File name: Pandora282s1_Ilo-UNAM_20250410_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250415T185120.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250410_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250410 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1762 305.3168 305.4574 305.5979 305.7385 305.8790 306.0196 306.1601 306.3006 306.4411 306.5816 306.7221 306.8625 307.0030 307.1435 307.2839 307.4243 307.5647 307.7051 307.8455 307.9859 308.1263 308.2666 308.4070 308.5473 308.6876 308.8279 308.9682 309.1085 309.2488 309.3891 309.5293 309.6696 309.8098 309.9500 310.0902 310.2304 310.3706 310.5108 310.6510 310.7911 310.9313 311.0714 311.2115 311.3516 311.4917 311.6318 311.7719 311.9120 312.0520 312.1921 312.3321 312.4721 312.6121 312.7521 312.8921 313.0321 313.1721 313.3120 313.4520 313.5919 313.7318 313.8717 314.0116 314.1515 314.2914 314.4312 314.5711 314.7109 314.8508 314.9906 315.1304 315.2702 315.4100 315.5497 315.6895 315.8293 315.9690 316.1087 316.2484 316.3881 316.5278 316.6675 316.8072 316.9469 317.0865 317.2261 317.3658 317.5054 317.6450 317.7846 317.9242 318.0637 318.2033 318.3428 318.4824 318.6219 318.7614 318.9009 319.0404 319.1799 319.3193 319.4588 319.5982 319.7377 319.8771 320.0165 320.1559 320.2953 320.4347 320.5740 320.7134 320.8527 320.9921 321.1314 321.2707 321.4100 321.5493 321.6885 321.8278 321.9671 322.1063 322.2455 322.3847 322.5239 322.6631 322.8023 322.9415 323.0806 323.2198 323.3589 323.4980 323.6372 323.7763 323.9153 324.0544 324.1935 324.3325 324.4716 324.6106 324.7496 324.8887 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250410T112722.1Z 9231.477340 205 1 29.87 2 82.88 79.08 125.48 261.26 0.00 1 0.00 1 0 17 4.580e-01 1.610e-02 2.838e-01 7.386e-03 6.692696e-01 3.936510e-03 7.476210e-03 -6.000000e+00 2.567413e-01 226.60 -2.00 3.04 -2.00 321.34 0.00e+00 9.670865e-03 2.097034e-03 5.446903e-03 -6.000000e+00 1.232034e-02 292.98 -2.00 20.00 -2.00 320.69 0.00e+00 7.407 0.001 302.00 328.00 3 1.1529e+00 1.4512e-02 8.1412e-02 -6.0000e+00 6.3529e-01 2.7889e-01 2.0217e-02 4.0919e-02 -6.0000e+00 6.8911e-01 -3.3405e-01 1.9206e-02 2.3796e-02 -6.0000e+00 4.1215e-01 1.2627e-01 9.1126e-03 8.6818e-03 -6.0000e+00 1.8103e-01 6.3843e-05 -2.2773e-04 1.9452e-04 1.4716e-04 -6.0000e+00 1.1982e-02 1.6282e-02 0.0000e+00 12 8 8 10 0 0 -18.56 25.07 0.64 0.01628 0.01457 25 25 1 5 0 1194.510 33.50 20.00 25.07 27.60 3.7 1002.99 -257540 900000 -149200 900000 -238560 -151066 -55532 900000 3283 78180 -140338 -19462 -102012 900000 103907 -58438 56829 16706 -101027 -32013 -57632 -17136 31217 -28519 -4742 -65830 -52361 900000 -100014 -12343 -13177 15992 49143 15746 10280 -27549 13820 -24814 66996 5340 -4929 -5439 17933 19774 6872 17210 -10864 35954 9055 21019 30098 13399 11357 -275 17265 2971 7190 16093 15867 7837 4584 3193 9498 2082 6160 2994 10475 4577 981 8345 461 -1868 3249 -168 4414 311 1602 -10081 -6887 -4291 -857 -2186 1827 164 -1356 127 494 1617 1699 2637 -570 -1722 -955 -803 -2983 -1413 -1851 609 -1066 -830 -1762 786 -2735 -1630 -1200 -1697 -1479 -75 703 -95 1271 -665 189 616 -668 -858 -82 -114 61 1283 -540 1037 1532 1667 568 503 -1116 269 51 910 200 -198 501 109 -500 -296 880 171 65 340 -525 -273 -1369 -6908 900000 -1757 900000 -5931 -1482 -400 900000 24 563 -1653 -140 -1201 900000 748 -1051 409 180 -3853 -645 -1535 -296 337 -595 -82 -2179 -1545 900000 -4606 -258 -341 380 990 487 318 -1189 428 -1321 1736 307 -355 -423 1174 1323 534 1251 -1079 2329 808 1770 2577 1533 1455 -43 2410 494 1180 2409 2307 1213 755 591 1900 517 1591 782 2480 1176 284 2630 176 -769 1267 -64 1477 97 453 -3214 -2369 -1739 -399 -1083 968 94 -838 83 341 1146 1214 1820 -380 -1081 -568 -482 -2047 -1120 -1725 591 -1180 -940 -1907 816 -2627 -1519 -1210 -1840 -1543 -83 844 -130 1934 -1030 295 935 -973 -1290 -122 -179 94 2065 -889 1620 2292 2626 870 748 -1615 389 83 1568 387 -384 1017 234 -1169 -689 2078 414 161 810 -1190 -621 -2991 SS 20250410T114628.7Z 9231.490610 210 1 29.88 2 78.42 77.48 129.78 259.20 0.00 1 0.00 1 0 17 1.098e-01 6.829e-03 1.915e-02 1.423e-03 4.755109e-01 7.092332e-04 4.890588e-03 -6.000000e+00 6.117269e-02 226.60 -2.00 3.04 -2.00 319.35 0.00e+00 6.174988e-03 1.956913e-04 9.131784e-04 -6.000000e+00 2.820205e-03 292.98 -2.00 20.00 -2.00 318.49 0.00e+00 4.816 0.000 302.00 328.00 3 1.0190e+00 2.0151e-03 5.1692e-02 -6.0000e+00 1.5119e-01 8.1978e-03 2.3876e-03 2.1532e-02 -6.0000e+00 1.6386e-01 -3.1009e-02 1.8496e-03 1.2250e-02 -6.0000e+00 9.8264e-02 8.0208e-03 9.8766e-04 6.6152e-03 -6.0000e+00 4.2925e-02 1.0408e-03 -5.6132e-06 3.7568e-05 5.7866e-05 -6.0000e+00 2.7430e-03 1.5765e-02 0.0000e+00 11 8 0 10 0 0 6.84 25.07 0.47 0.01576 0.01572 117 117 1 5 0 255.290 33.25 20.00 25.07 29.55 3.7 1017.09 -32847 -24343 -36037 -33644 -41596 -51840 -38447 -40180 -37855 -21363 -18579 -31128 -27551 -18066 -3334 -6890 -4309 -1538 -5232 -772 1011 -7747 -1089 1196 -125 -5911 -4781 -2679 -8940 -5565 -2646 -164 -1680 -3247 -2998 -4428 -2705 -3887 -1215 1850 146 1323 1774 625 1567 1263 610 408 775 556 232 1550 541 1320 1579 1377 1162 434 1320 162 679 1139 1734 2760 1420 519 -617 -729 463 828 1342 804 478 533 198 -664 -1151 -2672 -2130 -1812 -1237 -1183 -1898 -1729 -916 -484 356 616 902 948 337 -189 -396 -617 -215 -346 -69 828 765 -46 -348 -1011 -992 -478 -929 -1120 -732 -490 -194 370 773 780 394 286 -128 -290 1 1 81 223 -33 370 681 357 454 262 -150 263 363 298 -7 -188 -266 -191 -126 -59 118 248 154 -118 -77 -288 -492 -633 -503 -905 -803 -958 -1266 -870 -1037 -1071 -548 -467 -954 -1013 -767 -152 -388 -262 -99 -378 -56 75 -620 -83 96 -11 -565 -462 -246 -847 -532 -285 -20 -219 -468 -406 -585 -383 -653 -243 430 39 340 479 177 447 371 183 125 242 180 82 602 212 554 696 625 545 206 605 74 320 585 927 1639 842 318 -363 -427 287 555 938 595 357 381 141 -427 -726 -1661 -1318 -1313 -972 -994 -1764 -1592 -894 -481 372 668 985 1010 337 -185 -362 -587 -208 -364 -78 1016 991 -60 -436 -1216 -1136 -542 -1102 -1423 -971 -657 -266 555 1215 1244 630 437 -191 -423 2 1 124 352 -53 582 1078 550 696 387 -211 385 558 472 -12 -332 -467 -351 -238 -116 235 505 309 -240 -148 -551 -936 SS 20250410T115143.9Z 9231.494258 213 1 29.91 2 77.20 77.02 130.96 258.59 0.00 1 0.00 1 0 17 6.851e-02 6.605e-03 1.073e-02 1.077e-03 4.404243e-01 5.361879e-04 4.512762e-03 -6.000000e+00 3.815650e-02 226.60 -2.00 3.04 -2.00 318.96 0.00e+00 5.223040e-03 1.297157e-04 4.690040e-04 -6.000000e+00 1.759094e-03 292.98 -2.00 20.00 -2.00 318.07 0.00e+00 4.390 0.000 302.00 328.00 3 9.2700e-01 1.4895e-03 4.7261e-02 -6.0000e+00 9.4303e-02 -1.2690e-04 1.7361e-03 2.0115e-02 -6.0000e+00 1.0221e-01 -2.2114e-02 1.2540e-03 1.0613e-02 -6.0000e+00 6.1292e-02 5.9594e-03 6.7219e-04 5.5890e-03 -6.0000e+00 2.6775e-02 1.7698e-03 3.2859e-05 2.8450e-05 4.7176e-05 -6.0000e+00 1.7109e-03 1.5720e-02 0.0000e+00 11 8 0 10 0 0 23.84 25.09 0.41 0.01572 0.01597 191 191 1 5 0 156.580 33.25 20.01 25.09 30.20 3.7 1020.72 -22022 -10491 -18341 -16636 -26452 -27870 -29307 -16644 -24076 -17179 -22163 -20709 -19005 -10267 -7340 -3918 -1313 -377 -1617 959 -1740 -677 -324 -1015 -1102 -2936 -2335 -2886 -5835 -3558 -2873 -492 584 -1247 -4299 -5137 -4123 -1516 567 334 475 918 2194 1117 2162 1344 776 481 113 377 704 1326 1248 1412 1325 880 890 357 181 60 10 1278 1994 2528 1414 -97 -442 -1303 -74 527 848 774 493 568 165 -601 -945 -2432 -1571 -1545 -1367 -1337 -1867 -1552 -1038 -279 -4 463 803 875 620 127 -96 -701 -151 -243 242 890 631 140 -320 -872 -1040 -593 -680 -958 -745 -613 -213 356 700 665 425 321 -193 -242 -150 27 68 260 -68 236 576 284 471 343 -54 510 397 158 102 -111 -193 -165 -114 -108 -25 375 238 50 -129 -512 -599 -602 -295 -599 -517 -806 -823 -930 -523 -916 -652 -885 -868 -959 -593 -507 -308 -110 -34 -158 97 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