File name: Pandora25s1_HoustonTX_20240719_L2Fit_fout2c1d20220503p1-8.txt File generation date: 20240720T063546.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v1d20220503.txt Level 1 file used: Pandora25s1_HoustonTX_20240719_L1_smca1c1d20220503p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20240719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.1116 305.2524 305.3931 305.5338 305.6745 305.8152 305.9558 306.0965 306.2371 306.3777 306.5183 306.6589 306.7995 306.9401 307.0806 307.2212 307.3617 307.5022 307.6427 307.7832 307.9236 308.0641 308.2045 308.3449 308.4853 308.6257 308.7661 308.9065 309.0468 309.1872 309.3275 309.4678 309.6081 309.7484 309.8886 310.0289 310.1691 310.3093 310.4495 310.5897 310.7299 310.8701 311.0102 311.1504 311.2905 311.4306 311.5707 311.7108 311.8509 311.9909 312.1310 312.2710 312.4110 312.5510 312.6910 312.8310 312.9709 313.1109 313.2508 313.3907 313.5306 313.6705 313.8104 313.9503 314.0901 314.2300 314.3698 314.5096 314.6494 314.7892 314.9290 315.0687 315.2085 315.3482 315.4879 315.6276 315.7673 315.9070 316.0466 316.1863 316.3259 316.4656 316.6052 316.7448 316.8843 317.0239 317.1635 317.3030 317.4425 317.5821 317.7216 317.8611 318.0005 318.1400 318.2794 318.4189 318.5583 318.6977 318.8371 318.9765 319.1159 319.2552 319.3946 319.5339 319.6732 319.8125 319.9518 320.0911 320.2304 320.3696 320.5089 320.6481 320.7873 320.9265 321.0657 321.2049 321.3441 321.4832 321.6223 321.7615 321.9006 322.0397 322.1788 322.3178 322.4569 322.5960 322.7350 322.8740 323.0130 323.1520 323.2910 323.4300 323.5689 323.7079 323.8468 323.9857 324.1246 324.2635 324.4024 324.5413 324.6801 324.8190 324.9578 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240719T131620.8Z 8966.553019 167 1 49.68 2 69.76 77.12 135.90 258.31 0.00 1 0.00 1 0 17 2.695e-02 5.014e-03 5.478e-03 8.658e-04 3.803639e-01 4.426364e-04 4.182418e-03 -6.000000e+00 1.560359e-02 229.96 -2.00 3.24 -2.00 318.30 0.00e+00 3.753956e-04 8.693205e-05 1.001562e-04 -6.000000e+00 7.157281e-04 294.29 -2.00 20.00 -2.00 317.35 0.00e+00 2.859 0.000 302.00 328.00 3 2.8265e+00 1.2040e-03 3.3963e-02 -6.0000e+00 3.8818e-02 -9.1157e-03 1.3771e-03 1.8446e-02 -6.0000e+00 4.1939e-02 -3.1723e-03 8.9812e-04 8.9326e-03 -6.0000e+00 2.5118e-02 -2.2517e-03 4.6860e-04 2.4706e-03 -6.0000e+00 1.0797e-02 1.1475e-03 -4.3115e-04 2.4796e-05 2.7290e-05 -6.0000e+00 7.3306e-04 -3.6477e-02 1.2550e-04 10 0 0 10 0 0 97.22 24.26 0.28 -0.03648 -0.03972 115 24 1 5 0 431.940 26.83 20.01 24.26 33.04 32.7 1100.00 23442 1327 -7463 995 -9856 -6657 47 -5355 2415 -5864 -7164 -2949 -5124 -2104 -2755 -1798 -476 -163 939 292 693 -1410 -414 -257 -1338 363 -1732 -404 -2173 -366 1765 1646 921 -245 -2713 -1870 -1562 690 -416 -644 -471 -535 -265 -396 257 -106 -723 -809 -249 -392 737 416 359 1048 629 891 897 239 444 686 470 989 1050 1516 1073 160 -8 -775 472 543 299 251 151 203 790 188 -683 -742 -361 -620 -992 -822 -1581 -1645 -953 -618 -340 54 239 674 605 723 351 327 364 197 340 360 243 -275 -222 -797 -703 -421 -446 -850 -693 -719 -225 781 234 223 242 151 -130 219 72 39 -66 74 -401 -133 55 158 289 486 213 632 650 465 392 97 -28 168 69 59 -163 167 -150 -257 -160 -327 -434 833 66 -422 49 -488 -311 2 -304 143 -402 -504 -211 -437 -192 -298 -218 -61 -22 134 44 106 -220 -66 -44 -249 70 -341 -75 -388 -65 337 352 205 -57 -620 -417 -381 194 -134 -246 -199 -224 -115 -175 113 -47 -322 -359 -110 -178 356 220 191 592 373 543 560 150 273 416 294 629 736 1088 788 118 -6 -540 348 433 250 221 132 171 649 139 -492 -515 -264 -493 -858 -756 -1586 -1661 -1021 -677 -393 64 286 775 678 743 352 321 381 220 409 465 325 -370 -281 -968 -829 -501 -550 -1118 -916 -1001 -318 1139 356 350 374 228 -191 313 102 55 -99 113 -635 -207 83 239 415 694 291 858 911 714 621 154 -46 278 121 106 -293 305 -279 -466 -287 -583 -750 SS 20240719T132442.1Z 8966.558820 170 1 49.57 2 67.98 78.00 137.58 258.95 0.00 1 0.00 1 0 17 2.089e-02 5.016e-03 3.604e-03 6.838e-04 3.515473e-01 3.499648e-04 3.880376e-03 -6.000000e+00 1.209529e-02 229.96 -2.00 3.24 -2.00 318.11 0.00e+00 3.102627e-04 6.515603e-05 8.723529e-05 -6.000000e+00 5.548369e-04 294.29 -2.00 20.00 -2.00 317.16 0.00e+00 2.644 0.000 302.00 328.00 3 2.5450e+00 9.4617e-04 3.1406e-02 -6.0000e+00 3.0090e-02 -1.2242e-02 1.0772e-03 1.7047e-02 -6.0000e+00 3.2510e-02 7.5443e-04 6.8684e-04 8.2619e-03 -6.0000e+00 1.9471e-02 -3.5049e-03 3.5590e-04 2.2811e-03 -6.0000e+00 8.3693e-03 1.9466e-03 -5.1278e-04 1.9683e-05 2.5255e-05 -6.0000e+00 5.6831e-04 -3.6174e-02 1.1285e-04 10 0 0 10 0 0 99.68 24.25 0.27 -0.03617 -0.04003 278 59 1 5 0 178.260 26.73 20.00 24.25 33.27 32.7 1100.00 -19881 -2398 -4520 881 -7491 -4248 -1408 -2663 2454 -1625 -3370 -2221 -2280 -1118 -632 -155 -647 793 463 346 1227 -102 723 605 -221 597 -442 -315 -909 14 1289 1600 1208 -59 -2347 -1743 -1781 -343 -668 -934 -787 -797 -311 -619 38 -276 -240 -549 -196 -201 700 586 522 938 716 1031 826 438 344 580 413 873 1301 1517 812 102 -117 -543 364 503 201 327 307 175 460 184 -515 -765 -645 -689 -753 -847 -1530 -1755 -973 -661 -305 136 374 648 593 662 236 232 326 352 321 508 322 -300 -275 -848 -756 -401 -490 -891 -538 -575 -200 544 243 335 176 201 -29 61 119 127 -70 38 -362 -144 -33 144 317 517 151 747 661 448 403 46 15 123 94 -26 -102 151 -65 -226 -282 -325 -429 -1310 -148 -295 51 -428 -228 -79 -172 170 -124 -264 -182 -216 -123 -81 -21 -93 118 73 57 205 -17 125 113 -44 124 -93 -63 -172 3 262 361 302 -16 -598 -434 -486 -102 -240 -372 -346 -370 -149 -302 18 -135 -116 -264 -94 -98 341 311 296 564 424 627 515 274 211 352 258 587 957 1140 624 74 -85 -388 262 410 173 294 276 152 389 140 -380 -543 -481 -554 -654 -783 -1537 -1861 -1045 -759 -353 162 447 748 666 682 236 226 337 387 379 641 438 -394 -355 -1051 -874 -469 -619 -1152 -727 -785 -287 804 371 527 272 305 -43 83 161 178 -101 58 -573 -225 -50 211 457 712 207 1013 922 681 629 73 23 205 161 -45 -184 278 -121 -415 -497 -568 -728 SS 20240719T132947.0Z 8966.562349 173 1 15.99 2 66.90 78.54 138.61 259.34 0.00 1 0.00 1 0 17 1.156e-02 5.027e-03 2.445e-03 6.333e-04 3.365881e-01 3.245914e-04 3.716797e-03 -6.000000e+00 6.693240e-03 229.96 -2.00 3.24 -2.00 317.59 0.00e+00 3.885596e-04 5.228389e-05 7.292529e-05 -6.000000e+00 3.069519e-04 294.29 -2.00 20.00 -2.00 316.65 0.00e+00 2.529 0.000 302.00 328.00 3 1.5050e+00 8.6580e-04 3.0017e-02 -6.0000e+00 1.6651e-02 -1.2685e-02 9.7672e-04 1.6243e-02 -6.0000e+00 1.7988e-02 -4.7191e-03 5.9533e-04 7.8687e-03 -6.0000e+00 1.0774e-02 -1.5234e-04 3.0152e-04 2.1903e-03 -6.0000e+00 4.6325e-03 6.2945e-03 -1.1836e-04 1.8118e-05 2.4552e-05 -6.0000e+00 3.1433e-04 -3.7581e-02 1.5719e-04 12 1 1 12 1 1 60.48 24.26 0.27 -0.03758 -0.03847 159 105 1 5 0 99.890 26.83 20.01 24.26 33.50 32.6 1100.00 -5068 -2424 -2893 -3179 -3965 -4844 -2528 -2944 -418 -1614 -1970 -2715 -2814 -1501 -570 -770 -196 820 607 1006 975 550 817 -9 -34 485 247 -341 -514 142 966 610 1266 55 -1675 -2268 -1952 -1062 -730 -757 -446 -438 -345 -453 7 -9 -312 -264 -337 2 464 596 611 968 589 647 823 651 693 463 637 838 1272 1567 869 40 -7 -471 197 373 235 309 148 181 331 -15 -482 -832 -733 -657 -798 -991 -1599 -1575 -1042 -686 -345 105 311 397 508 616 336 406 482 193 331 536 333 -197 -323 -769 -748 -256 -431 -848 -569 -549 -266 340 165 311 182 115 -173 110 240 136 54 159 -227 -252 58 153 356 456 278 854 790 513 415 92 33 103 151 121 -218 -14 -139 -233 -304 -304 -524 -416 -215 -267 -277 -313 -373 -204 -271 -42 -174 -214 -312 -372 -213 -93 -141 -38 166 130 223 221 125 190 -2 -9 125 64 -84 -129 35 242 169 384 18 -514 -687 -645 -382 -297 -362 -221 -229 -186 -248 4 -5 -170 -142 -180 1 268 351 385 645 388 438 568 450 469 311 441 624 983 1239 701 32 -5 -349 155 317 211 290 139 164 292 -13 -368 -641 -564 -546 -720 -954 -1670 -1659 -1167 -789 -402 126 374 462 572 662 348 409 514 219 389 676 436 -258 -415 -948 -896 -310 -543 -1099 -770 -754 -372 490 255 478 274 169 -243 149 323 190 78 235 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