File name: Pandora282s1_Ilo-UNAM_20250823_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20250824T045202.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 282 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora282_OF_v2d20240118.txt Instrument calibration file used: Pandora282s1_CF_v2d20240531.txt Level 1 file used: Pandora282s1_Ilo-UNAM_20250823_L1_smca1c2d20240531p1-8.txt Full location name: Grupo de Investigacion en Ciencias de la Atmosfera, UNAM, Peru Short location name: Ilo-UNAM Country of location: Peru Location latitude [deg]: -17.6020 Location longitude [deg]: -71.3389 Location altitude [m]: 85 Local noon date: 20250823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1626 1775 Nominal wavelengths inside fitting window [nm]: 492.1006 492.2213 492.3420 492.4627 492.5833 492.7039 492.8246 492.9452 493.0657 493.1863 493.3069 493.4274 493.5479 493.6684 493.7889 493.9093 494.0298 494.1502 494.2706 494.3910 494.5114 494.6318 494.7521 494.8724 494.9928 495.1130 495.2333 495.3536 495.4738 495.5940 495.7143 495.8344 495.9546 496.0748 496.1949 496.3150 496.4351 496.5552 496.6753 496.7954 496.9154 497.0354 497.1554 497.2754 497.3954 497.5153 497.6353 497.7552 497.8751 497.9950 498.1148 498.2347 498.3545 498.4743 498.5941 498.7139 498.8337 498.9534 499.0732 499.1929 499.3126 499.4322 499.5519 499.6716 499.7912 499.9108 500.0304 500.1500 500.2695 500.3891 500.5086 500.6281 500.7476 500.8670 500.9865 501.1059 501.2254 501.3448 501.4641 501.5835 501.7029 501.8222 501.9415 502.0608 502.1801 502.2994 502.4186 502.5378 502.6571 502.7763 502.8954 503.0146 503.1337 503.2529 503.3720 503.4911 503.6101 503.7292 503.8482 503.9673 504.0863 504.2053 504.3242 504.4432 504.5621 504.6810 504.7999 504.9188 505.0377 505.1566 505.2754 505.3942 505.5130 505.6318 505.7505 505.8693 505.9880 506.1067 506.2254 506.3441 506.4628 506.5814 506.7000 506.8186 506.9372 507.0558 507.1743 507.2929 507.4114 507.5299 507.6484 507.7669 507.8853 508.0037 508.1222 508.2406 508.3589 508.4773 508.5956 508.7140 508.8323 508.9506 509.0688 509.1871 509.3053 509.4236 509.5418 509.6600 509.7781 509.8963 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250823T122044.5Z 9366.514404 78 1 29.76 2 71.99 71.44 76.10 72.67 0.00 1 0.00 1 0 22 2.621e-03 2.608e-03 6.959e-04 6.949e-04 3.156322e+03 4.338354e+01 2.294847e+02 -6.000000e+00 1.494832e+02 290.21 -2.00 20.00 -2.00 505.27 0.00e+00 5.879828e-04 1.944983e-05 3.920881e-05 -6.000000e+00 7.483469e-05 290.21 -2.00 20.00 -2.00 500.46 0.00e+00 3.457050e-01 1.365345e-02 1.977630e-02 -6.000000e+00 5.175166e-02 227.23 -2.00 3.04 -2.00 502.05 0.00e+00 3.190 0.000 489.00 513.00 1 6.1089e+00 1.0487e-03 4.9221e-03 -6.0000e+00 3.9760e-03 9.6216e-03 2.7130e-04 5.4042e-04 -6.0000e+00 1.0349e-03 2.6728e-03 6.4598e-04 6.8023e-05 2.7950e-05 -6.0000e+00 2.6505e-04 2.0695e-02 -7.6383e-06 10 0 0 10 0 0 99.91 24.80 1.29 0.02070 0.02518 26 26 1 4 0 1144.230 33.25 20.00 24.80 22.20 3.9 964.90 -323 -158 -48 148 343 576 379 464 471 307 195 -9 -94 -102 -191 -96 -118 120 84 29 155 221 279 292 360 260 146 -65 -22 -338 -312 -247 -92 90 151 -24 41 -25 -234 -292 -166 -113 -35 97 169 204 140 41 -169 -447 -608 -736 -661 -461 -312 -236 -113 58 46 46 251 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-418 SQ 20250823T130212.2Z 9366.543197 105 1 31.38 2 62.75 66.83 66.95 68.67 0.00 1 0.00 1 0 15 3.336e-03 3.314e-03 1.753e-03 1.749e-03 2.476520e+03 1.077810e+02 1.682792e+02 -6.000000e+00 1.902738e+02 290.21 -2.00 20.00 -2.00 505.25 0.00e+00 4.006404e-04 4.897463e-05 2.791235e-05 -6.000000e+00 9.524910e-05 290.21 -2.00 20.00 -2.00 500.42 0.00e+00 2.039939e-01 3.449356e-02 1.815286e-02 -6.000000e+00 6.585160e-02 227.23 -2.00 3.04 -2.00 502.01 0.00e+00 2.172 0.000 489.00 513.00 1 8.0377e+00 2.6507e-03 3.4989e-03 -6.0000e+00 5.0597e-03 1.0057e-02 6.8678e-04 4.4368e-04 -6.0000e+00 1.3164e-03 4.5507e-04 -3.7603e-06 1.7140e-04 1.9506e-05 -6.0000e+00 3.3737e-04 1.8674e-02 2.7538e-05 10 0 0 10 0 0 97.17 24.80 1.45 0.01867 0.01865 9 9 1 4 0 3486.480 33.25 20.00 24.80 22.35 3.9 966.15 -415 -251 -134 85 32 606 -43 491 263 384 -144 -225 142 -189 253 -131 -167 85 -44 141 -134 100 171 359 204 565 195 -51 -387 -149 -386 -177 170 75 -154 252 -344 397 -382 -98 296 230 -111 207 333 446 327 21 -330 -507 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-215 -7 -170 -8 -158 61 133 62 425 -69 129 -22 231 -571 -456 -359 SQ 20250823T130639.8Z 9366.546294 108 1 31.80 2 61.77 66.28 65.97 68.18 0.00 1 0.00 1 0 15 4.106e-03 4.102e-03 2.191e-03 2.185e-03 2.149684e+03 1.337868e+02 1.555651e+02 -6.000000e+00 2.341897e+02 290.21 -2.00 20.00 -2.00 505.25 0.00e+00 5.508965e-04 6.120908e-05 3.898417e-05 -6.000000e+00 1.172378e-04 290.21 -2.00 20.00 -2.00 500.40 0.00e+00 2.593101e-01 4.310421e-02 1.493991e-02 -6.000000e+00 8.106369e-02 227.23 -2.00 3.04 -2.00 502.00 0.00e+00 2.103 0.000 489.00 513.00 1 8.4383e+00 3.3146e-03 3.3661e-03 -6.0000e+00 6.2283e-03 7.5439e-03 8.5933e-04 3.7912e-04 -6.0000e+00 1.6208e-03 3.0609e-04 2.7223e-05 2.1459e-04 2.1584e-05 -6.0000e+00 4.1527e-04 1.9518e-02 1.2336e-05 11 8 0 10 0 0 55.15 24.80 1.31 0.01952 0.01971 8 8 1 4 0 3974.820 33.25 20.00 24.80 22.42 3.9 966.86 -603 -395 -210 999 127 696 413 972 527 399 -321 -28 173 -95 283 76 -365 131 -226 185 -26 329 118 287 360 346 550 138 -519 -11 -454 -168 -602 -75 234 -117 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