File name: Pandora282s1_Ilo-UNAM_20250225_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250327T112240.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250225_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1762 305.3168 305.4574 305.5979 305.7385 305.8790 306.0196 306.1601 306.3006 306.4411 306.5816 306.7221 306.8625 307.0030 307.1435 307.2839 307.4243 307.5647 307.7051 307.8455 307.9859 308.1263 308.2666 308.4070 308.5473 308.6876 308.8279 308.9682 309.1085 309.2488 309.3891 309.5293 309.6696 309.8098 309.9500 310.0902 310.2304 310.3706 310.5108 310.6510 310.7911 310.9313 311.0714 311.2115 311.3516 311.4917 311.6318 311.7719 311.9120 312.0520 312.1921 312.3321 312.4721 312.6121 312.7521 312.8921 313.0321 313.1721 313.3120 313.4520 313.5919 313.7318 313.8717 314.0116 314.1515 314.2914 314.4312 314.5711 314.7109 314.8508 314.9906 315.1304 315.2702 315.4100 315.5497 315.6895 315.8293 315.9690 316.1087 316.2484 316.3881 316.5278 316.6675 316.8072 316.9469 317.0865 317.2261 317.3658 317.5054 317.6450 317.7846 317.9242 318.0637 318.2033 318.3428 318.4824 318.6219 318.7614 318.9009 319.0404 319.1799 319.3193 319.4588 319.5982 319.7377 319.8771 320.0165 320.1559 320.2953 320.4347 320.5740 320.7134 320.8527 320.9921 321.1314 321.2707 321.4100 321.5493 321.6885 321.8278 321.9671 322.1063 322.2455 322.3847 322.5239 322.6631 322.8023 322.9415 323.0806 323.2198 323.3589 323.4980 323.6372 323.7763 323.9153 324.0544 324.1935 324.3325 324.4716 324.6106 324.7496 324.8887 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250225T111026.6Z 9187.465585 132 1 29.51 2 84.47 97.61 51.99 106.48 0.00 1 0.00 1 0 25 5.328e-01 4.231e-02 4.001e-01 2.586e-02 7.854848e-01 1.466887e-02 7.965950e-03 -6.000000e+00 3.017340e-01 225.88 -2.00 3.04 -2.00 321.86 0.00e+00 -6.327246e-03 7.772577e-03 7.406908e-03 -6.000000e+00 1.505216e-02 293.52 -2.00 20.00 -2.00 321.29 0.00e+00 9.081 0.002 302.00 328.00 3 1.0811e+00 5.6886e-02 1.0646e-01 -6.0000e+00 7.4919e-01 1.1432e+00 7.2438e-02 7.4143e-02 -6.0000e+00 8.1616e-01 -1.4572e+00 4.9718e-02 2.1263e-02 -6.0000e+00 4.8325e-01 6.0136e-01 2.4612e-02 1.1042e-02 -6.0000e+00 2.1288e-01 1.1400e-05 -1.9057e-03 7.1212e-04 6.7408e-05 -6.0000e+00 1.4112e-02 1.4877e-02 0.0000e+00 12 8 8 10 0 0 14.48 25.36 1.35 0.01488 0.00056 10 10 1 5 0 2950.540 33.50 20.00 25.36 30.10 3.6 1021.49 -65887 900000 -25772 -33890 54096 16131 -84543 900000 900000 -7490 253308 -92020 900000 26873 900000 38315 36326 76194 68291 900000 -23054 900000 900000 128500 135244 96862 49456 900000 900000 46921 900000 118586 900000 74287 32991 48575 316047 -14263 -34954 66051 900000 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-3539 -426 -1733 2488 -5417 7169 -511 -202 -1242 189 2095 7094 -17652 -916 -3356 3838 794 -2718 -5211 -4213 743 -4720 -190 -1164 -6530 3556 3127 -3850 -1978 -2268 -7847 7100 -904 -919 153 -1634 -2429 2689 -3613 52 4275 3735 9681 6293 808 2 1750 -2994 2990 963 2082 -7140 -822 2657 1934 3112 -5613 5963 3838 -621 -6097 -850 -2855 -526 SS 20250225T112029.6Z 9187.472564 135 1 29.94 2 82.10 96.88 49.75 106.26 0.00 1 0.00 1 0 17 3.872e-01 1.026e-02 1.844e-01 4.820e-03 6.390920e-01 2.543840e-03 6.993714e-03 -6.000000e+00 2.167554e-01 225.88 -2.00 3.04 -2.00 320.99 0.00e+00 8.824075e-03 1.213724e-03 3.847219e-03 -6.000000e+00 1.012882e-02 293.52 -2.00 20.00 -2.00 320.30 0.00e+00 6.779 0.001 302.00 328.00 3 1.1799e+00 8.7132e-03 7.3293e-02 -6.0000e+00 5.3536e-01 1.5293e-01 1.1866e-02 3.3538e-02 -6.0000e+00 5.8102e-01 -1.9439e-01 1.1434e-02 2.1427e-02 -6.0000e+00 3.4752e-01 7.2612e-02 5.5897e-03 9.1856e-03 -6.0000e+00 1.5391e-01 1.1858e-04 -2.4166e-04 1.2714e-04 1.1919e-04 -6.0000e+00 9.9870e-03 1.5294e-02 0.0000e+00 12 8 8 10 0 0 24.14 25.37 0.54 0.01529 0.01348 36 36 1 5 0 831.380 33.50 20.00 25.37 30.98 3.6 1027.73 900000 900000 22655 -167704 -162397 -122737 -133103 900000 -27474 -164808 -157473 -109995 -113815 -112856 900000 -58645 -47674 13862 26787 -14342 -29492 -31435 900000 -4154 -14528 28680 -33239 23321 25420 -22877 -37337 -26441 -31547 -18926 -14270 13453 -7886 10271 -19733 -15276 -2271 1939 7868 511 7125 -834 3663 -13361 14398 2854 -68 4527 3861 -1960 4841 2543 5279 6953 4574 2061 4505 4709 5789 5080 2188 1835 4057 -616 -654 3075 2365 2741 493 2487 2823 698 -2082 -3965 -1794 -2523 -963 -1696 -597 -814 -1105 -700 540 418 1684 771 -115 -3060 -1255 -151 -1750 -315 214 673 521 129 -412 -1206 -2093 -1032 -1589 -1596 -271 -627 392 -635 826 237 533 368 189 -192 -755 209 -529 454 -28 301 1351 699 1113 180 -266 345 489 158 190 -373 -534 -65 -210 26 272 375 318 -170 -23 -513 -632 900000 900000 106 -2363 -1941 -943 -1313 900000 -129 -2941 -2662 -1291 -1817 -2385 900000 -1157 -963 169 315 -269 -665 -709 900000 -78 -321 431 -952 372 394 -623 -1438 -1118 -1659 -969 -663 455 -359 458 -1455 -1299 -192 169 691 50 673 -89 384 -1726 1481 350 -9 687 647 -380 932 518 1081 1401 917 417 918 1059 1482 1506 723 595 1252 -203 -213 1129 982 1195 220 1032 1074 267 -752 -1456 -714 -1106 -492 -1009 -391 -565 -753 -511 412 332 1334 601 -85 -2157 -900 -108 -1295 -269 212 709 616 156 -476 -1270 -2156 -1033 -1604 -1723 -304 -756 510 -872 1256 365 829 559 291 -281 -1107 318 -865 727 -46 469 2154 1090 1662 263 -374 485 772 267 357 -710 -1067 -136 -448 59 633 889 765 -401 -51 -1075 -1341 SS 20250225T113534.8Z 9187.483042 140 1 30.03 2 78.52 95.80 46.39 105.99 0.00 1 0.00 1 0 17 1.123e-01 6.758e-03 2.242e-02 1.495e-03 4.929697e-01 7.458015e-04 5.067387e-03 -6.000000e+00 6.240511e-02 225.88 -2.00 3.04 -2.00 319.42 0.00e+00 3.864334e-03 2.105026e-04 9.092134e-04 -6.000000e+00 2.891080e-03 293.52 -2.00 20.00 -2.00 318.55 0.00e+00 4.856 0.000 302.00 328.00 3 1.0880e+00 2.1242e-03 5.2304e-02 -6.0000e+00 1.5395e-01 2.0626e-02 2.5336e-03 2.2232e-02 -6.0000e+00 1.6691e-01 -3.8120e-02 1.9851e-03 1.1811e-02 -6.0000e+00 1.0019e-01 9.6840e-03 1.0584e-03 4.7946e-03 -6.0000e+00 4.3867e-02 9.2225e-04 7.4190e-05 3.9034e-05 4.5563e-05 -6.0000e+00 2.8048e-03 1.4641e-02 0.0000e+00 11 9 0 11 8 0 8.41 25.39 0.47 0.01464 0.01520 109 109 1 5 0 275.480 33.50 20.01 25.39 32.34 3.6 1035.20 -27408 -8557 -24032 -31838 -45336 -49169 -40177 -31504 -40472 -40098 -27686 -33882 -38212 -20998 -922 -7998 -9435 -6050 -5643 -1792 50 -4620 -3481 -6641 -1688 -60 -6690 -3348 -4404 -6060 -6342 -808 -721 -1046 -3630 -5723 -3319 -1140 584 2237 508 646 1858 312 1795 1690 1334 -617 1020 242 339 1106 1409 1521 1665 803 1294 700 305 -17 835 693 1774 2824 1171 735 -466 -922 396 979 775 1074 655 486 187 -627 -632 -2844 -1755 -1546 -1373 -832 -1763 -1591 -1070 -254 174 482 952 1053 581 106 -573 -490 -446 -119 24 1009 391 15 -639 -1058 -964 -506 -848 -1008 -884 -423 -211 192 733 590 463 319 12 -169 -194 37 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293.52 -2.00 20.00 -2.00 313.02 0.00e+00 1.013 0.000 302.00 328.00 3 3.1405e-01 1.4739e-04 1.1282e-02 -6.0000e+00 1.0742e-02 -1.3120e-03 1.6269e-04 5.5487e-03 -6.0000e+00 1.1645e-02 5.1964e-04 9.4359e-05 2.6148e-03 -6.0000e+00 6.9899e-03 -3.7738e-03 4.1635e-05 9.9123e-04 -6.0000e+00 3.0620e-03 1.3558e-01 4.8001e-06 3.0070e-06 1.0077e-05 -6.0000e+00 1.9561e-04 1.1846e-02 0.0000e+00 11 8 0 10 0 0 93.58 26.23 0.41 0.01185 0.01188 1913 1913 1 5 0 15.680 34.25 20.00 26.23 40.27 3.5 1085.33 189 -98 169 -1650 -2293 -1730 -33 991 1339 328 -1035 -790 -305 69 672 379 185 558 650 1359 743 442 923 864 394 409 43 -123 -569 169 1072 1072 1749 -218 -2162 -2362 -2137 -1294 -546 -287 -728 -798 -626 -841 -350 -436 -618 -561 -864 -442 363 498 705 942 667 847 687 494 386 265 657 1007 1274 1782 671 -176 -421 -868 333 464 528 655 420 700 427 16 -307 -1154 -722 -934 -1126 -1061 -1890 -1621 -1086 -628 -251 65 592 501 430 298 2 5 -7 -14 190 919 551 138 -86 -512 -709 -312 -640 -885 -691 -737 -269 233 472 446 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