File name: Pandora25s1_HoustonTX_20250509_L2Fit_fout2c9d20230101p1-8.txt File generation date: 20250510T063012.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20250509_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20250509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250509T130543.2Z 9260.545639 199 1 49.67 2 71.28 80.07 133.47 289.17 0.00 1 0.00 1 0 25 6.373e-02 5.177e-03 1.451e-02 1.338e-03 4.284262e-01 6.952969e-04 4.656936e-03 -6.000000e+00 3.741607e-02 230.68 -2.00 3.24 -2.00 318.95 0.00e+00 4.537928e-04 1.646304e-04 1.582360e-04 -6.000000e+00 1.676304e-03 289.67 -2.00 20.00 -2.00 318.12 0.00e+00 3.077 0.000 302.00 328.00 3 3.1378e+00 1.9315e-03 3.7176e-02 -6.0000e+00 9.3361e-02 1.4676e-02 2.2373e-03 2.0877e-02 -6.0000e+00 1.0081e-01 -3.4236e-03 1.6016e-03 1.0141e-02 -6.0000e+00 6.0163e-02 -3.2626e-03 8.4273e-04 2.8621e-03 -6.0000e+00 2.5698e-02 6.2463e-04 -5.5948e-04 3.8951e-05 3.1940e-05 -6.0000e+00 1.7837e-03 -1.0536e-02 0.0000e+00 10 0 0 10 0 0 99.81 24.21 0.20 -0.01054 -0.01474 98 21 1 5 0 506.690 26.73 20.00 24.21 26.74 33.1 1100.00 56568 -11592 -8348 -5767 -8307 -18796 17579 -15810 8384 -13358 -17185 -1136 -14731 -707 -10562 -736 -1518 6041 -2839 1055 96 -373 -926 -1915 -3107 -2485 -2980 -3998 -1047 -3540 5236 1766 1330 -2041 -3828 -673 -938 5092 213 -1839 -1733 -122 -1267 715 687 863 -1164 -1037 -26 258 932 168 684 1030 803 832 1397 -473 993 173 1282 628 1563 1116 319 -95 -36 -106 637 998 259 527 -110 188 328 638 -1026 -547 -172 -632 -557 -1281 -1649 -1066 -939 -890 -41 -94 236 309 666 530 401 493 380 498 398 467 0 -333 -335 -585 -295 8 -417 -915 -883 -547 18 102 15 153 149 39 138 388 441 246 -214 -246 -463 -88 1 198 194 691 309 1010 421 399 88 -80 22 361 28 -205 -83 254 -279 -219 -110 -275 -266 886 -367 -268 -181 -244 -602 423 -578 285 -576 -791 -48 -841 -40 -793 -57 -129 512 -280 105 10 -39 -96 -217 -384 -321 -390 -507 -123 -437 656 260 219 -366 -672 -113 -173 997 53 -534 -561 -41 -435 246 237 301 -414 -368 -9 95 365 73 306 491 403 432 741 -247 519 90 679 348 949 717 213 -61 -22 -67 411 704 203 421 -88 150 243 440 -657 -348 -111 -454 -444 -1119 -1574 -1037 -974 -959 -45 -107 269 342 707 535 389 468 372 530 466 596 0 -445 -436 -719 -345 9 -506 -1188 -1170 -743 26 151 24 249 240 61 209 564 630 355 -328 -390 -735 -141 2 304 284 988 435 1409 616 624 142 -136 37 626 51 -383 -160 499 -542 -427 -210 -502 -479 SS 20250509T131119.1Z 9260.549526 202 1 10.94 2 70.08 80.69 134.58 290.20 0.00 1 0.00 1 0 25 2.132e-02 5.028e-03 5.054e-03 7.697e-04 4.053556e-01 3.992877e-04 4.439455e-03 -6.000000e+00 1.251845e-02 230.68 -2.00 3.24 -2.00 318.32 0.00e+00 5.354113e-04 7.814822e-05 1.126812e-04 -6.000000e+00 5.608388e-04 289.67 -2.00 20.00 -2.00 317.47 0.00e+00 2.903 0.000 302.00 328.00 3 8.9606e-01 1.0850e-03 3.5089e-02 -6.0000e+00 3.1236e-02 4.4826e-03 1.2350e-03 1.9677e-02 -6.0000e+00 3.3728e-02 -1.0443e-02 8.1691e-04 9.5571e-03 -6.0000e+00 2.0129e-02 9.3106e-04 4.2582e-04 2.6845e-03 -6.0000e+00 8.5981e-03 7.2155e-03 -4.9677e-04 2.2286e-05 3.0455e-05 -6.0000e+00 5.9676e-04 -1.0711e-02 0.0000e+00 12 1 1 12 1 1 59.20 24.22 0.26 -0.01071 -0.01444 140 135 1 5 0 77.550 26.73 20.00 24.22 26.94 33.0 1100.00 -600 -4321 -8065 -6008 -10743 -10576 -5777 -6030 -909 -6775 -4565 -6947 -2287 -3581 -124 244 -387 -341 129 2038 -327 859 -412 633 -787 -329 -2176 -1258 -2421 -84 593 1108 617 -1086 -1891 -2050 -1352 -350 307 -620 -587 -897 -424 -532 31 -514 -406 -349 -566 176 591 1051 857 1095 696 913 589 781 380 788 931 1330 1321 1330 719 59 -109 -70 662 542 283 40 67 -126 279 -50 -293 -318 -122 -333 -949 -954 -1720 -1478 -1008 -708 -554 -97 34 347 366 529 364 730 791 379 465 276 22 -481 -207 -598 -150 66 -648 -1070 -685 -566 -282 317 5 180 30 199 77 488 434 347 89 -125 -538 -183 35 123 438 505 508 1110 649 315 270 -181 10 142 102 -105 -181 118 -198 -225 -168 -237 -382 -24 -203 -411 -286 -488 -468 -263 -313 -50 -425 -286 -478 -176 -334 -13 27 -47 -44 18 286 -48 126 -63 103 -139 -61 -414 -227 -421 -14 112 234 135 -254 -428 -458 -327 -99 97 -235 -232 -378 -185 -237 14 -231 -182 -156 -255 81 291 529 466 634 400 542 359 476 228 466 565 866 899 985 523 44 -76 -49 485 428 236 36 60 -108 231 -37 -211 -221 -89 -264 -824 -887 -1675 -1518 -1054 -790 -627 -113 40 394 404 562 360 734 806 414 550 353 29 -652 -266 -733 -176 78 -790 -1397 -900 -784 -399 465 8 287 48 309 111 686 599 497 130 -196 -837 -281 54 182 639 704 702 1517 918 472 421 -297 17 242 179 -190 -337 218 -369 -411 -303 -421 -657 SS 20250509T141329.6Z 9260.592704 237 1 11.25 2 56.65 87.74 146.28 304.65 0.00 1 0.00 1 0 25 1.567e-02 6.779e-03 8.422e-03 3.608e-03 2.643446e-01 1.878243e-03 2.964267e-03 -6.000000e+00 9.188143e-03 230.69 -2.00 3.24 -2.00 316.53 0.00e+00 -8.044231e-05 2.259886e-04 6.582326e-05 -6.000000e+00 4.119357e-04 289.67 -2.00 20.00 -2.00 315.71 0.00e+00 1.813 0.000 302.00 328.00 3 4.9121e+00 4.9201e-03 2.2235e-02 -6.0000e+00 2.2926e-02 4.6387e-02 5.4913e-03 1.2777e-02 -6.0000e+00 2.4766e-02 -3.0330e-03 3.1919e-03 6.2106e-03 -6.0000e+00 1.4780e-02 -2.1249e-03 1.5139e-03 1.7194e-03 -6.0000e+00 6.3033e-03 4.4948e-04 -1.7823e-03 1.0509e-04 2.1460e-05 -6.0000e+00 4.3883e-04 -8.1333e-04 0.0000e+00 12 9 1 12 1 1 21.14 24.22 0.28 -0.00081 -0.01421 3 4 1 5 0 2810.010 26.73 20.00 24.22 28.56 33.0 1100.00 -5415 4037 -4348 -2708 -8788 -2366 1020 2322 3128 1838 -5560 -2268 -3103 1902 -1568 734 -106 1670 257 2404 2984 -263 668 1695 50 112 955 -988 -2614 -1501 1738 2047 1087 -778 -3340 1332 -772 1736 -866 -726 -1143 -627 -205 301 517 338 -1971 -1214 -696 -837 1336 -485 1578 764 1287 576 1152 -73 216 374 425 -57 599 2033 -146 -65 -1118 11 495 332 911 806 599 -105 1276 -592 -555 -128 -282 -849 -832 -1239 -1914 -1104 -759 -770 -273 413 -195 490 198 627 -486 524 -560 99 -234 983 426 -86 -177 -809 -411 -171 -266 -675 -650 -932 352 318 376 243 11 420 -203 394 51 -18 -263 191 -527 -30 202 379 458 755 263 1340 497 438 138 268 -457 31 42 -327 283 379 -44 -686 -466 -229 -374 -878 651 -767 -444 -1382 -339 150 375 551 342 -1100 -448 -679 448 -424 210 -32 510 82 776 974 -88 226 594 18 43 362 -363 -923 -518 608 762 433 -322 -1351 510 -320 794 -462 -433 -731 -413 -137 202 347 227 -1330 -801 -451 -545 886 -342 1141 576 989 452 910 -58 170 293 338 -48 525 1837 -134 -57 -942 9 418 302 880 805 601 -104 1200 -528 -463 -103 -230 -744 -788 -1255 -2036 -1205 -860 -910 -333 512 -243 601 233 698 -516 538 -592 110 -278 1232 559 -113 -227 -989 -484 -202 -328 -866 -858 -1264 488 457 557 365 16 601 -278 517 66 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