File name: Pandora25s1_HoustonTX_20250501_L2Fit_fout2c9d20230101p1-8.txt File generation date: 20250502T062825.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20250501_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20250501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250501T123706.2Z 9252.525766 60 1 49.16 2 78.55 78.85 111.22 37.11 0.00 1 0.00 1 0 25 5.712e-01 2.895e-02 1.729e-01 2.825e-03 6.305478e-01 1.532819e-03 8.079832e-03 -6.000000e+00 3.384709e-01 230.26 -2.00 3.24 -2.00 320.78 0.00e+00 1.732268e-02 6.623845e-04 5.464383e-03 -6.000000e+00 1.519768e-02 289.10 -2.00 20.00 -2.00 320.11 0.00e+00 4.869 0.001 302.00 328.00 3 2.3834e+00 4.9854e-03 5.9745e-02 -6.0000e+00 8.4630e-01 3.0737e-01 6.2763e-03 3.4504e-02 -6.0000e+00 9.1547e-01 -4.7406e-01 5.2249e-03 2.5145e-02 -6.0000e+00 5.4190e-01 2.1254e-01 2.5832e-03 1.4092e-02 -6.0000e+00 2.2995e-01 1.7837e-04 -1.4302e-03 7.8817e-05 2.3920e-04 -6.0000e+00 1.6245e-02 -9.1858e-03 0.0000e+00 12 9 8 11 8 0 83.18 24.15 0.32 -0.00919 -0.01993 63 13 1 5 0 779.930 26.73 20.00 24.15 30.66 33.4 1100.00 -245135 81237 33639 251860 22092 23824 900000 -26156 900000 -42646 -24551 147428 -7089 50854 8659 403284 82639 153042 72603 115938 66233 93620 65522 58840 21535 37810 16670 29621 11950 21257 86454 58018 65567 36124 24078 47586 50239 92208 36955 22036 12209 24178 14713 24574 27903 31738 19777 23510 31507 24000 27322 21766 16285 21227 16449 12244 10371 -997 6042 2275 7023 5841 8981 6284 5862 7612 7105 3798 7013 3811 3198 2476 -518 -1110 1419 1337 -5908 -950 407 1188 -40 -1864 -3536 -1817 -3468 -4114 -3150 -2870 -2356 -1169 -37 -945 -3310 -2968 -3474 -1850 -2013 -1235 -934 -1175 -256 -1080 -726 -1556 -948 -1681 -1944 -1329 124 -1098 -17 92 335 -6 331 776 175 613 581 861 1119 1521 1962 1503 1453 2090 1447 2208 1326 1232 1060 631 433 971 -16 -458 -358 -465 -888 -920 -559 -972 -1235 -24947 447 317 694 199 193 900000 -331 900000 -658 -334 429 -113 641 204 1111 1341 1353 1459 1647 1468 1601 1380 1321 700 1046 569 877 431 779 2000 2157 2485 1952 1402 2115 2306 3326 2588 1972 1328 2488 1761 2784 3157 3587 2604 3093 3987 3313 3988 3711 3180 4216 3563 2807 2436 -248 1425 555 1707 1523 2589 2100 2094 2637 2414 1353 2609 1598 1490 1216 -260 -531 607 536 -2359 -361 169 557 -22 -1165 -2472 -1277 -2633 -3352 -2681 -2523 -2076 -992 -29 -700 -2476 -2230 -2779 -1685 -2066 -1401 -1130 -1460 -301 -1202 -757 -1601 -1027 -1888 -2314 -1628 164 -1579 -27 151 538 -10 505 1164 262 922 927 1442 1829 2484 3070 2283 2188 3009 2091 3103 2070 2105 1944 1210 850 1998 -35 -1018 -819 -1084 -2089 -2109 -1242 -2041 -2550 SS 20250501T124303.1Z 9252.529897 63 1 49.34 2 77.28 79.53 110.47 38.18 0.00 1 0.00 1 0 25 2.674e-01 5.436e-03 1.319e-01 1.653e-03 5.947049e-01 8.812875e-04 6.317461e-03 -6.000000e+00 1.567031e-01 230.26 -2.00 3.24 -2.00 320.35 0.00e+00 1.742419e-03 3.349303e-04 4.333653e-04 -6.000000e+00 7.015177e-03 289.10 -2.00 20.00 -2.00 319.64 0.00e+00 4.419 0.001 302.00 328.00 3 2.0207e+00 2.7098e-03 5.2894e-02 -6.0000e+00 3.9068e-01 1.5103e-02 3.4396e-03 2.9579e-02 -6.0000e+00 4.2205e-01 -1.9949e-02 3.1229e-03 1.4649e-02 -6.0000e+00 2.5188e-01 -1.5153e-03 1.5754e-03 5.1951e-03 -6.0000e+00 1.0760e-01 4.4305e-04 -8.2612e-04 4.6562e-05 5.1077e-05 -6.0000e+00 7.4831e-03 -9.2026e-03 0.0000e+00 10 0 0 10 0 0 97.74 24.16 0.19 -0.00920 -0.01541 112 24 1 5 0 440.470 26.73 19.99 24.16 30.92 33.2 1100.00 -73660 -51329 -35334 -55312 -44682 -87961 154440 -59601 155620 -73275 -78819 10333 -52036 -12674 -33298 65995 -10740 21696 -22309 8722 -20143 -410 -11818 -2339 -21884 -4547 -15194 -10955 -7892 -14887 13788 -4393 4408 -6930 -7825 1427 4698 12869 1362 -2247 -1568 205 -1885 2159 2298 1747 -3950 -1390 289 1768 1289 2134 -136 2699 1733 1099 1084 -1680 712 -589 1329 31 1444 242 673 -364 1104 -55 1439 1208 881 1061 -220 481 347 701 -1813 -75 -191 633 -638 -699 -1967 -773 -788 -955 141 -131 52 497 1146 742 350 221 691 335 -118 251 32 -409 -82 -561 -242 -13 -272 -1019 -1159 -636 -249 341 -56 146 31 90 112 642 327 241 -39 -255 -698 -144 333 76 256 487 215 1022 234 178 164 -128 45 306 -89 -180 -184 104 -225 -216 21 -5 -100 -662 -432 -273 -510 -345 -1043 249 -673 251 -1103 -1330 87 -951 -199 -802 752 -278 450 -733 238 -713 -13 -411 -81 -1006 -187 -710 -479 -330 -714 581 -263 279 -498 -553 97 342 968 141 -291 -216 30 -297 336 363 284 -693 -245 52 334 271 497 -35 708 489 326 333 -532 216 -178 406 11 543 98 286 -154 449 -23 649 626 485 615 -129 268 188 341 -834 -34 -93 359 -408 -487 -1532 -634 -661 -857 133 -127 50 469 1007 638 286 183 619 330 -129 299 40 -525 -103 -651 -267 -14 -314 -1213 -1456 -814 -343 499 -87 241 51 146 171 964 487 374 -62 -425 -1141 -236 525 121 388 708 314 1495 364 300 292 -237 87 603 -182 -390 -398 229 -500 -469 44 -10 -199 SS 20250501T124838.7Z 9252.533781 66 1 49.44 2 76.09 80.18 109.75 39.16 0.00 1 0.00 1 0 25 1.150e-01 4.902e-03 3.607e-02 1.202e-03 5.507322e-01 6.331227e-04 5.896142e-03 -6.000000e+00 6.741912e-02 230.26 -2.00 3.24 -2.00 319.98 0.00e+00 7.415258e-04 2.130643e-04 2.998611e-04 -6.000000e+00 3.018146e-03 289.10 -2.00 20.00 -2.00 319.24 0.00e+00 4.064 0.001 302.00 328.00 3 1.8300e+00 1.8780e-03 4.8686e-02 -6.0000e+00 1.6808e-01 5.2783e-03 2.3073e-03 2.7052e-02 -6.0000e+00 1.8158e-01 -1.2175e-02 1.9800e-03 1.3282e-02 -6.0000e+00 1.0837e-01 -4.1749e-03 1.0187e-03 3.9643e-03 -6.0000e+00 4.6292e-02 7.9100e-04 -8.3996e-04 3.4157e-05 4.3200e-05 -6.0000e+00 3.2194e-03 -9.3147e-03 0.0000e+00 10 0 0 10 0 0 89.64 24.15 0.28 -0.00931 -0.01563 171 36 1 5 0 289.090 26.73 20.00 24.15 31.22 33.2 1100.00 -4363 -19511 -47120 -23914 -39979 -41422 43574 -55118 20849 -43908 -30573 -21229 -24130 -28085 -17668 16980 -8544 6092 -8788 1896 -4778 213 -8927 542 -12302 -1996 -10557 -6502 -9234 -4307 3134 441 2076 -356 -5045 -1154 1755 5022 2040 -3034 -1781 -476 -1283 113 425 768 -1377 -914 758 635 1071 789 295 1628 343 1181 438 -405 51 214 690 169 1662 1247 726 429 799 -319 1259 450 620 413 469 138 657 566 -1036 -3 -10 -8 -643 -722 -1758 -853 -1062 -873 -380 -91 225 534 1059 608 567 494 474 186 40 214 -128 -606 -219 -488 -50 -28 -487 -903 -850 -581 -308 1192 -207 20 91 180 45 647 459 319 -108 -212 -432 -201 -102 -101 206 256 328 966 409 24 145 -81 -129 266 -93 -87 -152 244 -115 -222 22 -87 -194 -32 -193 -658 -257 -469 -490 242 -946 191 -768 -538 -380 -500 -757 -528 423 -307 208 -376 77 -215 9 -447 27 -701 -118 -641 -398 -568 -266 191 32 171 -32 -464 -102 165 544 280 -487 -319 -91 -259 23 88 160 -298 -201 169 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