File name: Pandora282s1_Ilo-UNAM_20250123_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250327T112213.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250123_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1762 305.3168 305.4574 305.5979 305.7385 305.8790 306.0196 306.1601 306.3006 306.4411 306.5816 306.7221 306.8625 307.0030 307.1435 307.2839 307.4243 307.5647 307.7051 307.8455 307.9859 308.1263 308.2666 308.4070 308.5473 308.6876 308.8279 308.9682 309.1085 309.2488 309.3891 309.5293 309.6696 309.8098 309.9500 310.0902 310.2304 310.3706 310.5108 310.6510 310.7911 310.9313 311.0714 311.2115 311.3516 311.4917 311.6318 311.7719 311.9120 312.0520 312.1921 312.3321 312.4721 312.6121 312.7521 312.8921 313.0321 313.1721 313.3120 313.4520 313.5919 313.7318 313.8717 314.0116 314.1515 314.2914 314.4312 314.5711 314.7109 314.8508 314.9906 315.1304 315.2702 315.4100 315.5497 315.6895 315.8293 315.9690 316.1087 316.2484 316.3881 316.5278 316.6675 316.8072 316.9469 317.0865 317.2261 317.3658 317.5054 317.6450 317.7846 317.9242 318.0637 318.2033 318.3428 318.4824 318.6219 318.7614 318.9009 319.0404 319.1799 319.3193 319.4588 319.5982 319.7377 319.8771 320.0165 320.1559 320.2953 320.4347 320.5740 320.7134 320.8527 320.9921 321.1314 321.2707 321.4100 321.5493 321.6885 321.8278 321.9671 322.1063 322.2455 322.3847 322.5239 322.6631 322.8023 322.9415 323.0806 323.2198 323.3589 323.4980 323.6372 323.7763 323.9153 324.0544 324.1935 324.3325 324.4716 324.6106 324.7496 324.8887 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250123T121451.3Z 9154.510316 1431 1 30.40 2 66.50 103.91 8.28 235.26 0.00 1 0.00 1 0 17 1.729e-02 7.723e-03 1.036e-02 3.060e-03 2.853546e-01 1.503296e-03 2.966964e-03 -6.000000e+00 9.592864e-03 225.48 -2.00 3.04 -2.00 317.38 0.00e+00 1.828186e-03 2.318612e-04 1.367034e-04 -6.000000e+00 4.447938e-04 293.42 -2.00 20.00 -2.00 316.47 0.00e+00 2.489 0.000 302.00 328.00 3 4.8655e+00 3.9660e-03 2.7432e-02 -6.0000e+00 2.3644e-02 3.0819e-02 4.4903e-03 1.2751e-02 -6.0000e+00 2.5642e-02 1.4626e-03 2.7292e-03 6.2585e-03 -6.0000e+00 1.5395e-02 -6.3488e-03 1.3961e-03 2.1761e-03 -6.0000e+00 6.7476e-03 2.4915e-04 -3.9812e-05 8.2110e-05 1.9364e-05 -6.0000e+00 4.3166e-04 1.3071e-02 0.0000e+00 11 9 0 11 8 0 90.83 25.50 0.57 0.01307 0.01277 12 12 1 5 0 2532.500 33.50 20.00 25.50 33.18 3.7 1042.40 -3518 5277 -3089 -438 -8383 2826 -4206 -2137 -203 -583 -2812 -4426 -591 -1478 5575 -3247 -81 1398 1745 -503 2664 3204 2777 1206 -192 2300 91 936 193 -573 1077 1363 -831 -2689 -5705 -2688 -3161 -1303 -2162 -734 1147 -1978 -1511 -194 -650 -466 -251 119 13 -91 1841 -207 1324 797 449 1456 582 958 472 839 163 548 753 2797 988 -586 -115 -1538 358 1608 950 540 602 1420 466 240 -2065 -2893 -836 -1028 -1533 -1696 -1656 -1386 -592 -249 579 311 598 896 1032 -1175 -534 -408 -263 -313 -521 564 836 294 -66 -944 -1011 -226 -324 -387 -1006 -634 -83 -198 638 727 850 433 -280 -492 -346 260 30 575 -223 486 503 178 928 -143 -299 355 590 289 -39 -256 -229 -467 -414 214 76 241 296 221 -82 -586 -537 -355 543 -360 -47 -851 241 -405 -227 -24 -73 -352 -571 -84 -248 1015 -661 -17 298 388 -119 628 738 649 303 -52 631 26 249 48 -141 279 387 -265 -925 -1879 -814 -1039 -488 -906 -360 610 -1138 -828 -107 -359 -259 -149 69 7 -52 1082 -124 832 533 312 1021 422 692 335 585 117 420 588 2322 856 -479 -86 -1203 287 1354 836 503 564 1276 425 197 -1673 -2211 -642 -832 -1419 -1635 -1726 -1500 -634 -287 702 371 717 1110 1188 -1261 -553 -399 -268 -355 -618 698 1122 399 -85 -1187 -1171 -261 -410 -493 -1345 -886 -114 -293 999 1113 1269 643 -407 -663 -456 352 43 847 -343 736 743 254 1321 -197 -389 475 791 422 -58 -392 -355 -750 -667 365 134 410 513 378 -142 -982 -865 SU 20250123T121832.6Z 9154.512877 1437 1 28.36 2 65.65 103.72 9.01 238.06 0.00 1 0.00 1 0 17 3.373e-02 9.645e-03 1.480e-02 4.294e-03 2.771224e-01 2.112437e-03 2.911607e-03 -6.000000e+00 1.871159e-02 225.48 -2.00 3.04 -2.00 317.47 0.00e+00 2.010524e-03 3.324781e-04 5.612422e-05 -6.000000e+00 8.677061e-04 293.42 -2.00 20.00 -2.00 316.57 0.00e+00 2.408 0.000 302.00 328.00 3 5.4325e+00 5.5869e-03 2.6610e-02 -6.0000e+00 4.6120e-02 5.0023e-02 6.3216e-03 1.2574e-02 -6.0000e+00 5.0018e-02 -4.1767e-03 3.8353e-03 6.1299e-03 -6.0000e+00 3.0030e-02 -3.0156e-03 1.9679e-03 2.3203e-03 -6.0000e+00 1.3160e-02 1.5320e-04 -1.3996e-04 1.1614e-04 2.1041e-05 -6.0000e+00 8.4213e-04 1.4169e-02 0.0000e+00 12 8 8 10 0 0 99.50 25.50 0.74 0.01417 0.01312 8 8 1 5 0 3543.780 33.50 19.99 25.50 33.13 3.7 1041.73 1814 18798 -227 1610 -17369 -1347 -13258 -6492 5075 -3583 7406 -9822 -4426 2491 3608 -3275 1292 300 2432 -2675 3404 4802 4877 1143 4921 -1093 -1095 4018 1067 -6542 5396 838 3047 -636 -8661 -2117 -5119 -1670 -4538 -904 53 -1020 -1902 1281 958 -240 -2276 -1383 273 -200 2763 -1297 679 83 211 858 1099 477 -779 1143 779 268 1261 3643 741 -129 132 -1255 -1026 807 1337 1182 671 484 1656 226 -150 -1490 -903 -739 -1404 -1415 -1301 -2384 -1119 -211 54 461 954 433 1634 -733 -194 -903 -169 -180 -297 1222 863 287 164 -1195 -2015 -1215 -256 -572 -1389 -330 -76 -510 652 841 875 -128 -276 -373 -376 -324 -245 9 -142 484 660 544 388 289 -811 952 879 181 147 233 148 103 550 -52 -95 666 18 -240 -220 -979 -649 172 1669 -25 167 -1891 -117 -1366 -701 548 -447 809 -1287 -627 385 641 -699 276 67 560 -673 828 1130 1156 297 1298 -290 -293 1062 269 -1745 1367 243 949 -197 -2704 -645 -1577 -576 -1945 -443 29 -530 -1032 684 512 -131 -1250 -802 153 -112 1582 -767 418 54 143 587 766 335 -540 767 537 200 1017 2872 615 -100 101 -937 -796 650 1193 1110 637 446 1414 191 -114 -1068 -658 -609 -1222 -1370 -1360 -2433 -1200 -242 66 579 1204 535 1856 -777 -200 -887 -172 -203 -346 1571 1130 379 204 -1480 -2317 -1394 -319 -762 -1817 -448 -107 -777 983 1307 1324 -196 -387 -519 -511 -426 -345 13 -223 748 993 792 536 409 -1093 1229 1209 254 219 360 232 166 878 -89 -167 1190 31 -432 -382 -1645 -1047 SU 20250123T122323.3Z 9154.516241 1446 1 15.93 2 64.53 103.48 10.00 241.07 0.00 1 0.00 1 0 17 1.927e-02 8.261e-03 1.062e-02 4.006e-03 2.657639e-01 1.978194e-03 2.790234e-03 -6.000000e+00 1.069493e-02 225.48 -2.00 3.04 -2.00 316.87 0.00e+00 1.508822e-03 2.682236e-04 6.539013e-05 -6.000000e+00 4.957091e-04 293.42 -2.00 20.00 -2.00 315.99 0.00e+00 2.310 0.000 302.00 328.00 3 4.8010e+00 5.1652e-03 2.5496e-02 -6.0000e+00 2.6361e-02 3.0768e-02 5.8160e-03 1.1915e-02 -6.0000e+00 2.8582e-02 -5.6562e-05 3.4394e-03 5.8151e-03 -6.0000e+00 1.7160e-02 -4.4654e-03 1.7103e-03 1.9701e-03 -6.0000e+00 7.5271e-03 3.2546e-04 3.6102e-04 1.0704e-04 1.8413e-05 -6.0000e+00 4.8088e-04 8.7977e-03 0.0000e+00 12 9 1 12 1 1 98.63 25.51 0.37 0.00880 0.01151 4 9 1 5 0 3185.740 33.50 20.00 25.51 33.10 3.7 1042.01 -2120 6869 668 -9184 -7680 -2523 -3549 -1952 -342 2669 -4299 -5849 -2033 -2172 3589 -1813 2973 2752 2362 1383 1761 -661 1534 1406 -457 3412 539 1588 1582 -2408 677 436 4348 -1614 -4718 -3209 -2387 -2547 -2688 -625 -38 -889 -1236 1 370 -1274 -343 -549 -615 -50 2172 567 13 755 870 741 774 482 -149 303 127 -106 637 2765 1004 274 -974 -1467 772 680 1074 1091 123 859 1373 780 -1604 -2645 -1046 -1812 -1003 -736 -1716 -1723 -283 -798 -127 915 950 720 1007 -379 -105 -655 -239 27 -97 1095 479 191 -512 -1131 -1977 -406 20 -1401 -502 -504 -352 257 741 381 362 383 382 -377 -361 -528 365 -237 -203 408 649 647 765 27 56 272 263 257 279 -195 408 46 110 -19 145 263 40 -450 -111 -840 -321 -288 947 101 -1324 -1044 -306 -456 -278 -54 433 -731 -1015 -350 -435 785 -469 767 738 665 408 532 -201 459 446 -156 1167 176 527 485 -749 217 153 1472 -613 -1716 -1185 -865 -1071 -1263 -341 -23 -522 -754 1 225 -792 -208 -350 -385 -31 1380 368 9 547 652 565 564 353 -115 229 98 -82 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