File name: Pandora66s1_HuntsvilleAL_20230917_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20240224T060053.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20230917_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20230917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230917T122022.5Z 8660.514149 58 1 44.60 2 80.68 93.76 108.06 87.97 0.00 1 0.00 1 0 25 5.523e-01 2.008e-02 1.579e-01 4.932e-03 7.031165e-01 2.708449e-03 7.716052e-03 -6.000000e+00 3.241801e-01 229.09 -2.00 3.38 -2.00 321.26 0.00e+00 4.489991e-03 1.393613e-03 1.816988e-03 -6.000000e+00 1.634215e-02 290.25 -2.00 20.00 -2.00 320.60 0.00e+00 5.868 0.003 302.00 328.00 3 2.5595e+00 9.7173e-03 6.7456e-02 -6.0000e+00 8.0588e-01 2.2066e-01 1.3288e-02 3.6599e-02 -6.0000e+00 8.7613e-01 -2.9904e-01 1.2273e-02 1.9435e-02 -6.0000e+00 5.1944e-01 1.2123e-01 5.7682e-03 6.7411e-03 -6.0000e+00 2.2018e-01 6.6407e-05 -9.6097e-04 1.3902e-04 9.3864e-05 -6.0000e+00 1.5914e-02 2.5825e-02 0.0000e+00 12 9 9 12 1 1 99.89 26.11 0.18 0.02582 0.01860 37 9 1 5 0 1173.470 26.11 20.00 22.81 28.58 38.7 974.34 -267501 900000 -113615 -158825 -186300 900000 -182590 900000 -170133 -174750 900000 -179490 900000 -80831 -27652 -82926 -29089 -12247 175374 5766 900000 -94558 80896 -34668 900000 -37540 7883 16486 -30670 23756 -39947 32867 39921 45690 133146 -18174 69035 -29443 17459 5331 11154 51635 43250 52267 113187 34303 -1497 17904 17926 6646 8984 13057 59334 24912 14209 16988 7066 -1945 9274 7356 -2197 2181 10834 11558 2470 4687 4199 1074 -4781 -3556 -2709 3724 -1273 1881 7571 -2299 4227 -3476 -2601 -1328 3697 -1078 -3772 1503 -1425 -1507 1316 -3047 -320 1479 1996 1427 -4311 -692 -2058 2515 -1406 632 117 -1314 -653 -3028 -261 -4116 852 -1671 -973 -1800 769 -846 206 944 1147 -802 -1357 282 810 2524 -1125 -435 -144 -131 1871 988 1540 389 550 959 1695 116 -191 449 751 -762 -755 -221 328 117 -48 917 -589 -379 -1371 -9069 900000 -1091 -2098 -3020 900000 -3179 900000 -3217 -3672 900000 -5172 900000 -1456 -390 -2240 -515 -216 842 94 900000 -4002 673 -926 900000 -1138 162 301 -865 479 -1739 873 1125 1244 1450 -873 1680 -2157 975 394 857 2821 2687 3028 3878 2492 -151 1558 1656 753 1119 1737 5448 3498 2336 2817 1316 -390 1614 1305 -455 458 2391 2813 676 1233 1126 315 -1676 -1405 -1088 1516 -529 704 2418 -735 1222 -1147 -987 -593 1735 -602 -2349 944 -989 -1054 933 -2303 -233 1060 1325 903 -2852 -472 -1544 2103 -1355 679 135 -1500 -688 -3092 -241 -4071 861 -1737 -1071 -2165 1000 -1201 319 1456 1760 -1208 -2043 406 1186 3824 -1787 -703 -228 -207 2815 1442 2149 532 739 1379 2747 205 -356 889 1564 -1647 -1747 -509 769 279 -114 2113 -1293 -785 -2930 SS 20230917T122851.9Z 8660.520045 63 1 15.95 2 78.94 95.00 106.39 89.18 0.00 1 0.00 1 0 25 3.602e-01 1.025e-02 1.276e-01 3.012e-03 6.244159e-01 1.591596e-03 6.887277e-03 -6.000000e+00 2.093192e-01 229.09 -2.00 3.38 -2.00 320.61 0.00e+00 3.261214e-03 6.711153e-04 1.231882e-03 -6.000000e+00 9.642900e-03 290.25 -2.00 20.00 -2.00 319.89 0.00e+00 5.026 0.002 302.00 328.00 3 1.7496e+00 5.1081e-03 5.8199e-02 -6.0000e+00 5.2117e-01 3.8577e-02 6.6173e-03 3.1847e-02 -6.0000e+00 5.6590e-01 -5.0911e-02 6.0353e-03 1.6498e-02 -6.0000e+00 3.3691e-01 1.3325e-02 2.9819e-03 5.5566e-03 -6.0000e+00 1.4271e-01 3.6209e-04 -5.0134e-04 8.4480e-05 6.9618e-05 -6.0000e+00 1.0260e-02 2.3961e-02 0.0000e+00 12 9 9 12 1 1 97.69 26.11 0.27 0.02396 0.02019 40 27 1 5 0 388.830 26.11 20.00 22.82 29.17 38.9 976.49 -189180 900000 -139651 -21710 -173242 93166 -162736 900000 -163814 -53136 -82787 -20432 -75241 -27882 -57588 -19717 -43059 6302 -4199 5724 -1958 -25278 -5795 -12596 22241 -20390 708 -13253 -3822 -15774 -4171 -6655 5679 -6215 11879 -11763 11786 -16519 4097 -9064 8648 2724 9478 -93 17214 2556 3571 -196 4845 -1016 4859 -640 11198 4733 4851 744 869 -1932 -1012 1974 1183 2424 3263 3032 65 1368 1046 1239 -946 394 -794 2432 -833 1188 -751 718 -2522 41 -1630 735 -829 -74 -3035 -190 -1220 -221 -876 -168 327 1041 932 1155 902 593 -28 654 377 -61 -41 -754 -499 -1203 -1713 -1330 -751 -1445 -532 -1461 285 -96 655 -15 669 -208 370 118 774 201 400 -594 146 -11 484 239 837 270 803 876 534 323 -131 -298 113 -77 -390 -406 138 304 -269 364 -354 21 -590 -3837 900000 -2050 -93 -3190 274 -3127 900000 -4066 -468 -1061 -169 -1386 -409 -1414 -389 -1207 119 -95 124 -47 -776 -158 -400 534 -789 22 -467 -125 -665 -188 -362 311 -360 606 -728 720 -1483 367 -1089 963 344 1173 -13 2064 365 518 -31 762 -185 934 -133 2268 1108 1195 199 236 -535 -271 516 331 750 1139 1168 24 532 410 474 -417 195 -432 1314 -453 593 -347 297 -1031 17 -791 411 -510 -51 -2330 -151 -985 -188 -781 -152 292 877 780 908 695 483 -24 653 410 -76 -50 -915 -594 -1307 -1863 -1402 -845 -1725 -669 -1885 398 -141 1047 -23 1099 -329 551 170 1133 312 656 -961 243 -18 750 357 1258 394 1144 1327 865 554 -234 -565 225 -156 -841 -875 303 676 -594 798 -739 41 -1207 SS 20230917T123811.5Z 8660.526522 69 1 49.43 2 77.04 96.37 104.55 90.51 0.00 1 0.00 1 0 25 1.396e-01 5.061e-03 2.379e-02 9.235e-04 5.478096e-01 4.774845e-04 6.036897e-03 -6.000000e+00 8.071709e-02 229.09 -2.00 3.38 -2.00 320.01 0.00e+00 1.284269e-03 1.645892e-04 2.640757e-04 -6.000000e+00 3.680189e-03 290.25 -2.00 20.00 -2.00 319.23 0.00e+00 4.340 0.001 302.00 328.00 3 1.3430e+00 1.4308e-03 5.0409e-02 -6.0000e+00 2.0054e-01 1.4722e-03 1.7605e-03 2.7651e-02 -6.0000e+00 2.1755e-01 2.1174e-03 1.4932e-03 1.3594e-02 -6.0000e+00 1.3008e-01 -1.0444e-02 7.6641e-04 4.1911e-03 -6.0000e+00 5.5032e-02 1.1190e-03 -2.5491e-04 2.6315e-05 4.5399e-05 -6.0000e+00 3.9321e-03 2.3836e-02 0.0000e+00 10 0 0 10 0 0 99.93 26.21 0.25 0.02384 0.02192 301 64 1 5 0 164.170 26.21 20.00 22.82 29.41 39.0 977.64 -71115 20464 -43376 -48771 -72171 -30062 -64566 -18014 -41860 -36234 -28137 -28092 -18452 -14712 -13193 -13736 -12331 -5866 -3640 -2361 271 -8787 -4733 -3793 3634 -8919 -4825 -4357 -4442 -2828 -3051 -927 2305 -1828 -2070 -5316 75 -3221 -181 -1982 -359 -85 175 241 2724 523 151 -73 538 722 1018 1059 3058 1150 1049 787 226 -635 419 659 767 1345 2036 1559 181 569 151 576 456 160 -243 150 -278 141 -43 -222 -823 -507 -480 -467 -731 -1100 -1784 -835 -802 -566 -68 312 469 833 862 927 275 728 507 427 530 447 66 -324 -665 -707 -471 -795 -889 -940 -483 -576 149 10 275 33 357 64 397 381 405 322 -111 -468 -332 -180 116 124 345 168 671 807 506 168 55 -248 -112 -135 -293 -172 161 175 -191 67 -73 -89 -178 -1012 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