File name: Pandora219s1_Ilocos_20241025_L2Fit_fwvt1c3d20240215p1-8.txt File generation date: 20241025T155239.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 219 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora219_OF_v2d20220124.txt Instrument calibration file used: Pandora219s1_CF_v3d20240215.txt Level 1 file used: Pandora219s1_Ilocos_20241025_L1_smca1c3d20240215p1-8.txt Full location name: Mariano Marcos State University Short location name: Ilocos Country of location: Philippines Location latitude [deg]: 18.0582 Location longitude [deg]: 120.5451 Location altitude [m]: 34 Local noon date: 20241025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 101 First and last pixel inside fitting window: 1602 1751 Nominal wavelengths inside fitting window [nm]: 492.0264 492.1479 492.2694 492.3909 492.5123 492.6338 492.7552 492.8766 492.9980 493.1193 493.2407 493.3620 493.4833 493.6046 493.7259 493.8472 493.9684 494.0897 494.2109 494.3321 494.4533 494.5744 494.6956 494.8167 494.9378 495.0589 495.1800 495.3011 495.4221 495.5432 495.6642 495.7852 495.9062 496.0271 496.1481 496.2690 496.3899 496.5108 496.6317 496.7526 496.8734 496.9942 497.1150 497.2358 497.3566 497.4774 497.5981 497.7188 497.8396 497.9603 498.0809 498.2016 498.3222 498.4429 498.5635 498.6841 498.8046 498.9252 499.0457 499.1662 499.2868 499.4072 499.5277 499.6482 499.7686 499.8890 500.0094 500.1298 500.2502 500.3705 500.4909 500.6112 500.7315 500.8518 500.9720 501.0923 501.2125 501.3327 501.4529 501.5731 501.6933 501.8134 501.9336 502.0537 502.1738 502.2939 502.4139 502.5340 502.6540 502.7740 502.8940 503.0140 503.1339 503.2539 503.3738 503.4937 503.6136 503.7335 503.8533 503.9732 504.0930 504.2128 504.3326 504.4523 504.5721 504.6918 504.8115 504.9312 505.0509 505.1706 505.2902 505.4099 505.5295 505.6491 505.7687 505.8882 506.0078 506.1273 506.2468 506.3663 506.4858 506.6052 506.7247 506.8441 506.9635 507.0829 507.2023 507.3216 507.4410 507.5603 507.6796 507.7989 507.9181 508.0374 508.1566 508.2758 508.3950 508.5142 508.6334 508.7525 508.8717 508.9908 509.1099 509.2290 509.3480 509.4671 509.5861 509.7051 509.8241 509.9431 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241025T012550.8Z 9064.059616 364 1 15.57 2 45.20 129.60 39.85 282.56 0.00 1 0.00 1 0 15 3.841e-03 3.825e-03 7.159e-04 7.145e-04 4.949721e+03 4.912170e+01 3.359553e+02 -6.000000e+00 2.322704e+02 294.19 -2.00 20.00 -2.00 505.25 0.00e+00 2.730849e-04 2.070727e-05 2.304758e-05 -6.000000e+00 1.131228e-04 294.19 -2.00 20.00 -2.00 500.39 0.00e+00 2.237473e-02 1.440015e-02 2.953521e-02 -6.000000e+00 7.752550e-02 226.85 -2.00 3.11 -2.00 501.99 0.00e+00 1.417 0.000 489.00 513.00 1 5.3145e+00 1.1123e-03 3.2705e-03 -6.0000e+00 5.9812e-03 1.3265e-02 2.8217e-04 7.2043e-04 -6.0000e+00 1.5361e-03 7.7895e-03 1.1628e-03 7.8809e-05 2.8320e-05 -6.0000e+00 4.4487e-04 7.2881e-02 -1.2729e-05 12 9 1 12 1 1 99.97 23.65 0.20 0.07288 0.08095 26 18 1 4 0 576.550 26.62 19.99 23.65 37.12 0.0 1025.41 -697 -468 -241 -280 -13 492 505 492 364 276 122 -237 -201 -427 -392 -538 -90 84 -127 -63 238 316 585 653 561 380 243 -92 -677 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-71 154 -74 97 8 301 393 801 599 534 220 216 32 179 450 92 205 280 329 235 496 106 -305 -480 -515 -510 -142 0 -270 24 -8 128 0 455 290 334 119 -324 -375 -524 -371 900000 SQ 20241025T013523.4Z 9064.066243 367 1 48.42 2 43.48 131.85 42.02 282.67 0.00 1 0.00 1 0 15 7.369e-03 7.382e-03 5.287e-03 5.257e-03 5.330661e+03 3.656231e+02 3.601330e+02 -6.000000e+00 4.455937e+02 294.19 -2.00 20.00 -2.00 505.16 0.00e+00 4.830531e-04 1.503749e-04 3.247596e-05 -6.000000e+00 2.169933e-04 294.19 -2.00 20.00 -2.00 500.24 0.00e+00 8.839529e-02 1.062534e-01 3.031108e-02 -6.000000e+00 1.486625e-01 226.85 -2.00 3.11 -2.00 501.82 0.00e+00 1.376 0.000 489.00 513.00 1 7.5883e+00 8.1752e-03 3.3396e-03 -6.0000e+00 1.1471e-02 1.0689e-02 2.1099e-03 7.3905e-04 -6.0000e+00 2.9442e-03 7.9947e-04 5.7708e-04 5.8295e-04 3.3998e-05 -6.0000e+00 8.5339e-04 6.9110e-02 4.5397e-05 12 8 8 10 0 0 99.81 23.66 0.19 0.06911 0.07311 14 3 2 4 0 3457.760 26.62 20.00 23.66 37.91 0.0 1029.24 -72 -1186 -79 -391 -253 1138 -576 511 1069 239 -29 -222 -1008 -837 -876 -891 -498 -572 -250 -1061 483 341 1759 253 1212 213 1351 -631 -126 -635 227 -925 -730 487 -275 -708 1106 1820 -221 -336 495 -54 -70 262 -96 635 -1089 452 1172 -857 -1096 -26 -338 -62 -99 462 -239 1550 -1318 1787 -155 228 868 -334 -304 334 283 -510 -481 -889 -577 410 -99 1663 -560 -31 -1062 102 929 -339 -489 -1152 948 -68 567 -556 -396 -194 146 885 658 749 529 -474 205 1413 -1132 242 87 -838 150 -661 1212 -933 -393 -478 -769 -132 139 429 448 -804 210 725 83 254 131 195 1217 -466 -714 257 183 505 1099 -677 0 258 -216 -430 -715 -291 -1055 -2005 117 -388 489 1004 -837 752 336 1183 654 128 -515 198 -397 -651 -915 900000 -68 -1151 -78 -398 -264 1193 -623 548 1136 253 -30 -229 -1036 -851 -889 -911 -517 -607 -269 -1161 522 370 1882 275 1307 231 1435 -672 -130 -646 227 -946 -764 516 -299 -772 1175 1901 -233 -354 519 -57 -75 283 -104 682 -1177 473 1192 -867 -1085 -25 -326 -61 -99 473 -250 1599 -1400 1841 -163 239 907 -351 -316 339 283 -509 -475 -874 -563 398 -98 1628 -559 -30 -1037 97 874 -323 -469 -1121 912 -67 558 -555 -396 -194 146 879 662 759 538 -483 204 1351 -1083 223 80 -767 137 -629 1171 -945 -400 -485 -776 -131 138 430 454 -834 217 751 81 247 128 189 1158 -443 -672 238 170 467 1012 -634 0 238 -199 -395 -651 -260 -941 -1808 104 -354 450 933 -801 715 322 1130 629 124 -496 186 -369 -597 -837 900000 SQ 20241025T015743.4Z 9064.081752 383 1 49.51 2 39.72 137.81 47.09 283.07 0.00 1 0.00 1 0 22 4.499e-03 4.452e-03 1.841e-03 1.831e-03 5.605867e+03 1.277840e+02 3.728785e+02 -6.000000e+00 2.720461e+02 294.19 -2.00 20.00 -2.00 505.16 0.00e+00 3.115399e-04 5.249300e-05 2.585816e-05 -6.000000e+00 1.324992e-04 294.19 -2.00 20.00 -2.00 500.19 0.00e+00 -6.310976e-02 3.721739e-02 3.230001e-02 -6.000000e+00 9.081198e-02 226.85 -2.00 3.11 -2.00 501.78 0.00e+00 1.299 0.000 489.00 513.00 1 7.5069e+00 2.8684e-03 3.3713e-03 -6.0000e+00 7.0061e-03 1.3040e-02 7.3589e-04 7.7889e-04 -6.0000e+00 1.7996e-03 8.8851e-04 1.5163e-03 2.0194e-04 3.2016e-05 -6.0000e+00 5.2106e-04 7.1857e-02 -1.4845e-05 11 8 0 10 0 0 99.93 23.61 0.29 0.07186 0.08237 24 5 1 4 0 2062.800 26.62 20.01 23.61 38.79 0.0 1032.56 -1224 -756 -148 -226 -206 400 327 544 512 513 182 -181 8 -268 -675 -744 -431 -204 -211 -6 273 232 427 609 299 355 147 33 -812 -122 -587 -273 490 705 -197 -280 151 267 -37 361 185 133 451 160 384 399 227 68 64 -490 -615 -587 -465 -508 -243 -249 -185 648 -450 704 563 612 325 360 -95 34 -119 -184 -96 -631 0 -521 471 466 -440 -420 -372 414 -714 -292 -500 -613 -437 394 -93 62 -406 137 -109 259 595 812 722 476 552 -53 -236 -406 -761 -730 -600 -2 480 -116 -375 -428 -359 -747 -310 210 -291 231 -175 647 239 874 684 914 156 -47 -213 507 400 186 234 177 363 -3 479 143 -299 -332 -540 -780 -441 -424 -580 -41 327 330 184 579 214 571 124 -554 -289 -947 -499 900000 -1170 -733 -146 -231 -216 424 351 586 549 543 191 -188 8 -272 -686 -763 -448 -216 -228 -6 297 252 464 663 327 386 158 35 -848 -124 -593 -278 508 749 -214 -305 163 284 -39 379 195 142 482 173 416 430 243 72 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