File name: Pandora282s1_Ilo-UNAM_20250302_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250327T112228.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250302_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250302 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1762 305.3168 305.4574 305.5979 305.7385 305.8790 306.0196 306.1601 306.3006 306.4411 306.5816 306.7221 306.8625 307.0030 307.1435 307.2839 307.4243 307.5647 307.7051 307.8455 307.9859 308.1263 308.2666 308.4070 308.5473 308.6876 308.8279 308.9682 309.1085 309.2488 309.3891 309.5293 309.6696 309.8098 309.9500 310.0902 310.2304 310.3706 310.5108 310.6510 310.7911 310.9313 311.0714 311.2115 311.3516 311.4917 311.6318 311.7719 311.9120 312.0520 312.1921 312.3321 312.4721 312.6121 312.7521 312.8921 313.0321 313.1721 313.3120 313.4520 313.5919 313.7318 313.8717 314.0116 314.1515 314.2914 314.4312 314.5711 314.7109 314.8508 314.9906 315.1304 315.2702 315.4100 315.5497 315.6895 315.8293 315.9690 316.1087 316.2484 316.3881 316.5278 316.6675 316.8072 316.9469 317.0865 317.2261 317.3658 317.5054 317.6450 317.7846 317.9242 318.0637 318.2033 318.3428 318.4824 318.6219 318.7614 318.9009 319.0404 319.1799 319.3193 319.4588 319.5982 319.7377 319.8771 320.0165 320.1559 320.2953 320.4347 320.5740 320.7134 320.8527 320.9921 321.1314 321.2707 321.4100 321.5493 321.6885 321.8278 321.9671 322.1063 322.2455 322.3847 322.5239 322.6631 322.8023 322.9415 323.0806 323.2198 323.3589 323.4980 323.6372 323.7763 323.9153 324.0544 324.1935 324.3325 324.4716 324.6106 324.7496 324.8887 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250302T120953.5Z 9192.506869 83 1 29.55 2 70.67 91.38 105.35 86.05 0.00 1 0.00 1 0 17 2.208e-02 7.682e-03 1.762e-02 3.523e-03 3.202548e-01 1.734036e-03 3.301434e-03 -6.000000e+00 1.227106e-02 225.98 -2.00 3.04 -2.00 318.08 0.00e+00 4.681507e-03 3.219788e-04 2.346431e-04 -6.000000e+00 5.682287e-04 293.51 -2.00 20.00 -2.00 317.16 0.00e+00 2.986 0.000 302.00 328.00 3 4.5433e+00 4.6556e-03 3.2504e-02 -6.0000e+00 3.0279e-02 3.3643e-02 5.3210e-03 1.4808e-02 -6.0000e+00 3.2827e-02 -8.2604e-03 3.3939e-03 7.4594e-03 -6.0000e+00 1.9702e-02 -4.1271e-03 1.7831e-03 4.2035e-03 -6.0000e+00 8.6243e-03 2.0281e-04 1.2681e-05 9.4805e-05 3.3159e-05 -6.0000e+00 5.5133e-04 1.4663e-02 0.0000e+00 11 8 0 10 0 0 59.23 25.48 0.34 0.01466 0.01476 11 11 1 5 0 2685.410 33.75 20.00 25.48 31.76 3.6 1030.67 2234 -4142 -3484 5553 -10833 383 -2335 -3962 1952 -3568 1131 -9437 629 -4155 3099 1787 -1951 1296 1836 -1886 1130 -655 2811 -5059 -2749 -1268 -4004 5661 -4116 -643 3121 3364 3768 -2569 -727 -6388 -1068 -3434 -1842 -1864 2592 -2616 264 1516 -736 -395 -717 -221 -770 -791 3078 1020 1035 -1205 738 620 1095 1768 1712 1034 127 1426 202 2993 876 -466 451 -922 -400 -100 728 1088 1109 971 737 -1369 815 -2172 -1789 -1391 -665 -1205 -1452 -1752 -1717 -72 488 168 603 491 410 -1019 -517 -581 84 -679 -346 700 755 658 -482 -124 -1807 -1061 252 -186 -713 -450 168 -15 537 556 610 55 -666 -552 393 -14 509 305 -10 263 779 592 635 494 -617 72 327 179 -234 -339 -256 -70 5 -107 80 486 293 4 -85 -548 -635 133 -296 -260 361 -726 22 -141 -271 140 -286 85 -807 57 -475 392 261 -316 214 319 -354 212 -123 512 -1048 -583 -275 -904 1106 -837 -126 648 777 876 -676 -175 -1544 -265 -1011 -644 -772 1135 -1163 119 691 -345 -187 -340 -103 -358 -369 1467 540 584 -737 460 393 706 1132 1072 645 82 911 145 2273 700 -353 312 -625 -283 -81 605 947 970 821 630 -1073 562 -1576 -1238 -1097 -595 -1125 -1473 -1858 -1810 -80 576 194 700 594 462 -1064 -526 -563 85 -724 -413 871 1025 899 -628 -156 -2133 -1248 321 -238 -956 -634 234 -23 813 872 937 85 -949 -775 537 -20 727 471 -17 414 1189 875 890 706 -842 95 465 263 -368 -555 -403 -115 9 -186 144 887 546 7 -150 -981 -1097 SS 20250302T121915.8Z 9192.513378 89 1 30.27 2 68.44 90.69 103.22 85.36 0.00 1 0.00 1 0 17 1.448e-02 6.553e-03 6.691e-03 2.087e-03 2.915352e-01 1.030428e-03 3.024536e-03 -6.000000e+00 8.046307e-03 225.98 -2.00 3.04 -2.00 317.31 0.00e+00 2.651889e-03 1.549929e-04 7.821212e-05 -6.000000e+00 3.725831e-04 293.51 -2.00 20.00 -2.00 316.41 0.00e+00 2.696 0.000 302.00 328.00 3 3.9980e+00 2.7133e-03 2.9385e-02 -6.0000e+00 1.9854e-02 8.1665e-03 3.0676e-03 1.3258e-02 -6.0000e+00 2.1525e-02 -2.4564e-03 1.8485e-03 6.4288e-03 -6.0000e+00 1.2919e-02 -2.2737e-03 9.3616e-04 2.6781e-03 -6.0000e+00 5.6553e-03 4.8865e-04 9.8374e-05 5.5888e-05 2.2933e-05 -6.0000e+00 3.6150e-04 1.4394e-02 0.0000e+00 11 8 0 10 0 0 99.10 25.49 0.34 0.01439 0.01513 23 23 1 5 0 1315.690 33.50 20.00 25.49 31.96 3.6 1032.65 -4298 2072 -1715 -2971 -4663 -3677 -2794 3011 -2842 -3514 -4224 -3885 -1186 -1776 3224 -1311 -426 362 2425 1331 1817 49 2253 1043 2321 1207 596 653 -1985 -1131 -611 1502 2431 -912 -3420 -4140 -2221 -1153 -288 201 -987 -889 -613 -442 -363 -192 -765 -636 -547 -1049 346 698 608 1093 1111 843 740 412 339 598 460 1363 1548 2150 652 -81 -346 -1077 171 535 622 1012 534 872 383 -140 -943 -1968 -958 -1077 -1716 -985 -1601 -1689 -1249 -201 -102 603 973 724 559 -156 -479 -421 -385 -384 390 847 500 78 19 -731 -894 -666 -555 -869 -882 -422 180 161 550 499 452 430 -403 -410 188 -226 387 206 -75 94 744 306 399 595 -153 411 95 85 -67 -124 -19 -56 -61 -54 9 398 349 -226 -195 -708 -300 -460 232 -208 -346 -482 -355 -281 320 -360 -474 -562 -524 -179 -290 586 -281 -95 84 581 335 469 13 573 284 658 361 181 188 -547 -305 -177 469 761 -312 -1115 -1292 -736 -439 -121 100 -510 -481 -344 -252 -207 -111 -439 -357 -303 -583 201 438 405 717 756 585 527 295 237 412 325 1030 1204 1806 570 -66 -278 -841 138 463 563 960 513 807 334 -117 -762 -1506 -747 -898 -1542 -980 -1638 -1801 -1340 -230 -117 719 1168 850 644 -174 -489 -432 -391 -434 463 1065 655 102 25 -880 -1046 -783 -679 -1139 -1149 -575 256 234 818 767 680 635 -576 -544 256 -305 555 304 -115 142 1096 438 566 807 -208 540 128 124 -100 -192 -30 -87 -100 -90 15 700 601 -402 -332 -1166 -496 SS 20250302T122929.5Z 9192.520480 92 1 23.55 2 66.01 89.91 100.90 84.61 0.00 1 0.00 1 0 17 1.105e-02 6.476e-03 1.881e-03 8.888e-04 2.660296e-01 4.406104e-04 2.791226e-03 -6.000000e+00 6.141217e-03 225.98 -2.00 3.04 -2.00 316.39 0.00e+00 2.803844e-03 5.306862e-05 1.036549e-04 -6.000000e+00 2.843646e-04 293.51 -2.00 20.00 -2.00 315.52 0.00e+00 2.441 0.000 302.00 328.00 3 2.4499e+00 1.1417e-03 2.6682e-02 -6.0000e+00 1.5154e-02 -7.1700e-03 1.2808e-03 1.2399e-02 -6.0000e+00 1.6429e-02 -4.3248e-03 7.4340e-04 5.8444e-03 -6.0000e+00 9.8600e-03 -7.4425e-04 3.5787e-04 2.6805e-03 -6.0000e+00 4.3164e-03 3.0692e-03 6.1259e-05 2.3625e-05 2.2671e-05 -6.0000e+00 2.7590e-04 1.4294e-02 0.0000e+00 12 9 1 12 1 1 98.16 25.51 0.40 0.01429 0.01475 71 92 1 5 0 327.060 33.75 20.00 25.51 32.62 3.6 1036.47 -1412 -197 -328 -2546 -4670 -3396 -2480 -697 -588 -1503 -3369 -2964 -1613 -676 1096 682 164 1196 1319 1970 1093 730 1272 914 950 1120 314 330 -1374 -346 780 1186 2001 -339 -2440 -2722 -2561 -1739 -317 47 -604 -433 170 -296 324 -223 -375 -479 -884 -267 440 845 973 779 642 909 756 578 160 244 657 1070 1303 2017 592 -143 -682 -1048 138 636 524 679 386 566 306 -305 -679 -1707 -982 -942 -1244 -1230 -1947 -1797 -1127 -552 -207 139 836 653 716 183 132 -139 -88 62 143 892 566 -46 -240 -676 -814 -452 -640 -887 -748 -709 -174 409 566 486 369 187 -94 -139 -36 -54 164 378 -59 67 444 382 565 479 26 716 325 361 168 -78 -87 -83 -79 21 -21 328 160 -142 -247 -641 -660 -256 -39 -68 -508 -829 -559 -423 -131 -123 -309 -746 -660 -374 -182 313 220 52 390 450 693 399 262 457 347 355 434 124 123 -517 -127 302 469 862 -149 -1074 -1140 -1158 -850 -165 27 -372 -278 113 -201 219 -152 -254 -317 -577 -173 297 587 715 580 495 710 579 444 126 190 500 875 1118 1791 545 -123 -560 -864 112 569 503 659 379 537 283 -265 -576 -1367 -801 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