File name: Pandora25s1_HoustonTX_20250323_L2Fit_fout2c9d20230101p1-8.txt
File generation date: 20250324T063201.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c9p1-8
Local principal investigator: Jimmy Flynn
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 25
Spectrometer number: 1
Processing software version used: BlickP v1.8.74
Instrument operation file used: Pandora25_OF_v7d20190903.txt
Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt
Level 1 file used: Pandora25s1_HoustonTX_20250323_L1_smca1c9d20230101p1-8.txt
Full location name: University Of Houston
Short location name: HoustonTX
Country of location: United States
Location latitude [deg]: 29.7200
Location longitude [deg]: -95.3400
Location altitude [m]: 19
Local noon date: 20250323
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 8, but repeated E-MLE of HCHO.
First and last pixel inside fitting window: 281 423
Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250323T141309.6Z 9213.592473 208 1 8.69 2 66.67 102.61 58.92 191.50 0.00 1 0.00 1 0 17 1.271e-02 4.902e-03 6.666e-03 1.576e-03 3.455802e-01 8.064616e-04 3.817132e-03 -6.000000e+00 7.378013e-03 227.68 -2.00 3.24 -2.00 317.71 0.00e+00 4.790539e-04 1.324322e-04 8.449913e-05 -6.000000e+00 3.297634e-04 286.46 -2.00 20.00 -2.00 316.92 0.00e+00 2.505 0.000 302.00 328.00 3 2.5368e+00 2.1441e-03 2.9953e-02 -6.0000e+00 1.8298e-02 1.8721e-02 2.4215e-03 1.6484e-02 -6.0000e+00 1.9814e-02 -8.0070e-03 1.5074e-03 8.0715e-03 -6.0000e+00 1.1831e-02 -1.4043e-03 7.6818e-04 2.3074e-03 -6.0000e+00 5.0680e-03 2.2212e-03 -2.1525e-04 4.5796e-05 2.6391e-05 -6.0000e+00 3.5545e-04 -9.5165e-03 0.0000e+00 12 1 1 12 9 1 99.99 24.32 0.22 -0.00952 -0.01113 33 41 1 5 0 255.220 26.83 20.00 24.32 29.24 32.6 1100.00 2596 -1269 -3723 -5073 -5265 -5752 2910 -1795 3592 -3403 -2428 27 -2298 230 -1456 333 -1339 -145 -780 1759 -1293 -710 224 -159 114 -913 -626 -977 -669 653 3146 1150 1068 -685 -1498 -825 -1292 571 71 -440 -1488 -528 -528 -691 69 -106 -723 -383 -417 130 1154 1051 673 797 913 921 458 539 762 67 1096 999 1362 549 392 -173 -107 -47 785 209 -90 32 -295 37 133 90 5 98 70 -228 -902 -1098 -1569 -1313 -973 -904 -508 -114 305 59 475 623 435 778 622 228 404 519 116 -365 -427 -356 -131 175 -534 -787 -652 -583 -228 253 171 -54 -128 197 8 527 568 491 227 -112 -461 -241 -56 184 275 506 245 1084 578 324 39 -257 -29 245 55 -7 -237 134 -48 -373 -198 -243 -202 182 -101 -312 -409 -389 -416 207 -150 315 -335 -240 3 -270 31 -225 56 -242 -27 -154 352 -270 -148 48 -36 27 -226 -155 -233 -152 148 744 302 303 -203 -431 -233 -393 195 28 -198 -728 -268 -275 -364 36 -56 -381 -200 -217 68 631 610 410 507 597 615 311 366 511 45 743 712 1031 440 318 -136 -81 -35 606 175 -81 30 -274 33 115 73 4 73 54 -189 -814 -1065 -1602 -1384 -1065 -1033 -599 -137 366 70 539 670 447 782 647 253 481 659 154 -488 -554 -439 -155 207 -662 -1016 -867 -797 -322 372 261 -85 -197 294 11 726 774 683 327 -168 -704 -366 -83 269 391 701 331 1449 803 473 59 -400 -45 396 92 -12 -415 238 -85 -662 -343 -412 -336
SS 20250323T142510.9Z 9213.600821 213 1 8.00 2 64.13 104.38 59.48 194.45 0.00 1 0.00 1 0 17 4.331e-01 7.455e-02 5.403e-02 1.110e-02 2.670799e-01 5.601855e-03 3.106739e-03 -6.000000e+00 2.521586e-01 227.69 -2.00 3.24 -2.00 317.71 0.00e+00 2.386125e-02 9.387775e-04 4.339741e-04 -6.000000e+00 1.123998e-02 286.46 -2.00 20.00 -2.00 316.98 0.00e+00 2.278 0.000 302.00 328.00 3 4.9887e+00 1.5023e-02 2.8622e-02 -6.0000e+00 6.2569e-01 1.2925e-01 1.6977e-02 3.0572e-02 -6.0000e+00 6.7805e-01 -3.8654e-01 9.7036e-03 1.1315e-02 -6.0000e+00 4.0491e-01 2.5391e-01 4.6233e-03 1.7967e-02 -6.0000e+00 1.7299e-01 2.5269e-04 5.6269e-04 3.2162e-04 1.7507e-04 -6.0000e+00 1.2114e-02 -8.9350e-03 0.0000e+00 12 9 9 12 33 1 999.00 24.30 0.94 -0.00893 -0.00471 1 3 2 5 0 4000.000 26.83 20.00 24.30 29.29 32.7 1100.00 -88061 184127 134845 187503 135469 104505 159854 83093 120641 70797 40721 69302 39590 70225 59070 900000 78858 85840 75870 78540 80383 68334 60905 48087 29823 17428 19640 12422 17265 24165 69232 36113 32326 30696 20642 30267 30792 39302 15583 2716 -2799 3663 631 10723 6875 15007 10345 14556 18762 15302 15755 8427 9723 4699 2821 -4080 -4099 -13061 -6398 -8275 -1003 -2252 2618 -990 -2876 -711 2949 -2067 -2672 -1665 -5700 -3131 -7759 -8778 -8051 -6300 -9046 -3952 -4201 -3810 -2821 -6214 -4389 -5015 -3723 -6089 -4352 -4364 -4442 -2430 -1619 -3211 -5452 456 -3531 338 -2199 1848 99 -1411 -328 536 820 216 2704 1366 2195 1310 3069 3635 1844 2866 1323 -704 -82 1261 1705 1155 2948 1684 3273 4043 4626 2815 2978 2279 1786 3725 2932 3588 1400 1046 -1117 987 877 -2410 -720 -2305 -2840 -2820 -2086 -3859 -3039 -51588 9969 11723 9092 9235 8360 6966 7171 7061 6249 4486 6148 5580 9166 10157 900000 13328 14145 14072 14366 14160 12660 11282 9324 6428 4073 4408 2916 3891 5406 11369 8877 8841 8596 5894 7587 7989 10342 5620 1191 -1349 1727 317 5131 3502 7318 5293 7148 8785 7378 7819 4663 5512 2842 1732 -2612 -2587 -8733 -4016 -5368 -646 -1583 1919 -791 -2354 -543 2062 -1463 -1971 -1327 -5007 -2778 -7107 -7866 -6805 -4866 -6648 -2709 -3020 -3017 -2446 -5968 -4370 -5190 -3994 -6988 -5140 -5307 -5451 -2889 -1824 -3429 -5553 432 -3588 362 -2618 2320 133 -1915 -426 653 953 254 3291 1757 2912 1814 4367 5400 2886 4525 2075 -1073 -118 1721 2302 1612 4254 2567 5041 6179 6922 4155 4243 3154 2399 4909 4037 5173 2129 1630 -1786 1588 1457 -4223 -1268 -4156 -5163 -5063 -3635 -6616 -5065
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