File name: Pandora25s1_HoustonTX_20241105_L2Fit_fwvt1c9d20230101p1-8.txt File generation date: 20241218T130308.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20241105_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 1709 1859 Nominal wavelengths inside fitting window [nm]: 492.0722 492.1924 492.3125 492.4327 492.5528 492.6729 492.7930 492.9131 493.0332 493.1532 493.2732 493.3932 493.5132 493.6332 493.7532 493.8731 493.9931 494.1130 494.2329 494.3528 494.4726 494.5925 494.7123 494.8321 494.9519 495.0717 495.1915 495.3112 495.4309 495.5507 495.6704 495.7900 495.9097 496.0293 496.1490 496.2686 496.3882 496.5078 496.6273 496.7469 496.8664 496.9859 497.1054 497.2249 497.3444 497.4638 497.5832 497.7026 497.8220 497.9414 498.0608 498.1801 498.2995 498.4188 498.5381 498.6573 498.7766 498.8958 499.0151 499.1343 499.2535 499.3727 499.4918 499.6110 499.7301 499.8492 499.9683 500.0874 500.2064 500.3255 500.4445 500.5635 500.6825 500.8015 500.9204 501.0394 501.1583 501.2772 501.3961 501.5150 501.6338 501.7527 501.8715 501.9903 502.1091 502.2279 502.3466 502.4654 502.5841 502.7028 502.8215 502.9402 503.0588 503.1775 503.2961 503.4147 503.5333 503.6518 503.7704 503.8889 504.0075 504.1260 504.2444 504.3629 504.4814 504.5998 504.7182 504.8366 504.9550 505.0734 505.1917 505.3101 505.4284 505.5467 505.6650 505.7832 505.9015 506.0197 506.1379 506.2561 506.3743 506.4925 506.6106 506.7288 506.8469 506.9650 507.0830 507.2011 507.3192 507.4372 507.5552 507.6732 507.7912 507.9091 508.0271 508.1450 508.2629 508.3808 508.4987 508.6165 508.7344 508.8522 508.9700 509.0878 509.2056 509.3233 509.4411 509.5588 509.6765 509.7942 509.9119 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241105T165937.5Z 9075.708073 181 1 49.75 2 48.34 158.77 86.80 126.42 0.00 1 0.00 1 0 15 2.386e-03 2.365e-03 8.884e-04 8.863e-04 4.143544e+03 5.644741e+01 2.951360e+02 -6.000000e+00 1.349541e+02 289.38 -2.00 20.00 -2.00 505.23 0.00e+00 6.531807e-04 2.466261e-05 4.081868e-05 -6.000000e+00 6.773550e-05 289.38 -2.00 20.00 -2.00 500.34 0.00e+00 -1.518219e-03 1.744888e-02 2.539546e-02 -6.000000e+00 4.686777e-02 225.60 -2.00 3.24 -2.00 501.94 0.00e+00 1.502 0.000 489.00 513.00 1 7.7438e+00 1.3405e-03 3.2094e-03 -6.0000e+00 3.6012e-03 7.9159e-03 3.4638e-04 6.2967e-04 -6.0000e+00 9.3677e-04 6.7539e-04 4.9990e-04 8.6040e-05 3.5084e-05 -6.0000e+00 2.4057e-04 -1.4926e-02 2.3658e-05 11 1 0 11 32 0 99.00 24.07 1.75 -0.01493 -0.01146 13 3 1 4 0 3826.190 26.62 19.99 24.07 27.47 32.8 1072.11 -87 -262 -104 -134 21 445 448 506 -7 88 233 -44 -12 -261 -291 -296 -2 -147 -59 -70 63 418 215 180 289 131 251 -133 -5 -187 134 64 -6 282 -79 -93 134 -47 52 -229 -194 68 -90 61 47 -54 68 -193 141 -219 -274 -168 -584 -184 -90 -171 -39 -344 72 -32 210 584 134 322 -114 55 48 -164 -49 -170 -319 303 -331 47 25 -614 220 -216 -384 169 -24 90 -84 -248 -329 -21 93 -6 97 -29 30 -44 271 81 -97 162 48 166 59 -54 -660 -295 -701 -70 -163 -340 -145 -189 -5 108 -36 20 97 293 126 4 460 373 190 -177 -40 146 -105 369 -16 283 18 127 80 787 254 94 320 -95 -473 -154 238 32 -197 -210 355 24 24 11 251 -53 261 -173 -45 -269 -447 -86 -261 -105 -138 22 468 475 538 -8 93 244 -45 -12 -267 -296 -303 -2 -153 -63 -74 67 442 228 190 307 139 265 -140 -5 -191 135 65 -6 291 -83 -98 141 -49 54 -237 -200 70 -93 63 49 -56 71 -201 145 -222 -274 -165 -571 -180 -89 -172 -39 -353 73 -33 215 595 137 329 -116 56 48 -163 -48 -167 -312 295 -324 46 25 -609 215 -210 -371 162 -23 86 -81 -241 -321 -21 91 -6 95 -29 29 -43 269 81 -96 159 47 159 56 -51 -615 -275 -664 -68 -160 -337 -143 -186 -4 105 -35 20 96 291 126 4 460 374 191 -177 -40 143 -102 357 -15 275 17 124 78 759 246 90 303 -90 -446 -145 225 30 -191 -205 346 24 23 10 248 -52 255 -168 -43 -255 -423 SQ 20241105T170522.2Z 9075.712063 184 1 49.47 2 47.90 160.53 85.83 127.17 0.00 1 0.00 1 0 15 1.593e-03 1.595e-03 2.266e-04 2.261e-04 3.240543e+03 1.409205e+01 2.291849e+02 -6.000000e+00 9.011623e+01 289.38 -2.00 20.00 -2.00 505.24 0.00e+00 6.263474e-04 6.289643e-06 3.950188e-05 -6.000000e+00 4.523070e-05 289.38 -2.00 20.00 -2.00 500.38 0.00e+00 -2.996782e-02 4.437382e-03 2.124208e-02 -6.000000e+00 3.129606e-02 225.60 -2.00 3.24 -2.00 501.98 0.00e+00 1.489 0.000 489.00 513.00 1 5.0632e+00 3.4086e-04 2.9459e-03 -6.0000e+00 2.4047e-03 2.8707e-03 8.8146e-05 5.1536e-04 -6.0000e+00 6.2553e-04 9.9159e-03 4.7037e-04 2.2064e-05 2.8820e-05 -6.0000e+00 1.6064e-04 -1.3808e-02 1.7139e-05 10 0 0 10 0 0 99.96 24.07 1.81 -0.01381 -0.01055 367 78 1 4 0 134.780 26.62 20.00 24.07 27.69 32.8 1073.25 -26 -19 39 114 77 349 357 274 225 109 64 -14 -156 -71 -88 -187 -100 -26 18 -75 47 243 211 279 339 183 138 120 -11 -139 -52 -96 -189 77 -97 -285 -106 9 -105 -133 -14 -38 10 63 37 51 83 -14 -15 -135 -273 -268 -337 -329 -135 -125 -193 -75 -61 71 131 263 153 89 115 105 36 -12 -25 -123 -172 -17 -149 -155 -44 -176 -249 -185 -78 -131 -187 -160 -192 -204 9 -88 -144 -85 -93 -30 -13 19 151 110 39 176 134 -82 -153 -167 -318 -285 -332 -192 -111 -345 -156 -77 -68 -34 73 -41 8 131 175 257 282 338 238 152 212 212 50 171 171 0 63 164 80 150 251 31 50 139 -59 -48 69 30 -57 18 166 39 46 165 137 52 57 -66 -143 -161 -268 -26 -19 39 118 80 363 378 293 239 115 67 -15 -161 -72 -88 -190 -103 -27 20 -79 49 256 222 295 359 195 146 126 -12 -141 -53 -96 -191 78 -102 -298 -111 10 -108 -137 -15 -39 11 64 39 53 86 -15 -15 -136 -272 -264 -328 -321 -132 -126 -196 -77 -62 73 134 267 156 90 116 107 36 -12 -25 -121 -167 -17 -146 -153 -43 -173 -246 -180 -75 -125 -178 -153 -186 -199 8 -86 -142 -84 -92 -30 -13 19 150 111 39 174 132 -79 -146 -156 -300 -266 -317 -186 -109 -341 -156 -76 -66 -33 72 -41 8 131 176 259 282 339 239 151 211 207 49 167 165 0 61 159 77 145 241 30 48 130 -56 -46 65 29 -56 18 162 39 46 163 136 52 56 -64 -137 -154 -257 SQ 20241105T171002.6Z 9075.715308 187 1 12.25 2 47.58 161.98 85.06 127.78 0.00 1 0.00 1 0 15 1.631e-03 1.633e-03 1.614e-04 1.611e-04 3.202968e+03 1.000280e+01 2.264572e+02 -6.000000e+00 9.221216e+01 289.38 -2.00 20.00 -2.00 505.24 0.00e+00 6.673396e-04 4.480531e-06 4.127985e-05 -6.000000e+00 4.628295e-05 289.38 -2.00 20.00 -2.00 500.40 0.00e+00 -3.989068e-02 3.156747e-03 2.115254e-02 -6.000000e+00 3.202534e-02 225.60 -2.00 3.24 -2.00 501.99 0.00e+00 1.480 0.000 489.00 513.00 1 3.0121e+00 2.4247e-04 2.9449e-03 -6.0000e+00 2.4607e-03 7.8880e-04 6.2724e-05 5.1109e-04 -6.0000e+00 6.4013e-04 7.7229e-02 5.5032e-04 1.5712e-05 2.8956e-05 -6.0000e+00 1.6438e-04 -1.3515e-02 1.2347e-05 12 1 1 12 1 1 99.16 24.06 1.83 -0.01351 -0.00970 335 109 1 4 0 36.220 26.62 20.00 24.06 27.80 32.8 1073.14 -65 -70 55 84 113 326 378 195 190 170 61 14 -136 -104 -110 -178 -128 22 37 -64 72 262 203 289 353 208 141 141 -25 -189 -41 -114 -194 54 -98 -319 -115 35 -83 -119 -19 -21 -20 34 76 102 86 77 -40 -177 -309 -268 -344 -337 -187 -149 -155 -111 0 85 175 236 180 114 124 59 52 4 -54 -123 -136 -76 -133 -146 -51 -174 -269 -159 -118 -130 -193 -141 -194 -209 27 -43 -159 -74 -53 -7 -2 60 166 81 7 198 116 -74 -155 -158 -288 -273 -335 -177 -149 -349 -165 -39 -92 -10 9 -84 -18 100 157 219 296 352 271 166 200 172 69 201 220 24 96 232 69 134 231 22 9 94 -51 -61 107 -39 -122 61 130 51 166 177 83 50 23 -79 -166 -192 -227 -64 -69 55 86 117 341 396 206 201 178 63 14 -140 -106 -111 -181 -130 23 38 -67 75 275 214 305 373 218 149 147 -26 -192 -42 -115 -196 55 -101 -334 -120 37 -85 -121 -19 -21 -21 35 80 107 90 80 -41 -180 -309 -265 -335 -330 -185 -149 -157 -113 0 86 178 239 183 116 126 60 52 4 -53 -120 -133 -74 -129 -144 -50 -172 -265 -153 -114 -125 -186 -137 -187 -203 27 -42 -157 -73 -52 -7 -2 59 167 81 7 196 114 -73 -148 -149 -272 -256 -318 -172 -147 -348 -163 -39 -89 -9 9 -82 -18 100 158 221 296 354 273 165 199 170 68 196 215 24 94 227 68 131 225 21 9 89 -49 -58 102 -38 -118 60 127 50 165 176 83 50 23 -77 -161 -183 -216 SQ 20241105T171452.3Z 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