File name: Pandora282s1_Ilo-UNAM_20250614_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20250615T045541.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250614_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1626 1775 Nominal wavelengths inside fitting window [nm]: 492.1006 492.2213 492.3420 492.4627 492.5833 492.7039 492.8246 492.9452 493.0657 493.1863 493.3069 493.4274 493.5479 493.6684 493.7889 493.9093 494.0298 494.1502 494.2706 494.3910 494.5114 494.6318 494.7521 494.8724 494.9928 495.1130 495.2333 495.3536 495.4738 495.5940 495.7143 495.8344 495.9546 496.0748 496.1949 496.3150 496.4351 496.5552 496.6753 496.7954 496.9154 497.0354 497.1554 497.2754 497.3954 497.5153 497.6353 497.7552 497.8751 497.9950 498.1148 498.2347 498.3545 498.4743 498.5941 498.7139 498.8337 498.9534 499.0732 499.1929 499.3126 499.4322 499.5519 499.6716 499.7912 499.9108 500.0304 500.1500 500.2695 500.3891 500.5086 500.6281 500.7476 500.8670 500.9865 501.1059 501.2254 501.3448 501.4641 501.5835 501.7029 501.8222 501.9415 502.0608 502.1801 502.2994 502.4186 502.5378 502.6571 502.7763 502.8954 503.0146 503.1337 503.2529 503.3720 503.4911 503.6101 503.7292 503.8482 503.9673 504.0863 504.2053 504.3242 504.4432 504.5621 504.6810 504.7999 504.9188 505.0377 505.1566 505.2754 505.3942 505.5130 505.6318 505.7505 505.8693 505.9880 506.1067 506.2254 506.3441 506.4628 506.5814 506.7000 506.8186 506.9372 507.0558 507.1743 507.2929 507.4114 507.5299 507.6484 507.7669 507.8853 508.0037 508.1222 508.2406 508.3589 508.4773 508.5956 508.7140 508.8323 508.9506 509.0688 509.1871 509.3053 509.4236 509.5418 509.6600 509.7781 509.8963 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250614T145419.4Z 9296.621058 407 1 31.37 2 49.12 34.59 101.31 241.13 0.00 1 0.00 1 0 15 3.449e-03 3.442e-03 1.892e-03 1.888e-03 2.329900e+03 1.164057e+02 1.727940e+02 -6.000000e+00 1.972706e+02 290.98 -2.00 20.00 -2.00 505.25 0.00e+00 4.882194e-04 5.278388e-05 3.275485e-05 -6.000000e+00 9.869311e-05 290.98 -2.00 20.00 -2.00 500.41 0.00e+00 8.833435e-02 3.709680e-02 1.432125e-02 -6.000000e+00 6.799328e-02 226.37 -2.00 3.04 -2.00 502.01 0.00e+00 1.525 0.000 489.00 513.00 1 8.2679e+00 2.8484e-03 2.6037e-03 -6.0000e+00 5.2264e-03 6.0504e-03 7.3890e-04 3.6834e-04 -6.0000e+00 1.3593e-03 3.9919e-04 -1.7471e-04 1.8585e-04 2.1809e-05 -6.0000e+00 3.4887e-04 1.4975e-02 4.3275e-05 10 0 0 10 0 0 53.08 25.20 1.43 0.01497 0.01376 8 8 1 4 0 3920.700 33.25 20.00 25.20 27.37 3.8 999.99 -261 138 18 151 269 517 486 250 520 523 -49 171 471 -323 -20 111 -164 -77 -117 -318 -7 -51 -41 173 514 213 -6 382 -270 -17 -90 -100 -261 149 481 -291 238 -12 -784 -160 -259 21 175 -66 490 341 115 -220 -119 -197 -1370 -504 -606 -767 -108 -394 48 -317 3 25 149 300 607 336 -153 354 30 -105 -461 -260 -54 -372 50 202 -356 -13 -227 -360 124 210 -421 -389 462 -404 112 -368 -313 -328 -276 -239 158 107 359 634 543 -10 16 -411 -564 -293 -249 -319 -293 -146 -549 -45 -237 -489 -254 33 -79 -79 555 115 557 290 323 741 581 191 -18 471 15 -235 -154 -179 587 -303 157 60 601 73 -102 -294 -198 36 -540 108 -79 488 418 129 287 105 158 164 405 -449 -480 143 -256 138 18 155 283 534 508 263 542 538 -52 177 479 -328 -21 113 -171 -79 -123 -338 -7 -54 -43 184 546 227 -7 394 -272 -17 -91 -102 -264 155 509 -310 250 -13 -812 -164 -266 22 182 -69 518 361 121 -228 -121 -195 -1378 -492 -590 -760 -105 -397 49 -327 3 26 153 309 624 345 -156 354 30 -102 -446 -258 -53 -357 48 197 -351 -13 -218 -352 120 202 -410 -369 439 -391 109 -362 -309 -323 -272 -237 158 108 354 622 546 -10 15 -390 -523 -277 -236 -297 -283 -145 -540 -44 -238 -484 -250 32 -77 -77 549 115 559 293 328 747 581 189 -18 452 15 -227 -150 -173 565 -293 150 57 587 70 -97 -279 -187 34 -513 104 -77 479 413 128 287 106 159 163 393 -429 -451 138 SQ 20250614T150800.5Z 9296.630562 419 1 29.65 2 47.35 31.11 104.05 239.84 0.00 1 0.00 1 0 15 3.376e-03 3.354e-03 1.861e-03 1.858e-03 2.146265e+03 1.138694e+02 1.507026e+02 -6.000000e+00 1.930534e+02 290.98 -2.00 20.00 -2.00 505.26 0.00e+00 4.283379e-04 5.198750e-05 3.053868e-05 -6.000000e+00 9.658595e-05 290.98 -2.00 20.00 -2.00 500.44 0.00e+00 1.565740e-01 3.649500e-02 1.499582e-02 -6.000000e+00 6.654718e-02 226.37 -2.00 3.04 -2.00 502.03 0.00e+00 1.474 0.000 489.00 513.00 1 8.1919e+00 2.8024e-03 2.5433e-03 -6.0000e+00 5.1151e-03 4.0544e-03 7.2692e-04 3.6235e-04 -6.0000e+00 1.3306e-03 4.3220e-04 -1.3885e-04 1.8229e-04 1.8607e-05 -6.0000e+00 3.4142e-04 1.4317e-02 4.0022e-05 10 0 0 10 0 0 80.49 25.22 1.43 0.01432 0.01335 8 8 1 4 0 3705.620 33.50 20.00 25.22 27.65 3.8 1001.73 -607 -182 -99 280 277 467 357 706 162 43 -48 152 341 -209 -105 -60 -307 156 154 2 179 71 148 193 457 -46 168 20 -481 -115 -485 -55 -97 -214 56 358 119 28 -36 -144 -120 304 -22 226 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92 187 58 -206 -275 -109 129 -238 78 100 77 58 435 443 140 -13 55 -72 -528 -561 -76 SQ 20250614T151218.3Z 9296.633545 422 1 31.93 2 46.83 29.96 104.90 239.42 0.00 1 0.00 1 0 15 3.723e-03 3.724e-03 2.180e-03 2.176e-03 2.474642e+03 1.344471e+02 1.719848e+02 -6.000000e+00 2.129146e+02 290.98 -2.00 20.00 -2.00 505.26 0.00e+00 5.338335e-04 6.099166e-05 3.493217e-05 -6.000000e+00 1.065252e-04 290.98 -2.00 20.00 -2.00 500.42 0.00e+00 1.445141e-01 4.281665e-02 1.717409e-02 -6.000000e+00 7.341531e-02 226.37 -2.00 3.04 -2.00 502.02 0.00e+00 1.459 0.000 489.00 513.00 1 8.5247e+00 3.2898e-03 2.6550e-03 -6.0000e+00 5.6427e-03 4.1618e-03 8.5210e-04 4.0881e-04 -6.0000e+00 1.4684e-03 3.1007e-04 7.4816e-04 2.1355e-04 2.1037e-05 -6.0000e+00 3.7642e-04 1.1901e-02 2.9899e-05 10 0 0 10 0 0 -35.99 25.23 1.34 0.01190 0.01709 8 8 1 4 0 3990.300 33.50 20.00 25.23 27.72 3.8 1002.30 -444 -321 -174 235 243 729 409 506 -90 92 -598 111 439 -396 -203 -173 -377 -300 -38 66 70 214 -175 175 255 379 580 107 -365 -148 -519 29 -89 420 8 197 260 -419 -19 -497 -43 246 155 362 418 614 418 301 162 -673 -632 -572 -701 -746 43 -282 271 -5 -140 -430 629 51 821 687 153 302 105 -394 -478 -313 409 -566 -237 13 -365 85 97 -448 -397 -29 -364 -478 210 -126 -86 -263 -226 -567 -511 -215 -17 -1 446 540 110 424 335 -154 -649 -365 -229 40 -464 -303 -393 -7 -32 -392 -18 33 543 484 878 268 364 268 650 413 488 308 47 198 -726 -262 182 -224 558 82 -76 -391 522 -464 200 -593 -142 -141 -406 50 313 3 104 210 369 -156 303 -20 167 -395 -479 157 -433 -320 -173 240 254 772 440 545 -97 98 -629 114 444 -400 -204 -175 -391 -319 -39 70 73 224 -184 184 269 398 602 110 -379 -149 -521 29 -92 431 9 207 270 -433 -20 -506 -44 251 161 377 437 641 433 308 162 -687 -627 -555 -678 -733 43 -281 274 -5 -142 -439 636 52 834 697 154 300 103 -397 -476 -308 398 -558 -235 13 -356 85 96 -435 -382 -28 -352 -466 205 -125 -83 -256 -220 -555 -500 -210 -16 -1 449 542 110 413 320 -150 -619 -342 -214 39 -444 -299 -395 -7 -32 -384 -18 32 535 484 886 265 361 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