File name: Pandora66s1_HuntsvilleAL_20230822_L2Fit_fwvt1c3d20200122p1-8.txt File generation date: 20230823T123641.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20230822_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20230822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 1678 1827 Nominal wavelengths inside fitting window [nm]: 492.1087 492.2293 492.3498 492.4704 492.5910 492.7115 492.8320 492.9525 493.0730 493.1935 493.3139 493.4344 493.5548 493.6752 493.7956 493.9159 494.0363 494.1566 494.2770 494.3973 494.5175 494.6378 494.7581 494.8783 494.9985 495.1187 495.2389 495.3591 495.4792 495.5994 495.7195 495.8396 495.9597 496.0797 496.1998 496.3198 496.4398 496.5598 496.6798 496.7998 496.9197 497.0397 497.1596 497.2795 497.3994 497.5192 497.6391 497.7589 497.8787 497.9985 498.1183 498.2381 498.3578 498.4776 498.5973 498.7170 498.8367 498.9563 499.0760 499.1956 499.3152 499.4348 499.5544 499.6740 499.7935 499.9130 500.0325 500.1520 500.2715 500.3910 500.5104 500.6298 500.7493 500.8686 500.9880 501.1074 501.2267 501.3460 501.4654 501.5846 501.7039 501.8232 501.9424 502.0616 502.1808 502.3000 502.4192 502.5383 502.6575 502.7766 502.8957 503.0148 503.1339 503.2529 503.3719 503.4910 503.6100 503.7289 503.8479 503.9668 504.0858 504.2047 504.3236 504.4425 504.5613 504.6802 504.7990 504.9178 505.0366 505.1554 505.2741 505.3929 505.5116 505.6303 505.7490 505.8677 505.9863 506.1049 506.2236 506.3422 506.4608 506.5793 506.6979 506.8164 506.9349 507.0534 507.1719 507.2904 507.4088 507.5272 507.6456 507.7640 507.8824 508.0008 508.1191 508.2374 508.3557 508.4740 508.5923 508.7105 508.8288 508.9470 509.0652 509.1834 509.3015 509.4197 509.5378 509.6559 509.7740 509.8921 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230822T112557.0Z 8634.476354 41 1 22.54 2 88.09 76.99 152.20 49.39 0.00 1 0.00 1 0 22 1.537e-02 1.522e-02 1.535e-03 1.529e-03 1.994425e+04 1.128692e+02 1.220436e+03 -6.000000e+00 8.751341e+02 291.80 -2.00 20.00 -2.00 505.43 0.00e+00 3.822146e-03 4.333142e-05 2.457467e-04 -6.000000e+00 4.387040e-04 291.80 -2.00 20.00 -2.00 501.08 0.00e+00 4.559027e-01 2.938166e-02 1.333903e-01 -6.000000e+00 3.032758e-01 230.74 -2.00 3.38 -2.00 502.56 0.00e+00 16.178 0.065 489.00 513.00 1 5.6845e+00 2.2521e-03 2.7424e-02 -6.0000e+00 2.3289e-02 -5.6379e-02 5.6833e-04 3.3572e-03 -6.0000e+00 6.0834e-03 6.2424e-04 -1.4622e-03 1.3399e-04 1.4323e-04 -6.0000e+00 1.5253e-03 1.8088e-01 -9.5250e-04 12 9 9 12 1 1 35.69 26.73 11.81 0.18088 0.17074 7 4 1 4 0 2794.000 26.73 20.00 23.64 32.43 40.8 999.39 -2811 -1430 -103 1226 2514 2928 3305 2646 2103 1496 1199 -310 -1058 -1543 -1178 -1226 -120 246 807 1023 910 1082 795 806 1511 976 785 -583 -1927 -2523 -2422 -2051 -955 172 861 232 594 -374 -620 -417 207 477 1013 1288 1604 1695 1366 1010 -38 -1655 -2932 -2872 -2571 -1549 -712 385 938 1575 1206 1191 1328 1230 1697 1483 755 237 -276 -1120 -1704 -1979 -1957 -1583 -936 -900 -859 -507 -1724 -1813 -2487 -2906 -1745 -2047 -1469 -1517 -1006 -1312 -1504 -1250 -743 -528 305 724 1569 1433 1485 1172 114 -1315 -2599 -3187 -3056 -2623 -1283 -424 59 -190 -377 -369 -710 -475 -784 307 1273 2134 2397 3025 3441 2714 1869 1372 900 339 807 1435 1849 2053 1688 1360 966 741 106 -436 -744 -1228 -1238 -1331 -322 495 843 903 576 816 885 800 1210 358 -244 -1547 -2519 -2354 -2481 -1283 -95 1117 2317 2747 3134 2534 2009 1420 1129 -292 -991 -1443 -1103 -1164 -112 234 778 992 887 1057 783 775 1454 946 758 -561 -1881 -2423 -2324 -1988 -914 169 858 233 590 -372 -614 -412 205 479 998 1285 1611 1706 1371 1006 -37 -1618 -2917 -2816 -2518 -1532 -700 386 956 1608 1238 1225 1332 1246 1719 1503 764 238 -275 -1112 -1732 -1996 -1974 -1559 -927 -901 -864 -504 -1706 -1819 -2485 -2904 -1732 -1998 -1439 -1505 -1008 -1328 -1523 -1254 -738 -524 304 727 1568 1413 1461 1115 106 -1237 -2430 -2974 -2880 -2468 -1251 -420 59 -193 -384 -373 -720 -487 -819 312 1291 2215 2428 3078 3551 2863 1992 1451 938 348 818 1491 1878 2097 1744 1413 1008 774 110 -450 -764 -1267 -1287 -1374 -337 524 904 984 623 889 969 879 1322 391 -265 -1672 -2722 -2545 SQ 20230822T113026.2Z 8634.479470 46 1 47.84 2 87.19 77.62 151.54 51.08 0.00 1 0.00 1 0 29 9.554e-03 9.420e-03 3.899e-04 3.886e-04 2.285445e+04 2.941429e+01 1.447852e+03 -6.000000e+00 5.444923e+02 291.80 -2.00 20.00 -2.00 505.42 0.00e+00 2.817967e-03 1.103527e-05 1.825616e-04 -6.000000e+00 2.730500e-04 291.80 -2.00 20.00 -2.00 500.98 0.00e+00 6.452751e-01 7.504429e-03 1.295899e-01 -6.000000e+00 1.890429e-01 230.74 -2.00 3.38 -2.00 502.49 0.00e+00 13.912 0.041 489.00 513.00 1 4.2193e+00 5.7553e-04 2.3499e-02 -6.0000e+00 1.4512e-02 -7.3063e-02 1.4481e-04 3.4092e-03 -6.0000e+00 3.7984e-03 3.6821e-03 2.1751e-03 3.2819e-05 1.5397e-04 -6.0000e+00 9.4986e-04 3.9078e-03 -2.3604e-06 12 9 9 12 1 1 -3.19 26.73 6.76 0.00391 0.01900 89 20 1 4 0 529.570 26.73 20.00 23.63 32.97 40.1 999.91 -1499 -734 247 825 1546 1993 2096 1802 1588 1037 696 -50 -569 -687 -739 -617 -62 262 546 454 622 442 592 684 873 839 581 -229 -1163 -1559 -1541 -1390 -672 60 184 77 58 -262 -634 -637 -226 5 518 872 890 980 877 490 -237 -1015 -1642 -1835 -1833 -1245 -577 -16 466 659 704 724 813 977 993 774 576 316 -11 -500 -1044 -1284 -1312 -977 -796 -573 -470 -690 -862 -1212 -1420 -1482 -1140 -1044 -977 -843 -682 -875 -855 -759 -355 -85 343 644 1010 866 938 881 143 -719 -1538 -2197 -2045 -1676 -1055 -449 -193 -300 -330 -356 -278 -226 -224 123 581 1082 1425 1910 2010 1569 1053 624 333 170 517 958 1103 1286 1070 834 668 403 -210 -378 -452 -867 -855 -466 -136 376 768 822 569 536 591 662 741 416 -239 -888 -1356 -1446 -1338 -668 226 758 1448 1901 1983 1719 1509 979 668 -48 -538 -645 -697 -589 -59 254 527 442 609 434 583 679 871 821 579 -227 -1128 -1483 -1462 -1333 -658 59 186 78 59 -262 -631 -633 -226 5 517 880 908 1001 892 494 -237 -1016 -1611 -1776 -1773 -1220 -567 -16 467 666 712 733 826 999 1021 797 588 320 -11 -497 -1053 -1286 -1313 -983 -792 -575 -474 -691 -851 -1207 -1399 -1454 -1119 -1033 -955 -833 -684 -887 -865 -762 -352 -85 341 647 1014 855 914 843 132 -667 -1411 -2014 -1894 -1565 -1010 -443 -195 -303 -333 -358 -278 -229 -230 127 600 1115 1468 1941 2081 1628 1101 647 346 173 531 981 1137 1307 1098 861 689 416 -216 -385 -458 -882 -877 -485 -142 398 809 880 620 579 644 722 805 449 -257 -964 -1467 -1540 SQ 20230822T113320.9Z 8634.481492 48 1 48.87 2 86.60 78.03 151.10 52.15 0.00 1 0.00 1 0 29 7.494e-03 7.393e-03 2.624e-04 2.617e-04 2.250085e+04 1.979684e+01 1.419665e+03 -6.000000e+00 4.270831e+02 291.80 -2.00 20.00 -2.00 505.41 0.00e+00 2.360345e-03 7.420533e-06 1.610502e-04 -6.000000e+00 2.141577e-04 291.80 -2.00 20.00 -2.00 500.93 0.00e+00 6.767172e-01 5.062478e-03 1.272685e-01 -6.000000e+00 1.482274e-01 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