File name: Pandora66s1_HuntsvilleAL_20231110_L2Fit_fout2c3d20200122p1-8.txt File generation date: 20231128T194833.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Michael Newchurch Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 66 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora66_OF_v5d20200114.txt Instrument calibration file used: Pandora66s1_CF_v3d20200122.txt Level 1 file used: Pandora66s1_HuntsvilleAL_20231110_L1_smca1c3d20200122p1-8.txt Full location name: The University of Alabama in Huntsville- SWIRLL Short location name: HuntsvilleAL Country of location: United States Location latitude [deg]: 34.7252 Location longitude [deg]: -86.6464 Location altitude [m]: 221 Local noon date: 20231110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 1, fieldcal refday 20200921 First and last pixel inside fitting window: 253 395 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2425 305.3831 305.5238 305.6644 305.8050 305.9456 306.0862 306.2268 306.3673 306.5079 306.6484 306.7890 306.9295 307.0700 307.2105 307.3510 307.4914 307.6319 307.7723 307.9128 308.0532 308.1936 308.3340 308.4744 308.6148 308.7551 308.8955 309.0358 309.1762 309.3165 309.4568 309.5971 309.7374 309.8777 310.0179 310.1582 310.2984 310.4386 310.5789 310.7191 310.8593 310.9994 311.1396 311.2798 311.4199 311.5600 311.7002 311.8403 311.9804 312.1205 312.2605 312.4006 312.5407 312.6807 312.8207 312.9607 313.1007 313.2407 313.3807 313.5207 313.6606 313.8006 313.9405 314.0805 314.2204 314.3603 314.5002 314.6400 314.7799 314.9197 315.0596 315.1994 315.3392 315.4790 315.6188 315.7586 315.8984 316.0381 316.1779 316.3176 316.4573 316.5970 316.7367 316.8764 317.0161 317.1558 317.2954 317.4351 317.5747 317.7143 317.8539 317.9935 318.1331 318.2727 318.4122 318.5518 318.6913 318.8308 318.9703 319.1098 319.2493 319.3888 319.5282 319.6677 319.8071 319.9465 320.0860 320.2254 320.3647 320.5041 320.6435 320.7828 320.9222 321.0615 321.2008 321.3401 321.4794 321.6187 321.7580 321.8972 322.0365 322.1757 322.3149 322.4542 322.5934 322.7325 322.8717 323.0109 323.1500 323.2892 323.4283 323.5674 323.7065 323.8456 323.9847 324.1238 324.2628 324.4019 324.5409 324.6799 324.8189 324.9579 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231110T163755.1Z 8714.692998 246 1 33.94 2 53.41 164.30 44.15 204.83 0.00 1 0.00 1 0 17 8.539e-03 5.852e-03 2.306e-03 1.326e-03 1.909618e-01 6.714842e-04 2.260536e-03 -6.000000e+00 4.865469e-03 224.76 -2.00 3.38 -2.00 315.70 0.00e+00 2.561029e-04 6.812656e-05 2.401790e-05 -6.000000e+00 2.198393e-04 284.54 -2.00 20.00 -2.00 315.02 0.00e+00 1.673 0.000 302.00 328.00 3 4.7486e+00 1.7233e-03 1.8739e-02 -6.0000e+00 1.1991e-02 3.0290e-02 1.9302e-03 9.3905e-03 -6.0000e+00 1.3054e-02 6.0258e-03 1.1075e-03 4.6254e-03 -6.0000e+00 7.8056e-03 -7.4519e-03 5.0294e-04 1.3130e-03 -6.0000e+00 3.3199e-03 7.4049e-04 -1.8697e-04 3.8727e-05 1.7644e-05 -6.0000e+00 2.4008e-04 1.1983e-02 0.0000e+00 12 1 1 12 1 1 100.00 26.32 0.30 0.01198 0.01058 59 19 1 5 0 565.550 26.32 20.00 22.97 22.92 37.8 980.29 -2482 1669 -2512 -3233 -2570 814 -586 2239 202 -937 1241 -138 -518 1052 -97 15 -1082 678 528 1070 324 662 289 530 1205 157 -845 165 -246 1814 942 1313 822 -1262 -1139 -1070 -865 -717 -402 -1342 -861 -855 -488 -523 294 -522 -701 -1038 -333 192 723 259 1885 1008 895 693 406 -105 424 443 1107 1172 1596 798 -535 -486 -168 28 471 -93 -164 227 101 122 190 -16 -244 -300 -248 -169 -580 -1003 -1918 -1038 -874 -666 -46 -115 -115 594 482 483 162 1086 454 509 452 650 82 -371 -541 -597 -674 -414 -534 -928 -572 -699 225 -136 470 155 345 -91 5 131 439 391 52 -245 -168 -117 205 128 627 239 735 1094 870 350 157 -135 45 -272 -83 -203 189 196 -145 9 -182 -384 -763 -630 428 -661 -774 -587 178 -140 577 54 -259 329 -39 -162 363 -35 6 -434 275 221 457 140 283 128 245 575 73 -411 74 -103 739 406 597 398 -616 -519 -494 -443 -405 -255 -928 -633 -650 -377 -405 224 -397 -518 -744 -243 140 526 200 1504 806 731 576 341 -88 348 365 943 1072 1489 779 -510 -442 -142 23 419 -90 -169 232 102 123 177 -14 -205 -242 -211 -153 -559 -1058 -2063 -1163 -1007 -817 -57 -145 -144 735 548 521 168 1089 484 570 537 809 106 -469 -669 -686 -779 -481 -672 -1184 -760 -934 312 -193 685 225 494 -125 7 163 546 511 70 -340 -238 -164 280 173 799 303 885 1326 1117 458 214 -189 62 -386 -126 -308 293 312 -224 14 -275 -566 -1151 SS 20231110T164647.9Z 8714.699166 252 1 48.29 2 52.96 166.88 44.98 207.69 0.00 1 0.00 1 0 17 8.260e-02 2.705e-02 1.496e-02 6.407e-03 1.901357e-01 3.206805e-03 2.240877e-03 -6.000000e+00 4.705778e-02 224.76 -2.00 3.38 -2.00 316.58 0.00e+00 4.354239e-04 3.953201e-04 8.828939e-05 -6.000000e+00 2.126615e-03 284.54 -2.00 20.00 -2.00 315.83 0.00e+00 1.656 0.000 302.00 328.00 3 7.5196e+00 8.3223e-03 1.8584e-02 -6.0000e+00 1.1597e-01 3.3754e-02 9.3701e-03 9.4030e-03 -6.0000e+00 1.2627e-01 1.6960e-02 5.4553e-03 4.6200e-03 -6.0000e+00 7.5499e-02 -7.5899e-03 2.5661e-03 1.3678e-03 -6.0000e+00 3.2104e-02 4.6735e-05 -3.9016e-05 1.8992e-04 1.6990e-05 -6.0000e+00 2.3227e-03 1.3392e-02 0.0000e+00 12 9 8 11 32 0 99.99 26.32 -1.03 0.01339 0.01310 18 4 1 5 0 2682.040 26.32 20.00 22.97 23.24 37.7 980.17 -22979 68820 -12688 1811 -11174 19092 -2738 23171 -9670 -15863 23194 -6346 14 -3274 -485 -507 -6458 -930 10937 2935 5022 -7184 -1255 -2891 19618 -1042 -4083 4790 -4311 4629 -5479 7248 4525 3566 6884 -7285 4208 -6648 -3017 -3964 -2357 4111 2674 3931 10939 1699 -648 -769 209 -2653 -1938 -1223 14555 1236 2264 2278 852 -7023 703 346 -1281 -1883 5079 808 -2967 -1741 286 -1968 -2714 -4590 -4825 2741 -69 -37 3789 -126 -2697 -3348 -1985 -133 1550 228 -4101 1872 -1790 -2306 1747 -1300 1415 3170 1463 2508 -2392 1240 -913 4915 -698 2287 853 -1533 -1537 -3737 -2100 -4619 3478 278 327 -1750 2359 -544 1296 1651 2506 -2548 -3243 -64 2284 4328 -770 -1270 83 -1496 1107 94 -735 -600 -498 511 2963 -642 -1445 946 2010 -1665 -1351 605 799 572 1507 1627 -1187 -329 -3073 -5105 7229 -2789 311 -1967 2463 -473 3432 -2161 -3842 3725 -1430 3 -894 -143 -150 -2080 -292 3324 937 1574 -2531 -430 -1054 6273 -396 -1558 1637 -1510 1480 -2034 2509 1706 1338 2335 -2894 1660 -3226 -1676 -2528 -1578 2667 1798 2612 6739 1136 -430 -494 130 -1705 -1303 -863 9195 931 1721 1757 673 -5625 542 269 -1056 -1589 4287 739 -2708 -1431 226 -1572 -2356 -4311 -4897 2662 -68 -35 3361 -104 -2081 -2499 -1545 -113 1443 222 -4403 1990 -2120 -2783 2123 -1673 1762 3880 1673 2580 -2369 1221 -921 5133 -852 2964 1102 -2067 -1942 -4485 -2392 -5673 4263 369 455 -2461 3332 -833 2023 2552 3647 -3596 -4441 -81 2813 5480 -1104 -1848 122 -2200 1628 134 -992 -769 -609 624 3739 -886 -2095 1367 2916 -2471 -2116 973 1316 965 2525 2652 -1927 -514 -4854 SS 20231110T172537.6Z 8714.726129 273 1 3.52 2 51.95 178.52 49.44 219.12 0.00 1 0.00 1 0 17 7.066e-03 5.544e-03 1.760e-03 1.198e-03 1.866008e-01 6.115814e-04 2.218420e-03 -6.000000e+00 4.026059e-03 224.76 -2.00 3.38 -2.00 315.01 0.00e+00 2.400773e-04 5.396019e-05 2.336703e-05 -6.000000e+00 1.819191e-04 284.54 -2.00 20.00 -2.00 314.39 0.00e+00 1.619 0.000 302.00 328.00 3 2.5204e+00 1.5568e-03 1.8172e-02 -6.0000e+00 9.9222e-03 1.7719e-02 1.7367e-03 9.1640e-03 -6.0000e+00 1.0802e-02 1.1292e-03 9.9603e-04 4.5184e-03 -6.0000e+00 6.4591e-03 -3.4219e-03 4.4058e-04 1.2848e-03 -6.0000e+00 2.7470e-03 7.3469e-03 -2.9252e-04 3.4788e-05 1.7933e-05 -6.0000e+00 1.9868e-04 1.2342e-02 0.0000e+00 12 1 1 12 1 1 84.09 26.32 0.23 0.01234 0.01014 22 69 1 5 0 152.660 26.32 20.00 23.00 24.08 37.4 983.62 -1513 -271 -1826 -2220 -1409 -818 -2 1343 440 -1079 -391 -97 439 30 562 -669 146 603 603 975 927 610 1252 555 936 -58 137 -388 432 875 1334 1380 893 -1329 -1254 -1319 -691 -550 -366 -973 -835 -840 -591 -844 -204 -724 -681 -744 -352 320 345 527 1024 981 581 1090 384 -28 337 603 839 1298 1188 952 -488 -84 -352 207 687 431 200 21 -96 78 -29 -59 -170 -73 -114 -742 -917 -1304 -1694 -1347 -854 -511 -200 -173 181 75 419 296 395 714 697 358 587 476 138 -367 -282 -629 29 -7 -521 -888 -516 -644 -56 77 197 53 259 -61 274 351 78 125 159 -164 -224 -23 117 151 704 461 779 980 715 352 75 -137 -39 77 -226 -77 -33 106 -233 -81 -207 -485 -455 -494 -92 -619 -731 -414 -236 -1 453 152 -386 -136 -35 174 13 260 -313 69 293 301 498 475 312 655 289 504 -32 74 -207 213 427 678 742 483 -725 -676 -721 -394 -347 -259 -719 -658 -684 -469 -671 -168 -591 -539 -569 -273 248 269 433 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