File name: Pandora66s1_HuntsvilleAL_20230815_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20230816T100946.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20230815_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20230815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230815T132216.4Z 8627.557134 126 1 23.39 2 63.47 90.96 54.19 87.69 0.00 1 0.00 1 0 25 2.381e-02 6.456e-03 6.976e-03 2.213e-03 2.911736e-01 1.135590e-03 3.320875e-03 -6.000000e+00 1.388632e-02 231.16 -2.00 3.38 -2.00 317.25 0.00e+00 3.646740e-04 1.669582e-04 6.183717e-05 -6.000000e+00 6.330288e-04 292.16 -2.00 20.00 -2.00 316.35 0.00e+00 2.226 0.000 302.00 328.00 3 4.6193e+00 3.0177e-03 2.6223e-02 -6.0000e+00 3.4652e-02 3.2712e-02 3.4014e-03 1.4641e-02 -6.0000e+00 3.7504e-02 -3.2558e-03 2.0181e-03 7.0623e-03 -6.0000e+00 2.2413e-02 -5.0153e-03 9.8459e-04 1.9400e-03 -6.0000e+00 9.4719e-03 4.1424e-04 8.6503e-05 6.4898e-05 2.2686e-05 -6.0000e+00 6.7074e-04 1.5611e-02 0.0000e+00 12 9 1 12 1 1 99.98 26.62 0.10 0.01561 0.01626 18 9 1 5 0 1222.040 26.62 19.99 23.46 32.28 39.1 997.00 -11161 16706 -1351 -9721 -6551 4796 -4177 5596 -4198 -2056 2235 -3063 324 1227 -1073 -1465 -1907 -1136 653 1069 764 55 -102 459 3899 -786 -1153 131 -1296 4216 -987 987 1000 -1569 -330 -2221 376 -3055 -1213 -845 -323 271 -115 -238 2004 -543 -777 -799 389 -596 1029 316 2988 698 992 674 706 -1178 317 762 617 1082 1940 992 -239 -90 -78 -436 150 -218 -204 -166 -148 121 -71 -1054 -1096 -248 -515 -606 -653 -912 -1843 -560 -992 -412 166 -300 19 757 392 642 102 1033 536 675 741 645 -61 -197 -294 -847 -252 -894 53 -754 -432 -583 381 -186 284 319 268 -60 -301 329 639 479 53 -704 -341 -167 376 -103 715 50 1072 767 314 155 53 -277 -114 -226 -209 -105 339 76 82 251 -233 -366 -581 -1332 1615 -156 -1113 -663 466 -453 618 -560 -277 289 -449 53 228 -218 -324 -443 -275 161 272 196 14 -28 131 1129 -232 -354 37 -354 1117 -298 317 326 -523 -108 -719 133 -1252 -584 -441 -181 157 -68 -143 1173 -325 -457 -461 220 -350 635 200 1951 491 716 475 505 -849 232 557 451 852 1572 852 -202 -74 -60 -340 121 -199 -193 -161 -142 110 -62 -876 -837 -184 -412 -525 -608 -936 -1944 -615 -1131 -479 201 -374 24 882 438 681 106 1052 566 760 896 830 -82 -257 -372 -1036 -294 -1060 67 -977 -586 -802 550 -278 429 483 402 -87 -417 432 844 666 76 -1044 -510 -245 552 -145 982 66 1394 1024 435 222 77 -417 -175 -352 -345 -176 579 129 138 425 -381 -598 -937 SS 20230815T133004.6Z 8627.562553 132 1 45.71 2 61.86 92.09 52.63 88.75 0.00 1 0.00 1 0 17 7.481e-03 5.033e-03 8.507e-04 3.111e-04 2.734847e-01 1.599491e-04 3.133765e-03 -6.000000e+00 4.362979e-03 231.16 -2.00 3.38 -2.00 316.99 0.00e+00 1.876114e-04 2.190622e-05 5.327917e-05 -6.000000e+00 1.989072e-04 292.16 -2.00 20.00 -2.00 316.07 0.00e+00 2.110 0.000 302.00 328.00 3 1.6288e+00 4.2368e-04 2.4789e-02 -6.0000e+00 1.0887e-02 3.6801e-03 4.7609e-04 1.3754e-02 -6.0000e+00 1.1784e-02 2.4023e-03 2.7847e-04 6.6385e-03 -6.0000e+00 7.0423e-03 -6.7640e-03 1.3340e-04 1.8039e-03 -6.0000e+00 2.9758e-03 9.5960e-03 -4.8095e-05 9.1523e-06 2.1623e-05 -6.0000e+00 2.1076e-04 1.6262e-02 0.0000e+00 10 0 0 10 0 0 99.96 26.62 0.23 0.01626 0.01590 1113 238 1 5 0 40.770 26.62 20.00 23.46 32.37 39.3 998.06 -1355 -396 -2112 -2933 -2338 -289 -308 1344 -217 -440 -998 395 -352 706 -94 -195 -568 618 287 791 -299 922 923 549 361 143 -561 -323 -50 1359 1184 1512 642 -1641 -1500 -1298 -1103 -550 -234 -907 -809 -881 -740 -910 -169 -701 -593 -855 -368 342 728 490 1106 710 807 784 473 218 467 694 1129 1233 1417 743 -253 -95 -121 71 826 391 123 97 -10 78 -64 -30 -259 -173 -75 -447 -857 -1199 -1772 -1053 -880 -558 -240 115 128 451 496 603 156 895 665 380 484 397 -113 -333 -474 -532 -94 -156 -775 -794 -555 -546 14 60 195 -21 163 -23 279 345 435 196 120 -388 -299 -110 94 143 510 259 765 1069 623 234 118 -173 -18 -48 -95 -92 168 129 -188 -133 -144 -342 -409 -177 -55 -295 -376 -272 -33 -38 185 -33 -70 -158 66 -68 154 -22 -49 -148 166 81 228 -88 269 281 177 114 46 -180 -104 -15 415 389 497 229 -594 -511 -452 -430 -252 -119 -499 -478 -542 -466 -577 -106 -441 -364 -516 -218 207 468 317 752 510 595 590 362 166 348 519 879 980 1217 638 -225 -78 -94 55 691 350 119 92 -10 74 -59 -24 -207 -135 -60 -402 -820 -1200 -1892 -1121 -1006 -647 -291 142 158 526 558 650 157 933 708 428 579 500 -149 -427 -595 -647 -110 -191 -985 -1015 -743 -766 20 87 295 -32 236 -33 375 462 561 266 168 -577 -450 -163 135 204 690 350 988 1405 842 339 172 -261 -28 -74 -150 -152 282 214 -313 -223 -233 -559 -657 SS 20230815T133758.7Z 8627.568041 138 1 2.89 2 60.24 93.26 51.05 89.85 0.00 1 0.00 1 0 17 1.067e-02 5.873e-03 7.833e-03 3.518e-03 2.630873e-01 1.816085e-03 3.018097e-03 -6.000000e+00 6.221673e-03 231.16 -2.00 3.38 -2.00 316.46 0.00e+00 2.083924e-04 2.182234e-04 4.427227e-05 -6.000000e+00 2.836424e-04 292.16 -2.00 20.00 -2.00 315.59 0.00e+00 2.006 0.000 302.00 328.00 3 3.5948e+00 4.7622e-03 2.3636e-02 -6.0000e+00 1.5526e-02 2.7948e-02 5.3312e-03 1.3176e-02 -6.0000e+00 1.6804e-02 -2.6097e-03 3.0745e-03 6.3645e-03 -6.0000e+00 1.0042e-02 -4.6987e-03 1.4361e-03 1.7315e-03 -6.0000e+00 4.2435e-03 1.4913e-03 -2.2300e-04 1.0278e-04 2.1436e-05 -6.0000e+00 3.0055e-04 1.6180e-02 0.0000e+00 12 1 1 12 9 1 99.52 26.62 0.25 0.01618 0.01450 4 20 1 5 0 533.360 26.62 19.99 23.46 32.64 39.3 999.45 1105 503 541 -6235 -1257 -4533 531 702 11 -2821 822 -2633 1810 -330 -1043 677 257 259 8 -279 1365 -478 766 337 -164 1124 -1526 93 -1397 2486 -245 2642 185 -109 -2690 -577 -759 1069 -1472 -221 -936 -151 -1415 49 -151 16 -285 -519 -658 -98 245 210 2229 737 1245 960 1102 150 493 460 882 1058 1148 577 141 -349 -122 -444 233 -538 50 -116 -80 -718 612 -34 35 -524 345 -215 -53 -1196 -1792 -1318 -646 -643 171 -109 227 740 233 406 -226 885 253 -138 321 450 -347 -122 -858 -83 -536 -111 -599 -763 -342 167 -351 123 -583 238 358 179 32 450 1027 791 36 -174 -425 -42 -18 -31 914 -46 724 894 889 201 264 -410 -37 -222 209 -93 210 -103 -463 -116 -76 -477 -262 185 90 96 -1080 -188 -704 85 126 2 -589 165 -547 408 -87 -295 203 80 84 3 -98 474 -169 265 123 -63 439 -599 33 -508 884 -91 1025 79 -46 -1102 -237 -332 514 -828 -134 -615 -102 -953 32 -100 10 -193 -343 -430 -65 165 151 1660 562 969 764 887 121 388 364 699 903 1019 519 128 -305 -101 -366 200 -504 49 -116 -79 -707 568 -30 29 -424 286 -194 -52 -1244 -1921 -1434 -750 -772 207 -135 280 890 268 439 -236 902 268 -157 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