File name: Pandora282s1_Ilo-UNAM_20250625_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250626T045416.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250625_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250625 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 202 344 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1762 305.3168 305.4574 305.5979 305.7385 305.8790 306.0196 306.1601 306.3006 306.4411 306.5816 306.7221 306.8625 307.0030 307.1435 307.2839 307.4243 307.5647 307.7051 307.8455 307.9859 308.1263 308.2666 308.4070 308.5473 308.6876 308.8279 308.9682 309.1085 309.2488 309.3891 309.5293 309.6696 309.8098 309.9500 310.0902 310.2304 310.3706 310.5108 310.6510 310.7911 310.9313 311.0714 311.2115 311.3516 311.4917 311.6318 311.7719 311.9120 312.0520 312.1921 312.3321 312.4721 312.6121 312.7521 312.8921 313.0321 313.1721 313.3120 313.4520 313.5919 313.7318 313.8717 314.0116 314.1515 314.2914 314.4312 314.5711 314.7109 314.8508 314.9906 315.1304 315.2702 315.4100 315.5497 315.6895 315.8293 315.9690 316.1087 316.2484 316.3881 316.5278 316.6675 316.8072 316.9469 317.0865 317.2261 317.3658 317.5054 317.6450 317.7846 317.9242 318.0637 318.2033 318.3428 318.4824 318.6219 318.7614 318.9009 319.0404 319.1799 319.3193 319.4588 319.5982 319.7377 319.8771 320.0165 320.1559 320.2953 320.4347 320.5740 320.7134 320.8527 320.9921 321.1314 321.2707 321.4100 321.5493 321.6885 321.8278 321.9671 322.1063 322.2455 322.3847 322.5239 322.6631 322.8023 322.9415 323.0806 323.2198 323.3589 323.4980 323.6372 323.7763 323.9153 324.0544 324.1935 324.3325 324.4716 324.6106 324.7496 324.8887 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250625T124349.5Z 9307.530434 84 1 4.47 2 72.35 57.48 76.91 53.80 0.00 1 0.00 1 0 17 2.941e-02 7.120e-03 1.813e-02 3.772e-03 3.673743e-01 1.863670e-03 3.794164e-03 -6.000000e+00 1.636460e-02 226.40 -2.00 3.04 -2.00 318.02 0.00e+00 3.136156e-03 3.353123e-04 2.659610e-04 -6.000000e+00 7.478141e-04 290.72 -2.00 20.00 -2.00 317.14 0.00e+00 3.251 0.000 302.00 328.00 3 2.5324e+00 4.9896e-03 3.5884e-02 -6.0000e+00 4.0459e-02 -1.0737e-02 5.6760e-03 1.6528e-02 -6.0000e+00 4.3877e-02 -1.6222e-02 3.6168e-03 8.2285e-03 -6.0000e+00 2.6278e-02 6.1444e-03 1.8962e-03 3.3447e-03 -6.0000e+00 1.1456e-02 1.1209e-03 3.1497e-05 1.0038e-04 2.9254e-05 -6.0000e+00 7.3439e-04 1.6355e-02 0.0000e+00 12 9 1 12 1 1 96.99 24.91 0.53 0.01635 0.01659 7 54 1 5 0 557.690 33.25 20.00 24.91 27.44 3.8 1000.00 -7945 -4431 -6869 -11901 -11473 -13688 -13598 -4893 -3171 -2021 -2484 -5635 -1658 -11226 1430 3545 -3208 -2760 620 739 3588 1789 1994 -156 -232 765 1314 203 -3530 -3395 2288 -226 1050 -1885 -2720 -3863 -2429 -1723 285 -109 -134 96 -757 -558 798 1499 583 -294 -518 -381 2565 -94 1128 906 1972 1358 1761 -66 694 -108 664 282 1291 2636 1402 725 -997 -952 171 807 193 643 1112 268 466 -684 -529 -2491 -1745 -1694 -2029 -1083 -1355 -1141 -229 -176 -264 112 280 727 63 -139 -764 -1391 -932 -346 120 1177 508 39 -370 -817 -725 -265 -796 -550 -351 -622 -327 692 533 802 200 476 -302 -42 18 217 44 348 -70 280 528 309 590 795 -240 997 269 277 124 -120 -92 -350 -480 -187 190 375 255 -312 -83 -694 -450 -497 -303 -508 -884 -747 -866 -910 -338 -243 -163 -199 -485 -162 -1329 178 498 -517 -471 108 135 658 328 371 -32 -50 171 296 44 -752 -727 513 -54 276 -545 -740 -1016 -685 -564 103 -44 -60 45 -349 -263 373 706 277 -140 -247 -184 1288 -53 633 543 1222 866 1150 -41 447 -69 434 189 898 1989 1110 542 -706 -698 123 635 170 565 976 228 390 -549 -382 -1849 -1272 -1347 -1766 -1049 -1364 -1144 -243 -192 -306 129 326 856 70 -148 -784 -1383 -981 -389 138 1457 667 52 -483 -1018 -863 -316 -999 -705 -469 -847 -452 990 798 1248 308 717 -438 -59 25 311 65 531 -106 433 792 465 844 1130 -327 1372 387 423 196 -192 -151 -577 -817 -326 340 686 475 -574 -146 -1208 -776 SS 20250625T133424.9Z 9307.565566 114 1 29.57 2 62.57 50.69 67.89 47.70 0.00 1 0.00 1 0 25 5.773e-02 1.677e-02 3.596e-02 1.009e-02 2.630757e-01 4.981688e-03 2.669804e-03 -6.000000e+00 3.212612e-02 226.40 -2.00 3.04 -2.00 317.66 0.00e+00 4.948750e-03 8.091386e-04 1.361955e-04 -6.000000e+00 1.467950e-03 290.72 -2.00 20.00 -2.00 316.78 0.00e+00 2.159 0.000 302.00 328.00 3 6.7280e+00 1.3241e-02 2.4371e-02 -6.0000e+00 7.9428e-02 1.2141e-01 1.5009e-02 1.3212e-02 -6.0000e+00 8.6134e-02 -2.3735e-02 9.1913e-03 6.0593e-03 -6.0000e+00 5.1587e-02 -1.2884e-04 4.6709e-03 4.4120e-03 -6.0000e+00 2.2492e-02 5.1769e-05 2.4970e-04 2.7567e-04 3.4055e-05 -6.0000e+00 1.4416e-03 1.5711e-02 0.0000e+00 12 8 8 10 0 0 99.96 24.98 0.01 0.01571 0.01759 14 14 1 5 0 2111.670 33.25 20.00 24.98 27.84 3.8 1002.00 -17195 34179 11117 11015 -21149 -26412 -620 -445 -10585 -13648 -7486 4226 -9988 -2851 6408 4958 9019 5345 9147 5168 9630 3857 -4505 4285 -2978 5601 1893 12198 -6238 697 3235 2869 2746 -5318 -2391 -2602 560 -8642 -1955 465 515 -6226 4550 4134 -1573 -2124 -341 3360 -1369 655 6831 -3813 -878 -2640 746 -988 -2356 688 1761 1096 2963 -456 1022 2225 -752 487 -3699 -958 -653 -201 546 216 2175 442 -439 1854 137 -3643 -2912 -3139 -2892 -2578 120 147 3015 546 -35 2043 1989 3335 3225 -3443 -1644 -2807 -441 -1407 293 428 1465 1481 260 -1612 -3682 -2088 669 617 -1336 -168 -406 -855 888 1973 711 100 -1781 -771 -178 -184 -101 79 -239 1300 1099 435 -1283 543 -1755 253 946 -1189 -594 -108 -1270 -1085 823 998 -721 1361 1164 322 -145 259 -1792 -2014 2658 1127 1052 -2415 -2964 -56 -44 -1271 -1760 -877 445 -1396 -438 1047 922 1687 1079 1855 1129 2057 851 -1078 974 -753 1340 471 2594 -1492 154 748 729 765 -1686 -678 -699 157 -3063 -776 211 255 -3444 2342 2177 -878 -1204 -188 1740 -728 338 3483 -2331 -550 -1770 497 -676 -1660 468 1156 717 1957 -336 812 1716 -608 394 -2851 -687 -486 -170 462 192 1903 380 -392 1451 98 -2514 -2047 -2506 -2608 -2337 114 145 3065 613 -41 2481 2439 3925 3524 -3658 -1707 -2782 -446 -1446 329 536 1972 1991 333 -1918 -4122 -2321 792 778 -1790 -233 -591 -1333 1449 3272 1160 153 -2541 -1006 -226 -243 -142 121 -376 1998 1649 634 -1796 713 -2218 336 1209 -1679 -884 -165 -1988 -1743 1375 1766 -1335 2521 2197 603 -261 447 -3048 SS 20250625T140237.0Z 9307.585150 135 1 28.40 2 57.55 45.98 63.25 43.54 0.00 1 0.00 1 0 17 1.800e-02 9.351e-03 8.363e-03 3.869e-03 2.186635e-01 1.910997e-03 2.279665e-03 -6.000000e+00 1.001594e-02 226.40 -2.00 3.04 -2.00 316.44 0.00e+00 3.932657e-03 2.305862e-04 1.760042e-04 -6.000000e+00 4.576664e-04 290.72 -2.00 20.00 -2.00 315.63 0.00e+00 1.857 0.000 302.00 328.00 3 5.6927e+00 4.9641e-03 2.0809e-02 -6.0000e+00 2.4763e-02 4.9395e-02 5.5666e-03 1.1025e-02 -6.0000e+00 2.6854e-02 -6.2202e-03 3.2375e-03 4.9171e-03 -6.0000e+00 1.6083e-02 -3.6058e-03 1.5573e-03 3.2845e-03 -6.0000e+00 7.0122e-03 2.1771e-04 1.1660e-04 1.0343e-04 2.4107e-05 -6.0000e+00 4.4945e-04 1.5806e-02 0.0000e+00 12 9 9 12 9 1 99.99 25.00 0.37 0.01581 0.01668 7 8 1 5 0 3549.510 33.50 20.00 25.00 26.46 3.7 991.73 -6003 5483 -526 4371 -7726 -4472 521 -5195 -735 1934 -3686 1593 -1475 2271 1429 -375 -1261 2771 2984 2135 1649 2356 445 -134 603 -146 -1391 4270 128 -1969 1402 -178 1781 -707 -2732 -3922 -2599 -4198 -1786 -1186 1505 -2674 -287 1449 -1171 -1018 -709 -451 -1136 -259 3614 -1143 944 435 878 -47 358 459 1130 1027 744 1723 1315 3008 700 -448 -372 -1240 -558 103 410 1138 549 1337 697 -735 242 -2855 -1348 -2183 -826 -1638 -1904 -1925 -1243 443 736 154 479 1193 638 -71 -226 -284 -147 -265 295 1512 836 236 -737 -66 -2245 -722 -239 -321 -976 -481 -366 -167 615 520 161 118 -40 -929 -255 217 386 764 -365 96 703 597 408 615 -896 273 13 344 -13 78 467 -455 -84 138 297 657 67 77 -75 -273 -1334 -1180 1057 -111 821 -1417 -739 85 -988 -148 395 -766 314 -339 583 388 -115 -404 880 982 733 582 806 155 -49 225 -56 -548 1498 44 -667 486 -68 721 -307 -1113 -1528 -1077 -2036 -927 -717 968 -1722 -186 941 -780 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