 2.0329e-03 -6.0000e+00 5.5198e-03 1.0469e-03 1.0971e-03 3.2018e-04 -6.0000e+00 1.4328e-03 1.3510e+00 8.8722e-04 2.7588e-04 2.1021e-05 -6.0000e+00 3.6780e-04 1.4810e-03 1.1535e-05 12 1 1 12 1 1 999.00 24.15 1.92 0.00148 0.00764 1 512 1 4 0 2.400 26.73 19.99 24.15 43.41 33.7 1100.00 78 55 271 -201 286 377 618 497 -29 -450 721 96 -1029 -245 -640 -84 22 227 -427 420 344 536 45 628 543 369 -351 188 -84 -203 -202 -89 365 207 -511 160 57 30 -379 -647 134 -112 -348 553 -154 -258 203 -52 239 -109 -516 -156 -116 -524 -224 -60 -174 161 -256 -304 133 239 52 -145 491 101 389 309 -675 -604 -71 34 -370 124 542 128 -390 95 -969 -110 -434 -11 -80 -170 -345 8 -438 -88 -73 171 435 406 -154 -150 273 135 327 -143 -59 58 -655 13 -245 -979 -631 -597 -120 446 -268 -88 -280 867 -111 184 -382 482 -21 493 436 263 -98 354 347 40 650 196 -317 30 16 237 292 152 228 202 606 118 -200 -216 -251 634 -332 522 152 -39 -359 11 -164 -515 448 -285 -120 77 54 273 -207 297 394 646 524 -30 -471 743 100 -1061 -247 -647 -85 23 235 -449 438 360 561 47 659 572 389 -371 194 -86 -205 -202 -90 369 214 -532 166 59 32 -390 -662 137 -114 -360 575 -161 -269 211 -54 242 -109 -513 -153 -114 -511 -221 -60 -176 164 -263 -312 136 245 53 -148 500 102 390 306 -666 -595 -69 33 -364 121 534 126 -382 92 -937 -106 -417 -11 -78 -165 -339 8 -431 -86 -72 168 429 400 -155 -151 274 133 321 -139 -57 56 -622 12 -234 -963 -630 -596 -118 437 -260 -87 -275 855 -111 183 -385 485 -21 494 441 263 -97 347 341 39 638 191 -312 30 16 230 283 147 217 192 575 111 -190 -208 -246 616 -329 516 150 -38 -358 11 -161 -503 428 -273 -114 SQ 20240715T193833.2Z 8962.818439 6 1 7.33 2 18.06 246.48 98.28 107.61 0.00 1 0.00 1 0 15 1.756e-03 1.757e-03 6.722e-05 6.710e-05 2.542657e+03 4.171197e+00 1.796967e+02 -6.000000e+00 1.011986e+02 294.24 -2.00 20.00 -2.00 505.24 0.00e+00 4.247242e-04 1.888278e-06 2.785867e-05 -6.000000e+00 5.043640e-05 294.24 -2.00 20.00 -2.00 500.41 0.00e+00 -7.480198e-02 1.316209e-03 1.570021e-02 -6.000000e+00 3.454749e-02 230.03 -2.00 3.24 -2.00 502.00 0.00e+00 1.052 0.000 489.00 513.00 1 5.4004e-01 1.0129e-04 2.1183e-03 -6.0000e+00 2.6591e-03 -3.5074e-04 2.6203e-05 3.8290e-04 -6.0000e+00 6.9022e-04 9.7988e-01 3.7118e-04 6.5821e-06 2.0428e-05 -6.0000e+00 1.7719e-04 4.9211e-04 1.9743e-05 10 0 0 10 0 0 98.97 24.15 1.95 0.00049 0.00307 2248 477 1 4 0 2.580 26.73 19.99 24.15 44.04 33.5 1100.00 -76 -51 96 110 146 378 366 253 249 144 74 9 -142 -99 -150 -191 -148 20 33 -56 127 261 176 296 377 229 192 214 -31 -188 -82 -210 -230 95 -67 -278 -110 -4 -121 -149 -54 -53 0 51 72 71 87 9 -53 -212 -316 -308 -419 -376 -178 -147 -129 -48 -1 82 160 217 168 134 158 67 51 -5 -29 -167 -181 -149 -162 -114 5 -107 -247 -155 -117 -196 -228 -172 -248 -177 43 -91 -137 -56 -28 -36 -41 53 163 127 75 185 110 -82 -142 -213 -359 -342 -361 -154 -107 -320 -149 -63 -172 -56 14 -70 9 127 174 234 312 361 285 194 217 148 14 207 210 -6 133 235 62 192 259 26 59 82 -106 -92 108 33 -76 103 106 53 149 176 110 88 50 -88 -178 -188 -248 -74 -51 96 112 150 396 384 268 263 150 77 10 -146 -101 -152 -195 -151 21 34 -59 134 274 186 312 399 239 202 222 -32 -191 -83 -210 -234 98 -70 -291 -114 -4 -125 -152 -55 -55 0 53 75 74 91 10 -55 -215 -316 -304 -408 -368 -176 -147 -131 -49 -1 83 164 220 171 137 160 68 51 -5 -29 -165 -177 -146 -157 -112 5 -107 -243 -151 -113 -188 -220 -167 -239 -173 43 -89 -135 -55 -28 -35 -41 53 164 127 75 183 108 -79 -135 -201 -337 -324 -346 -151 -107 -319 -147 -62 -168 -55 14 -69 9 126 174 236 315 362 285 195 214 146 14 201 205 -6 131 230 60 187 251 25 57 79 -100 -88 103 31 -74 101 104 52 147 174 109 88 49 -86 -172 -179 -235 SQ 20240715T193840.5Z 8962.818525 6 2 6.86 2 18.09 246.53 98.26 107.62 0.00 1 0.00 1 0 15 1.764e-03 1.765e-03 6.704e-05 6.693e-05 2.544260e+03 4.158036e+00 1.794709e+02 -6.000000e+00 1.016510e+02 294.24 -2.00 20.00 -2.00 505.24 0.00e+00 4.163232e-04 1.882460e-06 2.766149e-05 -6.000000e+00 5.066182e-05 294.24 -2.00 20.00 -2.00 500.41 0.00e+00 -7.522114e-02 1.312278e-03 1.578997e-02 -6.000000e+00 3.470175e-02 230.03 -2.00 3.24 -2.00 502.01 0.00e+00 1.052 0.000 489.00 513.00 1 5.3438e-01 1.0097e-04 2.1208e-03 -6.0000e+00 2.6710e-03 -3.4689e-04 2.6125e-05 3.8435e-04 -6.0000e+00 6.9329e-04 9.8558e-01 3.8038e-04 6.5671e-06 2.0317e-05 -6.0000e+00 1.7798e-04 4.8903e-04 2.0118e-05 10 0 0 10 0 0 99.24 24.15 1.95 0.00049 0.00313 2248 477 1 4 0 2.580 26.73 19.99 24.15 44.04 33.5 1100.00 -86 -61 98 132 141 408 373 268 240 126 57 -5 -156 -100 -125 -174 -133 26 40 -55 106 266 168 291 390 229 184 193 -36 -210 -76 -223 -219 100 -67 -285 -114 -12 -115 -143 -45 -26 -2 37 73 79 100 20 -37 -189 -298 -313 -413 -355 -164 -156 -148 -56 -16 74 146 217 171 121 160 51 47 4 -41 -170 -190 -150 -174 -141 -2 -111 -238 -170 -106 -198 -230 -145 -237 -170 33 -93 -151 -56 -39 -55 -44 21 167 108 71 183 113 -70 -146 -209 -369 -356 -369 -136 -98 -311 -152 -65 -161 -51 29 -74 5 127 158 206 307 367 300 213 249 156 21 224 225 25 128 243 89 222 257 20 53 85 -112 -83 97 -18 -92 77 113 49 149 192 115 87 56 -80 -180 -208 -244 -84 -60 98 135 145 429 393 284 254 132 59 -5 -158 -102 -127 -178 -136 27 42 -58 112 280 178 308 408 240 194 201 -37 -213 -76 -223 -221 103 -70 -300 -119 -13 -119 -147 -46 -27 -2 38 76 82 104 20 -38 -192 -298 -305 -403 -349 -162 -157 -150 -57 -17 75 148 221 174 123 162 52 46 4 -41 -166 -186 -147 -170 -139 -2 -109 -234 -164 -103 -190 -222 -141 -229 -166 32 -92 -149 -55 -39 -55 -44 21 166 108 71 182 110 -68 -139 -198 -348 -337 -354 -133 -97 -310 -150 -64 -157 -50 29 -73 5 127 159 208 308 368 300 214 246 154 21 218 220 25 125 238 87 217 249 19 51 80 -106 -78 93 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