File name: Pandora25s1_HoustonTX_20250511_L2Fit_fout2c9d20230101p1-8.txt File generation date: 20250512T062920.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jimmy Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 25 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora25_OF_v7d20190903.txt Instrument calibration file used: Pandora25s1_CF_v9d20230101.txt Level 1 file used: Pandora25s1_HoustonTX_20250511_L1_smca1c9d20230101p1-8.txt Full location name: University Of Houston Short location name: HoustonTX Country of location: United States Location latitude [deg]: 29.7200 Location longitude [deg]: -95.3400 Location altitude [m]: 19 Local noon date: 20250511 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 8, but repeated E-MLE of HCHO. First and last pixel inside fitting window: 281 423 Nominal wavelengths inside fitting window [nm]: 305.0808 305.2213 305.3618 305.5022 305.6427 305.7831 305.9235 306.0640 306.2044 306.3447 306.4851 306.6255 306.7658 306.9062 307.0465 307.1868 307.3272 307.4675 307.6077 307.7480 307.8883 308.0285 308.1688 308.3090 308.4492 308.5894 308.7296 308.8698 309.0100 309.1501 309.2903 309.4304 309.5705 309.7106 309.8507 309.9908 310.1309 310.2710 310.4110 310.5511 310.6911 310.8311 310.9711 311.1111 311.2511 311.3911 311.5310 311.6710 311.8109 311.9508 312.0907 312.2306 312.3705 312.5104 312.6503 312.7901 312.9300 313.0698 313.2096 313.3494 313.4892 313.6290 313.7688 313.9085 314.0483 314.1880 314.3277 314.4675 314.6072 314.7468 314.8865 315.0262 315.1658 315.3055 315.4451 315.5847 315.7243 315.8639 316.0035 316.1431 316.2826 316.4222 316.5617 316.7013 316.8408 316.9803 317.1198 317.2592 317.3987 317.5382 317.6776 317.8170 317.9564 318.0958 318.2352 318.3746 318.5140 318.6534 318.7927 318.9320 319.0714 319.2107 319.3500 319.4893 319.6285 319.7678 319.9070 320.0463 320.1855 320.3247 320.4639 320.6031 320.7423 320.8815 321.0206 321.1598 321.2989 321.4380 321.5771 321.7162 321.8553 321.9944 322.1334 322.2725 322.4115 322.5506 322.6896 322.8286 322.9676 323.1065 323.2455 323.3845 323.5234 323.6623 323.8012 323.9402 324.0790 324.2179 324.3568 324.4957 324.6345 324.7733 324.9122 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250511T123018.6Z 9262.521049 206 1 49.30 2 78.55 75.65 113.97 262.46 0.00 1 0.00 1 0 25 3.775e-01 9.314e-03 1.402e-01 2.159e-03 6.757076e-01 1.183798e-03 7.131986e-03 -6.000000e+00 2.247140e-01 230.79 -2.00 3.24 -2.00 320.80 0.00e+00 3.530053e-03 5.244857e-04 3.822450e-04 -6.000000e+00 1.007763e-02 289.81 -2.00 20.00 -2.00 320.13 0.00e+00 4.867 0.001 302.00 328.00 3 1.9096e+00 3.8761e-03 5.8977e-02 -6.0000e+00 5.6268e-01 7.1005e-02 5.1813e-03 3.4044e-02 -6.0000e+00 6.0873e-01 -7.3499e-02 4.9433e-03 1.7603e-02 -6.0000e+00 3.6045e-01 2.3885e-02 2.4100e-03 7.7148e-03 -6.0000e+00 1.5257e-01 2.8906e-04 -1.0541e-03 5.9855e-05 7.3490e-05 -6.0000e+00 1.0739e-02 -9.3098e-03 0.0000e+00 11 9 0 11 8 0 99.95 24.22 0.13 -0.00931 -0.01723 105 22 1 5 0 469.420 26.73 20.00 24.22 25.18 33.0 1100.00 -267489 35386 -116345 55121 -104388 -139108 900000 -139929 900000 -129384 -109316 -15074 -77192 -54731 -71402 900000 -10549 26155 -18034 22906 -14917 4854 -25295 1474 -19943 3009 -24515 -9279 -12464 -13935 23609 17941 10931 -2797 -11520 -4507 7772 40894 3395 -5767 -2305 5464 2677 3318 7700 7776 -1511 -115 9668 1827 6079 3584 2291 5443 2299 3583 2895 -3648 924 -1246 1207 305 1166 -359 1294 1297 2071 -314 3556 1211 2189 1427 676 1 1212 1489 -3227 -259 888 833 -394 -872 -2497 -692 -1333 -1261 -781 -200 -361 870 746 543 559 233 233 51 40 64 -191 -535 40 -781 -199 -239 -212 -1309 -852 -816 -252 -17 -248 -5 -39 304 120 483 523 442 -27 -128 -440 162 121 347 412 680 272 1062 485 168 255 22 108 405 -290 -206 -199 129 -251 -331 -48 -174 -36 -7340 74 -1051 116 -787 -1430 900000 -1775 900000 -1817 -1365 -92 -1033 -762 -1435 900000 -167 331 -366 343 -322 89 -636 32 -559 73 -775 -253 -350 -430 614 583 435 -135 -592 -217 366 1680 235 -514 -224 534 283 360 821 850 -185 -14 1167 254 897 604 429 1074 496 799 669 -899 214 -291 283 79 335 -117 441 440 690 -110 1309 514 1014 697 332 1 528 591 -1251 -98 365 396 -218 -546 -1725 -498 -1018 -1016 -654 -172 -312 726 593 409 407 172 187 46 41 72 -233 -667 48 -874 -207 -244 -226 -1478 -1000 -1007 -330 -24 -381 -8 -63 487 186 723 779 676 -43 -211 -730 263 191 533 615 986 386 1518 748 283 461 43 214 831 -623 -461 -453 297 -582 -753 -104 -366 -74 SS 20250511T124451.0Z 9262.531146 215 1 49.18 2 75.48 77.28 117.01 263.99 0.00 1 0.00 1 0 25 4.426e-01 3.754e-02 2.275e-01 1.155e-02 5.790673e-01 6.512205e-03 6.548124e-03 -6.000000e+00 2.650983e-01 230.79 -2.00 3.24 -2.00 320.63 0.00e+00 1.806723e-03 2.566157e-03 2.934530e-03 -6.000000e+00 1.344468e-02 289.81 -2.00 20.00 -2.00 319.92 0.00e+00 3.904 0.001 302.00 328.00 3 5.0728e+00 2.0672e-02 5.0143e-02 -6.0000e+00 6.6440e-01 1.8274e-01 2.6105e-02 3.3896e-02 -6.0000e+00 7.2077e-01 -2.4870e-01 2.1409e-02 1.5578e-02 -6.0000e+00 4.2565e-01 1.3200e-01 1.0623e-02 3.9902e-03 -6.0000e+00 1.8234e-01 3.1973e-05 -3.3425e-03 3.5079e-04 6.4768e-05 -6.0000e+00 1.3246e-02 -2.9206e-03 0.0000e+00 12 8 8 10 0 0 99.99 24.22 0.16 -0.00292 -0.02804 69 15 1 5 0 712.620 26.73 20.00 24.22 25.37 32.7 1100.00 16808 900000 -10461 900000 900000 -48379 900000 -90445 900000 -75890 -30894 900000 -8459 151202 -50264 -160733 38792 900000 23216 900000 900000 900000 42088 134135 -4285 170359 -8238 154596 -8693 43512 900000 96227 116229 14454 63778 133150 162385 900000 98896 3439 5200 30639 5973 32226 50287 50835 -2115 4590 36411 33975 35242 22427 5484 31507 17280 11721 22623 -17826 6954 -4506 13012 -10412 6842 -7855 3111 1891 14245 3429 16669 1262 9501 4713 180 -246 10399 17334 -22557 4738 4258 13077 -835 -734 -6340 8268 -3164 -5580 -1461 -2770 -2206 -1067 -253 -1246 2133 -6850 -742 -2985 13 -1812 -130 -3101 -28 -3331 -2172 -3090 2203 589 -3868 -1662 748 -761 -1031 -278 574 474 625 2255 698 -366 -497 -854 1108 1643 3828 552 1753 1588 3185 3521 623 -930 1254 -137 -515 4526 -1288 -156 -821 1149 -1184 -1336 424 -2820 -95 196 900000 -178 900000 900000 -969 900000 -2933 900000 -2527 -734 900000 -210 1699 -2464 -22740 1140 900000 872 900000 900000 900000 1457 2333 -243 2427 -507 2451 -506 1706 900000 3106 3546 1074 3066 3572 3656 900000 4967 446 737 3702 928 4061 5466 5552 -369 766 4727 4699 5196 4049 1241 6067 3969 2927 5254 -5954 1819 -1282 3221 -3404 2124 -3067 1157 698 4571 1224 5651 553 4261 2320 93 -122 4360 6205 -10707 1727 1667 5397 -450 -446 -4428 5358 -2411 -4621 -1223 -2428 -1936 -905 -201 -935 1475 -5113 -563 -2598 13 -1992 -154 -3846 -32 -3661 -2178 -3064 2192 631 -4521 -2010 947 -1067 -1580 -447 927 745 933 3163 978 -533 -761 -1374 1773 2566 5674 816 2468 2156 4111 4530 884 -1476 2119 -248 -974 8535 -2691 -339 -1842 2571 -2715 -3004 897 -5829 -184 SS 20250511T125552.8Z 9262.538805 218 1 10.51 2 73.14 78.50 119.32 265.17 0.00 1 0.00 1 0 17 2.840e-01 1.288e-02 1.484e-01 5.840e-03 4.919259e-01 3.058410e-03 5.278947e-03 -6.000000e+00 1.668453e-01 230.79 -2.00 3.24 -2.00 319.49 0.00e+00 7.253311e-04 8.596427e-04 1.926463e-04 -6.000000e+00 7.474842e-03 289.81 -2.00 20.00 -2.00 318.70 0.00e+00 3.393 0.000 302.00 328.00 3 3.8540e+00 8.7419e-03 4.1536e-02 -6.0000e+00 4.1641e-01 7.8874e-02 1.0366e-02 2.3929e-02 -6.0000e+00 4.4954e-01 -6.7570e-02 7.9099e-03 1.1729e-02 -6.0000e+00 2.6828e-01 2.7672e-02 4.1208e-03 3.4351e-03 -6.0000e+00 1.1463e-01 2.0285e-04 -2.1161e-04 1.6809e-04 3.7645e-05 -6.0000e+00 7.9480e-03 -1.2731e-02 0.0000e+00 12 9 9 12 1 1 99.96 24.23 0.34 -0.01273 -0.01432 6 7 1 5 0 1500.550 26.73 20.00 24.23 25.41 32.6 1100.00 -147060 200258 -72519 24525 -9206 -49198 146962 -19464 82277 -9537 -43594 46175 -48372 1426 -17865 8474 -5199 10863 13559 4684 15409 -1179 16213 -10020 -4032 3472 -7117 -15397 -13399 -8600 35479 7949 9991 341 -7276 8124 4197 24618 1876 -342 -4490 4512 -491 4753 6215 1069 -1935 -614 5453 1955 4009 -109 1682 3064 4287 2530 4060 -4966 2780 599 1160 911 1283 316 -1659 377 -422 1753 75 3249 965 756 -613 266 558 15 -1374 -1012 795 -474 -1796 -1967 -1557 -641 -1608 -2541 -467 -799 -167 137 -298 373 -215 -11 -549 524 368 288 -555 -139 223 -678 -67 419 -893 82 -210 -430 254 -76 131 76 123 167 566 425 33 -468 -18 -440 -500 1015 328 509 -672 1879 890 609 243 714 143 -383 -70 797 327 -461 138 165 -282 -648 -226 -776 -61 -9344 1140 -2736 364 -172 -1307 837 -479 884 -256 -1650 831 -2458 55 -981 416 -317 614 794 312 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