File name: Pandora66s1_HuntsvilleAL_20230901_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20230903T064403.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20230901_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20230901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230901T125300.8Z 8644.536814 252 1 13.10 2 71.71 92.59 89.43 266.12 0.00 1 0.00 1 0 17 2.348e-01 1.223e-02 9.450e-02 5.154e-03 3.841082e-01 2.631049e-03 4.310354e-03 -6.000000e+00 1.362448e-01 230.12 -2.00 3.38 -2.00 318.66 0.00e+00 1.711736e-03 5.786885e-04 1.232726e-04 -6.000000e+00 6.214893e-03 291.24 -2.00 20.00 -2.00 317.77 0.00e+00 3.145 0.000 302.00 328.00 3 4.5048e+00 7.2537e-03 3.6211e-02 -6.0000e+00 3.3924e-01 3.1201e-02 8.3557e-03 1.9449e-02 -6.0000e+00 3.6768e-01 -5.6726e-03 5.6135e-03 9.3866e-03 -6.0000e+00 2.1979e-01 -5.2925e-03 2.9165e-03 3.0560e-03 -6.0000e+00 9.2858e-02 1.7186e-04 -7.4530e-05 1.5165e-04 3.1206e-05 -6.0000e+00 6.6154e-03 2.5014e-02 0.0000e+00 12 9 9 12 1 1 98.99 26.21 0.02 0.02501 0.02445 4 4 1 5 0 2618.350 26.21 19.99 22.85 33.23 39.3 997.69 -14108 246253 -25468 9267 -45141 52541 -28894 19147 -8738 -33698 59011 -11851 289 -11297 -6597 -10685 -70 -7703 14294 -3920 25201 -14739 2787 -6674 20642 -4324 9384 -6302 982 -5432 551 369 3683 -2742 5008 -11050 1050 -7912 3241 -1965 340 1260 2217 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1822 -126 827 -161 1485 -944 -837 55 1430 2691 -1162 -832 -1052 534 309 607 237 516 315 1917 168 152 -132 399 215 505 -604 321 136 63 -464 -95 -387 -312 -1130 SS 20230901T130121.0Z 8644.542604 258 1 24.16 2 70.00 93.81 91.06 267.30 0.00 1 0.00 1 0 17 1.117e-02 4.787e-03 3.790e-03 7.179e-04 3.607166e-01 3.668107e-04 4.080899e-03 -6.000000e+00 6.481437e-03 230.12 -2.00 3.38 -2.00 318.16 0.00e+00 3.551497e-04 6.893473e-05 1.115888e-04 -6.000000e+00 2.956185e-04 291.24 -2.00 20.00 -2.00 317.25 0.00e+00 2.892 0.000 302.00 328.00 3 1.8277e+00 9.9410e-04 3.3498e-02 -6.0000e+00 1.6138e-02 -9.5702e-03 1.1330e-03 1.8112e-02 -6.0000e+00 1.7489e-02 -1.6982e-04 7.2098e-04 8.7429e-03 -6.0000e+00 1.0455e-02 -5.8164e-03 3.6882e-04 2.3986e-03 -6.0000e+00 4.4185e-03 3.3508e-03 -2.4392e-05 2.1099e-05 2.7090e-05 -6.0000e+00 3.1457e-04 2.3033e-02 0.0000e+00 12 1 1 12 1 1 99.94 26.21 0.24 0.02303 0.02285 209 92 1 5 0 115.010 26.21 20.00 22.85 33.52 39.3 999.36 -3435 829 -2606 -5879 -4067 -4329 -754 -151 -1079 -3352 1514 -1137 556 -362 2229 -335 -78 392 1489 193 693 -582 1291 -386 1136 -626 -538 -1074 -424 887 953 1145 582 -1709 -2060 -1545 -1310 -913 -857 -819 -953 -645 -961 -636 -110 -484 -760 -900 -596 219 326 653 978 991 776 854 114 94 281 678 967 1491 1626 975 -147 15 -59 211 787 420 316 109 165 56 0 -320 -375 -415 -329 -641 -771 -1118 -1599 -980 -588 -447 -80 94 255 398 582 576 415 796 568 441 453 431 -136 -396 -644 -656 -163 -360 -884 -829 -616 -474 7 130 134 169 186 147 311 411 344 241 16 -488 -385 -51 22 178 435 264 739 1074 519 252 11 -205 -95 -64 -248 -119 151 170 -191 -96 -50 -243 -279 -199 50 -163 -349 -219 -239 -44 -10 -79 -263 115 -98 55 -39 273 -46 -12 61 240 33 118 -101 233 -76 232 -125 -114 -215 -82 177 210 257 143 -429 -492 -381 -365 -302 -316 -348 -409 -289 -446 -296 -51 -226 -353 -416 -276 105 169 365 545 585 476 537 74 60 176 424 634 999 1192 762 -114 11 -41 150 610 349 269 95 142 48 0 -242 -263 -291 -253 -532 -686 -1103 -1603 -1033 -633 -512 -96 109 294 456 644 588 420 813 601 499 551 554 -183 -518 -824 -773 -193 -426 -1135 -1070 -836 -650 10 195 205 261 288 213 434 573 486 343 23 -755 -599 -77 32 262 605 367 990 1484 750 378 18 -326 -155 -106 -437 -211 273 314 -353 -171 -89 -417 -473 SS 20230901T130700.0Z 8644.546528 261 1 49.50 2 68.84 94.65 92.17 268.10 0.00 1 0.00 1 0 17 9.956e-03 5.080e-03 1.334e-03 3.157e-04 3.423114e-01 1.610029e-04 3.892328e-03 -6.000000e+00 5.778729e-03 230.12 -2.00 3.38 -2.00 317.82 0.00e+00 2.851485e-04 2.755159e-05 8.612911e-05 -6.000000e+00 2.635718e-04 291.24 -2.00 20.00 -2.00 316.92 0.00e+00 2.744 0.000 302.00 328.00 3 1.1116e+00 4.3270e-04 3.1786e-02 -6.0000e+00 1.4388e-02 -1.1012e-02 4.9054e-04 1.7190e-02 -6.0000e+00 1.5593e-02 -2.8916e-03 3.0216e-04 8.3017e-03 -6.0000e+00 9.3216e-03 -3.9602e-03 1.5237e-04 2.2736e-03 -6.0000e+00 3.9393e-03 8.0975e-03 -6.3314e-05 9.2534e-06 2.6169e-05 -6.0000e+00 2.8048e-04 2.3286e-02 0.0000e+00 10 0 0 10 0 0 93.84 26.21 0.22 0.02329 0.02281 848 181 1 5 0 58.290 26.21 20.00 22.84 33.91 39.6 1002.39 -3007 172 -3950 -3572 -4672 -726 -2763 426 -1873 -1204 -1983 -703 -1170 249 72 59 -389 644 375 780 134 723 998 365 681 83 -628 -654 252 1040 1527 1488 691 -1623 -1741 -1606 -1039 -844 -275 -1166 -939 -783 -711 -872 -124 -630 -570 -848 -434 284 607 485 1011 658 814 822 425 224 393 595 1014 1416 1554 888 -119 58 -36 227 827 491 147 116 55 82 -170 31 -297 -104 -204 -494 -842 -1209 -1783 -1032 -834 -586 -211 130 202 447 653 695 640 826 679 370 473 312 -173 -409 -566 -653 -64 -310 -864 -917 -586 -554 11 12 141 5 130 6 353 442 493 218 91 -422 -352 -141 68 127 507 287 897 1080 624 276 161 -111 -13 -23 -135 -124 148 102 -267 -140 -165 -309 -327 -228 14 -327 -270 -329 -50 -214 36 -179 -119 -200 -70 -137 34 11 10 -71 123 69 149 26 141 204 80 157 20 -149 -146 54 229 368 395 201 -480 -490 -467 -315 -304 -110 -544 -471 -385 -359 -444 -63 -321 -287 -424 -217 146 337 291 604 417 533 552 291 152 262 398 709 1015 1215 699 -92 44 -26 168 637 428 132 107 50 71 -142 25 -219 -76 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