File name: Pandora25s1_HoustonTX_20250213_L2Fit_fout2c9d20230101p1-8.txt File generation date: 20250214T064612.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20250213_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20250213 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250213T152205.6Z 9175.640342 314 1 19.77 2 63.30 125.44 110.03 294.79 0.00 1 0.00 1 0 17 8.446e-03 5.047e-03 1.635e-03 6.614e-04 2.682779e-01 3.364492e-04 3.020541e-03 -6.000000e+00 4.853006e-03 225.14 -2.00 3.24 -2.00 316.72 0.00e+00 2.045532e-04 4.278969e-05 4.589961e-05 -6.000000e+00 2.175379e-04 284.79 -2.00 20.00 -2.00 315.98 0.00e+00 2.213 0.000 302.00 328.00 3 2.1112e+00 8.7423e-04 2.5368e-02 -6.0000e+00 1.1972e-02 5.6255e-03 9.8127e-04 1.2674e-02 -6.0000e+00 1.2995e-02 -1.8802e-04 5.7679e-04 6.2426e-03 -6.0000e+00 7.7666e-03 -2.1238e-03 2.7813e-04 1.7796e-03 -6.0000e+00 3.3364e-03 5.1714e-03 -1.4321e-04 1.9328e-05 2.1983e-05 -6.0000e+00 2.3615e-04 -3.7241e-03 0.0000e+00 12 1 1 12 9 1 99.99 23.97 0.21 -0.00372 -0.00480 157 84 1 5 0 125.060 26.51 20.00 23.97 13.09 31.5 1064.84 -1902 -2469 -2359 -3568 -3978 -2268 -237 -365 585 -552 -1474 -664 -808 297 427 626 140 846 470 424 624 236 704 493 138 12 -334 -602 -179 337 1513 1417 1175 -455 -1721 -675 -939 95 92 -533 -822 -323 -632 -802 -432 -401 -660 -562 -353 93 590 651 870 713 522 844 377 382 620 729 942 1056 1110 918 179 -233 -63 -65 706 443 21 -35 -197 38 73 117 -112 -230 45 -314 -782 -1001 -1661 -1353 -968 -809 -529 -212 -11 116 374 468 508 922 720 427 473 467 -3 -388 -255 -400 -148 126 -500 -1026 -654 -553 -189 289 -15 10 34 103 67 439 489 384 120 2 -447 -149 21 174 332 607 472 1110 781 417 243 -74 -5 229 -2 -57 -327 20 -225 -274 -255 -299 -271 -287 -378 -366 -561 -564 -306 -34 -58 102 -95 -254 -118 -162 68 111 166 39 244 142 132 197 75 227 169 47 4 -118 -214 -60 110 517 527 444 -179 -648 -247 -376 41 48 -308 -494 -203 -409 -526 -282 -262 -424 -353 -217 58 382 452 607 525 398 626 286 289 483 563 712 854 931 822 162 -197 -52 -52 594 401 20 -35 -190 37 66 100 -91 -186 36 -268 -723 -984 -1765 -1447 -1100 -947 -628 -260 -14 138 430 511 529 961 752 472 560 589 -3 -508 -326 -492 -170 147 -610 -1339 -858 -761 -263 413 -23 14 52 151 94 570 647 508 163 2 -654 -216 30 246 461 800 614 1421 1058 588 351 -111 -7 349 -3 -92 -541 33 -374 -461 -414 -483 -427 SS 20250213T153746.0Z 9175.651227 326 1 22.18 2 60.58 128.47 113.02 297.17 0.00 1 0.00 1 0 17 1.157e-02 5.665e-03 3.926e-03 1.721e-03 2.495040e-01 8.768851e-04 2.811525e-03 -6.000000e+00 6.646247e-03 225.14 -2.00 3.24 -2.00 316.48 0.00e+00 -1.983925e-05 1.049376e-04 4.518300e-05 -6.000000e+00 2.979135e-04 284.79 -2.00 20.00 -2.00 315.75 0.00e+00 2.026 0.000 302.00 328.00 3 4.2405e+00 2.2712e-03 2.3319e-02 -6.0000e+00 1.6396e-02 2.8649e-02 2.5445e-03 1.1767e-02 -6.0000e+00 1.7796e-02 -1.0390e-03 1.4852e-03 5.8025e-03 -6.0000e+00 1.0636e-02 -2.3590e-03 7.0861e-04 1.6460e-03 -6.0000e+00 4.5695e-03 7.5207e-04 -1.0246e-04 5.0329e-05 2.0597e-05 -6.0000e+00 3.2339e-04 -4.0562e-03 0.0000e+00 12 1 1 12 1 1 99.90 23.96 0.12 -0.00406 -0.00483 21 10 1 5 0 1008.130 26.51 20.00 23.96 13.37 31.7 1067.73 5708 -2746 -1079 -2018 -1108 -2714 3926 177 3067 -1175 -2372 2805 -1916 930 -574 -2903 -1254 1790 -800 1558 167 244 -124 -668 -124 -114 247 -1273 899 -811 3199 1898 1470 -1009 -2502 -816 -621 1885 96 -679 -1223 -228 -1084 -594 -317 -231 -1667 -601 -158 -384 517 495 1059 297 1108 816 814 -42 604 533 1498 760 955 1085 96 -139 -89 51 848 409 1 143 159 338 152 292 -681 118 245 -367 -792 -1283 -1474 -1251 -814 -885 -575 -219 -203 198 391 243 256 946 737 407 143 679 -44 -313 -277 -474 155 -53 -319 -717 -820 -532 -104 13 64 -16 323 44 48 368 336 369 121 -52 -523 -144 28 193 331 700 248 1401 407 383 366 -103 -12 213 11 -170 -274 198 -267 -307 -81 -426 -238 891 -495 -194 -343 -170 -409 592 31 566 -234 -474 551 -432 229 -159 -881 -390 560 -263 517 57 83 -43 -243 -47 -44 95 -474 312 -282 1122 715 590 -419 -1007 -320 -260 872 52 -408 -786 -151 -734 -403 -215 -156 -1122 -395 -102 -249 345 347 768 224 850 637 642 -33 471 415 1180 630 834 985 88 -121 -74 42 714 373 1 143 159 330 143 257 -564 94 199 -320 -748 -1297 -1557 -1362 -921 -1045 -700 -272 -254 242 457 269 268 963 771 452 170 852 -58 -411 -352 -574 180 -63 -394 -921 -1084 -721 -145 19 96 -25 478 63 66 481 434 487 167 -74 -764 -210 41 270 451 925 320 1778 536 526 518 -150 -17 317 17 -270 -443 324 -441 -502 -130 -672 -369 SS 20250213T154248.7Z 9175.654730 329 1 49.80 2 59.72 129.49 113.97 297.97 0.00 1 0.00 1 0 17 2.066e-02 5.878e-03 2.422e-03 9.052e-04 2.417184e-01 4.592996e-04 2.730221e-03 -6.000000e+00 1.186642e-02 225.14 -2.00 3.24 -2.00 317.00 0.00e+00 2.329652e-04 6.206181e-05 4.627278e-05 -6.000000e+00 5.319870e-04 284.79 -2.00 20.00 -2.00 316.25 0.00e+00 1.975 0.000 302.00 328.00 3 3.6044e+00 1.1996e-03 2.2716e-02 -6.0000e+00 2.9273e-02 9.9931e-03 1.3483e-03 1.1456e-02 -6.0000e+00 3.1777e-02 3.0235e-03 7.9824e-04 5.6474e-03 -6.0000e+00 1.8992e-02 -3.4815e-03 3.8846e-04 1.6098e-03 -6.0000e+00 8.1564e-03 1.5231e-03 -3.8488e-04 2.6835e-05 1.9745e-05 -6.0000e+00 5.7764e-04 -1.7631e-03 0.0000e+00 11 1 0 11 8 0 99.99 23.96 0.16 -0.00176 -0.00466 388 82 1 5 0 127.660 26.51 20.01 23.96 13.75 31.7 1069.46 -22349 396 -2065 -425 -2230 -73 1795 866 2696 197 -329 1214 487 176 1287 1736 540 965 1059 762 968 1086 859 633 -64 306 -573 -427 -2 868 1993 2620 1123 -14 -1623 97 -423 855 -79 -794 -761 -790 -783 -1009 -448 -670 -684 -664 -39 -63 853 509 570 903 410 775 283 459 481 643 787 1060 955 1061 101 -224 -125 -323 971 412 121 -106 -82 -215 416 34 -168 -314 210 -436 -687 -961 -1566 -1468 -907 -882 -398 -37 -81 361 262 395 232 798 527 386 396 377 -10 -354 -252 -501 -132 -4 -474 -878 -567 -555 -106 828 185 147 60 104 -27 507 425 412 22 101 -544 -175 -73 126 283 524 344 1035 587 242 243 -200 -11 195 87 -87 -218 33 -222 -227 -138 -264 -265 -3742 57 -308 -58 -289 -9 229 120 406 32 -53 197 89 37 290 424 139 256 292 217 280 312 253 197 -20 100 -187 -136 -1 251 599 844 395 -5 -564 32 -149 348 -37 -423 -443 -481 -490 -638 -281 -420 -420 -397 -23 -37 517 331 378 627 295 568 211 342 352 467 588 816 798 909 87 -187 -100 -250 782 362 113 -104 -81 -205 369 28 -131 -231 158 -356 -632 -947 -1612 -1586 -1008 -1051 -485 -46 -103 440 306 435 241 790 544 423 467 477 -14 -467 -323 -612 -151 -5 -579 -1147 -751 -770 -149 1226 282 230 92 152 -37 669 550 553 31 147 -821 -263 -106 183 388 704 453 1337 776 334 354 -295 -17 300 137 -146 -366 57 -388 -390 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